TiO2 Photocatalytic Cyclization Reactions for the Syntheses of Aryltetralones
发表时间：2016-10-01
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- 摘要：
- This work focuses on a new strategy to overcome the overoxidation in heterogeneous TiO2 photocatalysis and to realize high-efficiency photosynthesis. We demonstrate that TiO2 photocatalysis can integrate C–C and C═O formation in a tandem manner to achieve efficient oxidative cyclization for the syntheses of aryltetralones. This protocol does not need any additive besides the inexpensive and/or recyclable TiO2, O2, and (solar) light. High yields with excellent diastereoselectivities are obtained for a wide scope of electron-rich substrates. Our findings demonstrate that in contrast to the conve
- 通讯作者：
- Yuliang Liu, Mingfu Zhang, Chen-Ho Tung, and Yifeng Wang*
- 是否译文：
- 否
- CN号：
- https://pubs.acs.org
- 发表时间：
- 2016-10-01