Water-Soluble Pentagonal-Prismatic Titanium-Oxo Clusters
Release time:2019-06-12
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- Abstract:
- By using solubility control to crystallize the prenucleation clusters of hydrosol, a family of titanium-oxo clusters possessing the {Ti18O27} core in which the 18 Ti(IV)-ions are uniquely connected with μ-oxo ligands into a triple-decked pentagonal prism was obtained. The cluster cores are wrapped by external sulfate and aqua ligands, showing good solubilities and stabilities in a variety of solvents including acetonitrile and water and allowing their solution chemistry being studied by means of electrospray ionization mass spectroscopy, 17O NMR, and vibrational spectroscopy. Furthermore, this
- Correspondence Author:
- Guanyun Zhang, Caiyun Liu, De-Liang Long, Leroy Cronin, Chen-Ho Tung, and Yifeng Wang*
- Volume:
- 138
- Issue:
- 35
- Page Number:
- 11097–11100
- Translation or Not:
- no
- Date of Publication:
- 2016-08-01