奚宝娟，女，1982年8月，教授，博士生导师

山东省泰山学者青年专家

山东省杰青青年基金获得者

课题组一直从事无机固体材料的化学研究，主要以储能、光/电催化为导向对无机材料在纳米尺度、微纳结构方面进行晶体材料及其组装结构的普适制备、选择性合成进行方法学的探索，并且对材料在储能和光/电催化应用方面开展基础应用研究。近三年在Angew., Adv. Mater., Nano Lett., Adv. Energy Mater., Chem. Mater.和J. Mater. Chem. A等刊物发表通讯作者论文20余篇。

邮箱：baojuanxi@sdu.edu.cn

【主讲课程】

大学化学 (本科生)

 

【研究领域和兴趣】

研究方向：无机合成化学与先进能源材料

研究内容主要包括：

(1) 新型高性能储电器件如锂/钠/钾离子电池及锂硫电池等的电极材料的探索：电极材料的设计，制备及其电化学性能的检测，研究结构-性能的内在联系。

(2) 无机材料相关的催化性能的研究：开展对新型结构催化剂材料的研究，利用化学液相合成及晶体结构的本质习性等来对进行材料进行控制合成和优化组装，获得结构新颖的功能材料。

 

【拟招收研究生情况】

 每年拟招收化学、物理、材料方向的硕士研究生1-2名，博士生1名，博士后数量不限。

自2022年以来代表性论文：

[8] Jia Yuan, Peng Wang, Ning Song, Yu Wang, Jazhen Ma, Shenglin Xiong, Xiaogang Li, Jinkui Feng, and Baojuan Xi*, “Alloying Strategy Regulating Size and Electronic Structure of Mo_0.25Nb_0.75Se₂ to Achieve High-Performance Lithium–Sulfur Batteries”, Angew. Chem. Int. Ed. 2024, 63(xx), 202420866; on line.

 

[7] Bin Li, Peng Wang, Jia Yuan, Ning Song, Jinkui Feng, Shenglin Xiong*, and Baojuan Xi*, “P-doped RuSe₂ on Porous N-doped Carbon Matrix as Catalysts for Accelerated Sulfur Redox Reactions”, Angew. Chem. Int. Ed. 2024, 63(48), 63, e202408906; DOI: 10.1002/anie.202408906.

[6] Bin Li, Peng Wang, Jia Yuan, Ning Song, Jinkui Feng, Shenglin Xiong*, and Baojuan Xi*, “Origin of Phase Engineering CoTe₂ Alloy toward Kinetics-Reinforced and Dendrite-Free Lithium−Sulfur Batteries”, Adv. Mater. 2024, 36(8), 2309324.

[5] Chuanliang Wei, Baojuan Xi*, Peng Wang, Yazhan Liang, Zhengran Wang, Kangdong Tian, Jinkui Feng*, and Shenglin Xiong*, “In-Situ Anchoring Ultrafine ZnS Nanodots on 2D MXene Nanosheets for Accelerating Polysulfide Redox and Regulating Li Plating”, Adv. Mater. 2023, 35(32), 2303780; DOI: 10.1002/adma.202303780.

[4] Peng Wang, Zhengchunyu Zhang, Ning Song, Xuguang An, Jie Liu, Jinkui Feng, Baojuan Xi*, and Shenglin Xiong*, “WP Nanocrystals on N,P Dual-Doped Carbon Nanosheets with Deeply-Analyzed Catalytic Mechanisms for Lithium–Sulfur Batteries”, CCS Chem. 2023, 5(2), 397–411; DOI: 10.31635/ccschem.022.202202163.

[3] Peng Wang, Fanghan Sun, Shenglin Xiong*, Zhengchunyu Zhang, Bin Duan, Chenghui Zhang, Jinkui Feng, and Baojuan Xi*, “WSe₂ Flakelets on N-doped Graphene for Accelerating Polysulfide Redox and Regulating Li Plating”, Angew. Chem. Int. Ed. 2022, 61(7), e202116048; DOI:10.1002/anie.202116048.

[2] Zhengchunyu Zhang, Peng Wang, Chuanliang Wei, Jinkui Feng, Shenglin Xiong*, and Baojuan Xi*,  Synchronous Regulation of d-Band Centers in Zn Substrates and Weakening Pauli Repulsion of Zn ions using the Ascorbic Acid Additive for Reversible Zinc Anodes, Angew. Chem. Int. Ed. 2024, 63(19), e202402069; DOI: 10.1002/anie.202402069.

[1] Fan Liu, Jingui Zong, Yazhan Liang, Mingzhe Zhang, Kepeng Song*, Liwei Mi, Jinkui Feng, Shenglin Xiong* and Baojuan Xi*, Ordered Vacancies as Sodium Ion Micropumps in Cu−Deficient Copper Indium Diselenide to Enhance Sodium Storage, Adv. Mater. 2024, 36(26), 202403131; DOI: 10.1002/adma.202403131.   

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 【2022】

[1] Peng Wang, Fanghan Sun, Shenglin Xiong*, Zhengchunyu Zhang, Bin Duan, Chenghui Zhang, Jinkui Feng, and Baojuan Xi*, “WSe₂ Flakelets on N-doped Graphene for Accelerating Polysulfide Redox and Regulating Li Plating”, Angew. Chem. Int. Ed. 2022, 61(7), e202116048; DOI:10.1002/anie.202116048.

[2] Xiao Wang, Zhengchunyu Zhang, Man Huang, Jinkui Feng, Shenglin Xiong*, and Baojuan Xi*, “In-Situ Electrochemically Activated Vanadium Oxide Cathode for Advanced Aqueous Zn-Ion Batteries”, Nano Lett. 2022, 21(1), 119−127; DOI:10.1021/acs.nanolett.1c03409.

[3] Yuanxing Yun, Baojuan Xi*, Fang Tian, Weihua Chen, Wenping Sun, Hongge Pan, Jinkui Feng, Yitai Qian, and Shenglin Xiong*,  “Zero-strain Structure for Efficent Ptassium Storage: Nitrogen-enriched Carbon Dual-Confinement CoP Composite”, Adv. Energy Mater. 2022, 12(3), 2103341; DOI: 10.1002/aenm.202103341.

[4] Ning Song, Baojuan Xi*, Peng Wang, Xiaojian Ma, Weihua Chen, Jinkui Feng, and Shenglin Xiong*, “Immobilizing VN ultrafine nanocrystals on N-doped carbon nanosheets enable multiple effects for high-rate lithium–sulfur batteries”, Nano Res. 2022, 15(2), 1424–1432.

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【2021】

[1] Peng Wang, Baojuan Xi*, Zhengchunyu Zhang, Man Huang, Jinkui Feng, and Shenglin Xiong*, “Atomic Tungsten on Graphene with Unique Coordination Enabling Kinetically Boosted Lithium−sulfur Batteries”, Angew. Chem. Int. Ed. 2021, 60(28), 15563–15571. DOI:10.1002/anie.202104053. (Dedicated to Professor Yitai Qian on the occasion of his 80th birthday)

[2] Peng Wang, Baojuan Xi*, Man Huang, Weihua Chen, Jinkui Feng, and Shenglin Xiong*, “Emerging catalysts to promote kinetics of lithium−sulfur batteries”, Adv. Energy Mater. 2021, 11(7), 2002893.

[3] Zhengchunyu Zhang, Baojuan Xi*, Xiao Wang, Xiaojian Ma, Weihua Chen, Jinkui Feng, and Shenglin Xiong*, “Oxygen Defects Engineering of VO₂·xH₂O Nanosheets via In−Situ Polypyrrole Polymerization for Efficient Aqueous Zinc Ion Storage”, Adv. Funct. Mater. 2021, 31(34), 2103070; DOI: 10.1002/adfm.2103070.

[4] Xiao Wang, Zhengchunyu Zhang, Shenglin Xiong, Fang Tian, Zhenyu Feng, Yuxi Jia, Jinkui Feng, and Baojuan Xi*, "A high-rate and ultrastable aqueous zinc-ion battery with a novel MgV₂O₆ ·1.7H₂O nanobelt cathode", Small 2021, 17(20), 2100318; DOI: 10.1002/smll.202100318.

[5] Rui Luo#, Zhengchunyu Zhang#, Jing Zhang, Baojuan Xi*, Fang Tian, Weihua Chen, Jinkui Feng, and Shenglin Xiong, "Bimetal CoNi active sites on mesoporous carbon nanosheets to kinetically boost lithium−sulfur batteries", Small 2021, 17(23), 2100414; DOI: 10.1002/smll.202100414. # Contributed equally

[6] Peng Wang, Baojuan Xi,* Zhengchunyu Zhang, Ning Song, Weihua Chen, Jinkui Feng, and Shenglin Xiong, "

Dual-Functional MgO Nanocrystals Satisfying Both Polysulfides and Li Regulation toward Advanced Lithium−Sulfur Full Batteries", Small 2021, 17(44), 2103744; DOI: 10.1002/smll.202103744.

[7] Jianmei Han, Qiang Fu, Baojuan Xi*, Xuyan Ni, Chenglin Yan, Jinkui Feng, and Shenglin Xiong, “Loading Fe₃O₄ nanoparticles on paper-derived carbon scaffold toward advanced lithium-sulfur batteries”, J. Energy Chem. 2021, 51, 1–11; DOI: 10.1016/j.jechem.2020.04.002.

[8] Yuanxing Yun, Baojuan Xi*, Yu Gu, Fang Tian, Weihua Chen, Jinkui Feng, Yitai Qian,and Shenglin Xiong*, “Cu₃P nanoparticles confined in nitrogen/phosphorus dual-doped porous carbon nanosheets for efficient potassium storage”, J. Energy Chem. 2021, 66, 339−347; DOI: 10.1016/j.jechem.2021.05.045. 

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【2020】

[11] Xiao Wang, Baojuan Xi*, Xiaojian Ma, Zhenyu Feng, Yuxi Jia, Jinkui Feng, Yitai Qian, and Shenglin Xiong*, "Boosting zinc-ion storage capability by effectively suppressing vanadium dissolution based on robust layered barium vanadate", Nano Lett. 2020, 20(4), 2899−2906. DOI:10.1021/acs.nanolett.0c00732. 

[10] Ruchao Wei^#, Yu Gu^#, Lianli Zou^#, Baojuan Xi*, Yixuan Zhao, Yining Ma, Yitai Qian, Shenglin Xiong*, and Qiang Xu*, "Nanoribbon Superstructures of Graphene Nanocages for Efficient Hydrogen Evolution", Nano Lett. 2020, 20(10), 7342−7349. DOI:10.1021/acs.nanolett.0c02766. # Contributed equally

[9] Yu Gu, Baojuan Xi*, Ruchao Wei, Qiang Fu, Yitai Qian, Shenglin Xiong*, “Sponge Assembled by Graphene Nanocages with Double Active Sites to Accelerates Alkaline HER Kinetics”, Nano Lett. 2020, 20(11), 8375−8383.  DOI:10.1021/acs.nanolett.0c03565.  

[8]  Kangkang, Baojuan Xi*, Ruchao Wei, Haibo Li, Jinkui Feng, and Shenglin Xiong, “Hierarchical microcables contructed by CoP@C⊂carbon framework interwined with carbon nanobutes for efficient lithium storage”, Adv. Energy Mater. 2020, 10(10), 1902913, DOI:10.1002/aenm.201902913.

[7]  Nianxiang Shi, Yanting Chu, Baojuan Xi*, Man Huang, Weihua Chen, Bin Duan, Chenghui Zhang, Jinkui Feng, and Shenglin Xiong*, “Sandwich Structures Constructed by ZnSe⊂N-C@MoSe₂ Located in Graphene for Efficient Sodium Storage”, Adv. Energy Mater. 2020, 10(41), 2002298, DOI:10.1002/aenm.xxxx.

[6]  Man Huang, Yanting Chu, Baojuan Xi*, Nianxiang Shi, Bin Duan, Chenghui Zhang, Weihua Chen, Jinkui Feng, and Shenglin Xiong, “TiO₂-Based Heterostructures with Different Mechanism: A General Synergistic Effect toward High-Performance Sodium Storage”, Small 2020, 16(42), 2004054; DOI: 10.1002/smll.202004054.

[5]  Nianxiang Shi, Baojuan Xi*, Man Huang, Xiaojian Ma, Haibo Li, Jinkui Feng, and Shenglin Xiong, “Hierarchical octahedra contructed by Cu₂S@MoS₂⊂carbon framework with enhanced sodium storage”, Small 2020, 16(23), 2000952; DOI: 10.1002/smll.202000952.

[4] Man Huang, Baojuan Xi*, Nianxiang Shi, Ruchao Wei, Haibo Li, Jinkui Feng, and Shenglin Xiong, “Systematic Study of Alkali Cations Intercalated Titanium Dioxide Effect on Sodium and Lithium Storage ”, Small 2020, 16(33), 2001391; DOI: 10.1002/smll.202001391.

[3]  Nianxiang Shi, Baojuan Xi*, Fang Tian, Xiaojian Ma, Haibo Li, Jinkui Feng, and Shenglin Xiong, "Boosting Na⁺ storage ability of bimetallic Mo_xW_1-xSe₂ with expanded interlayers",  Chem. Eur. J. 2020, 26(43),  9580–9588; DOI: 10.1002/chem.202000820.

[2] Ruchao Wei^#, Xiao Wang^#, Baojuan Xi*, Zhenyu Feng, Haibo Li, Weihua Chen, Jinkui Feng, and Shenglin Xiong, “Layer-by-layer stacked  (NH4)2V4O9·0.5H2O Nanosheet Assemblies with Intercalation Pseudocapacitance for High Rate Aqueous Zinc-Ion Storage”, ACS Appl. Energy Mater. 2020, 3(6), 5343–5352. # Contributed equally.

[1]  Rui Luo, Baojuan Xi*, Ruchao Wei, Weihua Chen, Xiaojian Na, Zhenyu Feng, Jinkui Feng, and Shenglin  Xiong*, “N-doped Graphitic Ladder-structured Carbon Nanotubes as A Superior Sulfur Host for Lithium–Sulfur batteries”, Inorg. Chem. Front. 2020, 7(20), 3969–3979; DOI: 10.1039/d0qi00678e.

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【2019】

[4]  Wenzhi, Baojuan Xi*, Zhenyu Feng, haibo Li, Jinkui Feng, and Shenglin Xiong, “Sulfihilic few-layered MoSe₂ nanoflakes decorated rGO  as a highly efficient sulfur host for lithium-sulfur batteries”, Adv. Energy Mater. 2019, 9(36), 1901896. DOI:10.1002/aenm.201901896. 

[3] Baosong Li, Baojuan Xi*, fangfang Wu, Hongzhi Mao, Jing Liu, Jinkui Feng, and Shenglin Xiong, “One-step in situ formation of N-doped carbon nanosheets 3D porous networks/TiO2 hybrids with ultrafast sodium storage”, Adv. Energy Mater. 2019, 9(8), 1803070. DOI:10.1002/aenm.201803070. 

[2] Nianxiang Shi, Baojuan Xi*, Zhenyu Feng, Fangfang Wu, Denghu Wei, Jing Liu, and Shenglin Xiong*, “Insight into different-microstructured ZnO/graphene-functionaalized separators affecting the performance of lithium-sulfur batteries”, J. Mater. Chem. A. 2019, 7(8), 4009–4018. DOI: 10.1039/c8ta12409d.

[1] Nianxiang Shi, Baojuan Xi*, Zhenyu Feng, Jincheng Liu, Denghu Wei, JIng Liu, Jinkui Feng, and Shenglin Xiong, “Strong coupled W2C atomic nanoclusters on N/P-codoped graphene for kinetically enhanced sulfur host”, Adv. Mater. Interfaces 2019, 6(9), 1802088. DOI:10.1002/admi.201802088.

【2018】

[5] Qian Sun, Baojuan Xi*, Jiangying Li, Hongzhi Mao, Xiaojian Ma, Jianwen Liang, Jinkui Feng, and Shenglin Xiong, “Nitrogen-doped graphene-supported mixed transition-metal oxide porous particles to confine polysulfides for lithium-sulfur batteries”, Adv. Energy Mater. 2018, 8(22), 1800595. DOI: 10.1002/aenm.201800595. (I.F.: 21.875)

[4] Wenzhi Tian, Baojuan Xi*, Hongzhi Mao, Junhao Zhang, Jinkui Feng, Shenglin Xiong, “Systematic exploration of the role of a modified layer on the separator in the electrochemistry of lithium-sulfur batteries”, ACS Appl. Mater. Interfaces 2018, 10(36), 30306–30313.  (I.F.: 8.097)   

[3] Jiahui Li, Caining Xue, Baojuan Xi*, Hongzhi Mao, Yitai Qian*, and Shenglin Xiong, "Heteroatom dopings and hierarchical pores of graphene for synergistic improvement of lithium-sulfur battery performance", Inorg. Chem. Front. 2018, 5(5), 1053–1061. (I.F.: 5.106)

[2] Jianmei Han, Baojuan Xi*, Zhenyu Feng, Xiaojian Ma, Junhao Zhang, Shenglin Xiong, and Yitai Qian*, "Sulfur-hydrazine hydrate-based chemical synthesis of sulfur@graphene composite for lithium-sulfur batteries", Inorg. Chem. Front. 2018, 5(4), 785–792. (I.F.: 5.106)

[1] Jianmei Han, Xia Chen, Baojuan Xi*, Hongzhi Mao, Jinkui Feng, Shenglin Xiong, “High-surface-area nitrogen/phosphorus dual-doped hierarchical porous carbon derived from biochar for sulfur holder”, Chemistryselect 2018, 3(36), 10175–10181. (I.F.: 1.505)

 

【2017】

[3] Yong Jiang, Yibo Guo, Wenjun Lu, Zhenyu Feng, Baojuan Xi*, Shuangshuang Kai, Junhao Zhang, Jinkui Feng, and Shenglin Xiong*, "Rational incorporated MoS2/SnS2 nanoparticles on graphene sheets for lithium-ion and sodium-ion batteries", ACS Appl. Mater. Interfaces 2017, 9(33), 27697–27706. (I.F.:  7.504)

[2] Jing Bai, Baojuan Xi*, Zhenyu Feng, Junhao Zhang, Jinkui Feng, and Shenglin Xiong*, "General strategy for integrated SnO2/metal oxides as biactive lithium-ion battery anodes with ultralong cycling life", ACS Omega 2017, 2(10), 6415–6432.

[1] Nianxiang Shi, Shenglin Xiong, Fangfang Wu, Jin Bai, Yanting Chu, Hongzi Mao, Jinkui Feng, Baojuan Xi*, "Hydrothermal synthesis ZnWO4 hierarchical hexangular microstars for enhanced lithium storage properties", Eur. J. Inorg. Chem. 2017, 3, 734–740. (I.F.:  2.444)

【2016】

[4] Yong Jiang, Yazhi Feng, Baojuan Xi*, Shuangshuang Kai, Kan Mi, Jinkui Feng, Junhao Zhang and Shenglin Xiong, “Ultrasmall SnS2 nanoparticles anchored onwell-distributed nitrogen-doped graphene sheets for Li-ion and Na-ion batteries", J. Mater. Chem. A 2016, 4(27), 10719–10726. (I.F.:  8.262)

[3] Yanting Chu, Shenglin Xiong, Baosong Li,Yitai Qian and Baojuan Xi*, “Designed formation of MnO2@NiO/NiMoO4 nanowires@nanosheets hierarchical structures with enhanced pseudocapacitive properties", ChemElectroChem 2016, 3(9), 1347–1353.

[2] Xiaojian Ma, Lefei Huang, Fangfang Wu, Shenglin Xiong, and Baojuan Xi*, Formation of C@Fe3O4@C hollow sandwiched structures with enhanced lithium storage properties, Eur. J. Inorg. Chem. 2016, 23, 3722–3727. (I.F.: 2.942)

【进入山大前】

[7] Baojuan Xi, Ying Chuan Tan, Hua Chun Zeng*, A General Synthetic Approach for Integrated Nanocatalysts of Metal-Silica@ZIFs, Chem. Mater. 2016, 28 (1), 326–336.

[6] Baojuan Xi, et. al., Preparation of Ag/TiO2/SiO2 Films via Photo-Assisted Deposition and AdsorptiveSelf-Assembly for Catalytic Bactericidal Application”, Applied Surface Science 2014, 311, 582.

 [5] Baojuan Xi, L.K. Verma, Jing Li, C.S. Bhatia, A.J. Danner, H.S. Yang and Huachun Zeng*, TiO2 Thin Films Prepared via Adsorptive Self-Assembly for Self-Cleaning Applications, ACS Appl. Mater. Interfaces 2012, 4(2), 1093–1102. (Most read, 2012)

 [4] Baojuan Xi, Shenglin Xiong, Dechen Xu, Jingfa Li, Hongyang Zhou, Jun Pan, Jiangying Li, and Yitai Qian*, Tetraethylenepentamine-Directed Controllable Synthesis of wurtzite ZnSe Nanostructures with Tunable Morphology”, Chem. Eur. J. 2008, 14(31), 9786–9791.

 [3] Baojuan Xi, Dechen Xu, Shenglin Xiong, Chengming Wang, Xiaoming Feng, Hongyang Zhou, and Yitai Qian*, Preparation and Characterization of Cubic and Hexagonal Polytypes of ZnSe:Cu2+ One-dimensional Nanostructures, J. Phys. Chem. C 2008, 112(14), 5333–5338.

 [2] Baojuan Xi, Shenglin Xiong, Hai Fan, Xiaoqing Wang, and Yitai Qian*, Shape-Controlled Synthesis of Tellurium 1D Nanostructures via a Novel Circular Transformation Mechanism, CrystalGrowth & Design 2007, 7(6), 1185–1191.

 

 

【科研项目】

1、国家自然科学基金面上项目，No. 21971145, 2019.01-2022.12，负责人， 在研，65万。

2、国家自然科学青年基金项目，No. 21601108, 2018.01-2019.12，负责人， 结题，20万。

3、山东大学青年学者未来计划，No. 2017WLJH15, 2017.01-2022.12，负责人，在研，50万。

4、中国博士后科学基金面上项目二等资助，2018M632665，负责人，2018/03-2020/2，结题，5万。

• [1] 2007.9 -- 2009.5

  中国科技大学       化学类       博士生

• [2] 2004.9 -- 2007.7

  中国科技大学       化学类       硕士生

• [3] 2000.9 -- 2004.7

  聊城大学       化学教育       学士

• [4] 1997.9 -- 2000.7

  罗庄一中

• [1] 2017.09 -- 至今

  山东大学化学与化工学院      副教授

• [2] 2015.07 -- 2017.08

  山东大学化学与化工学院      助理研究员

• [3] 2010.04 -- 2015.02

  新加坡国立大学      博士后

• [4] 2009.06 -- 2011.04

  中国科学技术大学      博士后

• [1] 新型能源材料的研究