吴向坤，男，中共党员，博士。主要从事质谱仪器开发与质谱在大气高活性物质的检测、物化性质和微观反应机理等方向的研究。主持国家自然基金青年基金1项，博士后科学基金面上资助1项，参与国家重点研发计划，国家重大科学仪器设备开发专各1项。截至目前以第一作者和通讯作者身份在Angew. Chem. Int. Ed., J. Anal. Appl. Pyrolysis, Phys. Chem. Chem. Phys.和J. Chem. Phys.等国内外著名期刊发表SCI收录论文21篇。
主要从事质谱仪器开发与应用；大气中高活性物质的检测、物化性质和微观反应机理等方向的研究。
发表的主要论文成果：
25. X. Wu, C. Zhang, X. Gu, C. Fittschen, J.-C. Loison, M. Roy Chowdhury, G. A. Garcia,* L. Nahon, X. Tang,* “Photoionization and Dissociative Photoionization of Acetaldehyde in the 10.0–13.7 eV Range by Synchrotron Photoelectron Photoion Coincidence Spectroscopy” ChemPhysChem (2024), e202400208
24. X. Wu, P. Hemberger, and A. Bodi,* “Enlightening salt: enthalpy of formation of gaseous sodium chloride by photoelectron photoion coincidence spectroscopy” Mol. Phys. (2023), e2286308.
23. X. Wu, D. Salionov, P. Hemberger, F. Vogel, A. Bodi,* and S. Bjelić,* “Beyond vanilla: The dissociation mechanism of vanillin in four charge states” Comput. Theor. Chem. 1229 (2023), 114340.
22. X. Wu, Z. Pan, M. Steglich, P. Ascher, A. Bodi, S. Bjelić,* and P. Hemberger,* “A Direct Liquid Sampling Interface for Photoelectron Photoion Coincidence Spectroscopy” Rev. Sci. Instrum. 94 (2023), 034103.
21. X. Wu,* S. Bjelić, P. Hemberger, and A. Bodi,* “Isomer-Dependent Threshold Photoelectron Spectroscopy and Dissociative Photoionization Mechanism of Anisaldehyde” J. Phys. Chem. A 127 (2023), 661.
20. X. Wu,# Z. Zhang,# Z. Pan, X. Zhou, A. Bodi, and P. Hemberger,* “Ketenes in the Inductionof the Methanol-to-Olefins Process” Angew. Chem. Int. Ed. 61 (2022), e.202207777
19. X. Wu, Z. Zhang, Z. Pan, S. Bjelić, A. Bodi, and P. Hemberger,* “Isomer-Dependent Selectivities in the Pyrolysis of Anisaldehyde” Energy Fuels 36 (2022), 7200.
18. X. Wu, X. Zhou, S. Bjelić, P. Hemberger, B. Sztáray, and A. Bodi,* “A plethora of isomerization processes and hydrogen scrambling in the fragmentation of the methanol dimer cation: a PEPICO study” Phys. Chem. Chem. Phys. 24 (2022), 1437.
17. X. Wu, Z. Pan, S. Bjelić, P. Hemberger, and A. Bodi,* “Unimolecular thermal decarbonylation of vanillin stifled by the bimolecular reactivity of methyl-loss intermediate”, J. Anal. Appl. Pyrolysis 161 (2022), 105410.
16. X. Wu, X. Zhou,* S. Bjelić, P. Hemberger, and A. Bodi,* “Valence Photoionization and Energetics of Vanillin, a Sustainable Feedstock Candidate”, J. Phys. Chem. A 125 (2021), 3327.
15. X. Wu, X. Zhou,* P. Hemberger, and A. Bodi,* “Dissociative Photoionization of Chloro-, Bromo-, and Iodocyclohexane: Thermochemistry and the Weak C–Br Bond in the Cation”, J. Phys. Chem. A 125 (2021), 646.
14. X. Wu, X. Zhou,* P. Hemberger, and A. Bodi,* “Conformers, electronic states, and diabolical conical intersections in the valence photoelectron spectroscopy of halocyclohexanes”, J. Chem. Phys. 153 (2020), 054305.
13. X. Wu, X. Zhou,* P. Hemberger, and A. Bodi,* “A guinea pig for conformer selectivity and mechanistic insights into dissociative ionization by photoelectron photoion coincidence: fluorocyclohexane”, Phys. Chem. Chem. Phys. 22 (2020), 2351.
12. X. Wu, X. Zhou,* P. Hemberger, and A. Bodi,* “The ionization energy of the vinyl radical: a Mexican standoff with a happy ending”, Phys. Chem. Chem. Phys. 21 (2019), 22238.
11. X. Wu, T. Yu, Y. Chen, X. Zhou,* S. Liu, X. Dai, F. Liu and L. Sheng, “Dissociative photoionization of CF3Cl via the C2E and D2E states: competition of the C–F and C–Cl bond cleavages”, Phys. Chem. Chem. Phys. 21 (2019), 4998.
10. X. Wu, X. Tang, X. Zhou,* and S. Liu,* “Dissociation dynamics of energy-selected ions with threshold photoelectron-photoion coincidence velocity imaging”, Chin. J. Chem. Phys. 32 (2019), 11.
9. X. Wu, G. Tang, H. Zhang, X. Zhou,* S. Liu, F. Liu and L. Sheng, “Cl-Loss dynamics in the dissociative photoionization of CF3Cl with threshold photoelectron-photoion coincidence imaging”, Phys. Chem. Chem. Phys. 20 (2018), 4917.
8. X. Wu, M. Wu, X. Tang, X. Zhou,* S. Liu, F. Liu and L. Sheng, “Cl-loss dynamics of vinyl chloride cations in the B2A" state: role of the C2A' state”, J. Phys. Chem. A 121 (2017), 4743.
7. X. Wu, X. Zhou,* P. Hemberger and A. Bodi,* “Dissociative photoionization of dimethyl carbonate: the more it is cut, the bigger the fragment ion”, J. Phys. Chem. A 121 (2017), 2748.
6. X. Wu, Z. Gao, T. Yu, X. Zhou,* and S. Liu, “S(3P) fragmentation channel of carbonyl sulfide at 230 nm”, Acta Phys. –Chim. Sin. 33 (2017), 2004.
5. Y. Chen,# X. Wu,# T. Yu, X. Zhou,* B. Yan,* S. Liu, “Theoretical re-investigation on the N–N bond breaking of N2O+ cations in the A2Σ+ and B2Π states at the CASPT2 level”, Chem. Phys. Lett. 831 (2023), 140857.
4. Z. Zhang, Q. Li, X. Wu, C. Bourmaud, D. G.Vlachos,* J. Luterbacher,* A. Bodi,* and P. Hemberger,* “A solution for 4-propylguaiacol hydrodeoxygenation without ring saturation” Nat. Commun. 15 (2024), 6630.
3. Z. Zhang, M. Vanni, X. Wu, P. Hemberger,* A. Bodi,* S. Mitchell, and J. Perez-Ramirez, “CO Cofeeding Affects Product Distribution in CH3Cl Coupling overZSM-5 Zeolite: Pressure Twists the Plot” Angew. Chem. Int. Ed. 63 (2024), e.202401060
2. Z. Zhang, J. Tian, X. Wu, I. Surin, J. Perez-Ramirez,* P. Hemberger,* and A. Bodi,* “Unraveling Radical and Oxygenate Routes in the Oxidative Dehydrogenation of Propane over Boron Nitride” J. Am. Chem. Soc. 145(2023), 7910.
1. Z. Pan, A. Puente-Urbina, S. Batool, A. Bodi, X. Wu, Z. Zhang, J. A. van Bokhoven,* P. Hemberger,* “Tuning the zeolite acidity enables selectivity control by suppressing ketene formation in lignin catalytic pyrolysis” Nat. Commun. 14 (2023), 4512.
