Interfacial charge transfer in a functionalized polyoxotitanate cluster
发表时间：2016-06-01
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- 摘要：
- Understanding the charge transfer processes at the dye/TiO2 interface is often modeled using catechol/TiO2 systems. However, it indeed require precise structural information. In order to simulate the dye/TiO2 systems at a molecular level, herein we report the synthesis and structure of a novel titanium oxo-cluster [Ti4O(OiPr)6(DTBC)4] (1) functionalized with 3,5-di-tert-butylcatechol (DTBC). UV–Vis spectroscopy, electron spin resonance (ESR), X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations show that 1 exhibits property of Ti(III) which is caused by subst
- 通讯作者：
- Jie Hou, Qun Zhang, Yufei Wu, Yuliang Liu, Lin Du, Chen-Ho Tung, Yifeng Wang
- 论文编号：
- 017
- 页面范围：
- 279-283
- 是否译文：
- 否
- 发表时间：
- 2016-06-01