摘要：

For sol–gel synthesis of titanium oxide, the titanium(IV) precursors are dissolved in water to form clear solutions. However, the solution status of titanium(IV) remains unclear. Herein three new and rare types of titanium oxo clusters are isolated from aqueous solutions of TiOSO4 and TiCl4 without using organic ligands. Our results indicate that titanium(IV) is readily hydrolyzed into oxo oligomers even in highly acidic solutions. The present clusters provide precise structural information for future characterization of the solution species and structural evolution of titanium(IV) in water an

通讯作者：

Guanyun Zhang, Jie Hou, Chen-Ho, Tung and Yifeng Wang

卷号：

55

期号：

7

页面范围：

3212–3214

是否译文：

否

发表时间：

2016-03-01