摘要：

By using solubility control to crystallize the prenucleation clusters of hydrosol, a family of titanium-oxo clusters possessing the {Ti18O27} core in which the 18 Ti(IV)-ions are uniquely connected with μ-oxo ligands into a triple-decked pentagonal prism was obtained. The cluster cores are wrapped by external sulfate and aqua ligands, showing good solubilities and stabilities in a variety of solvents including acetonitrile and water and allowing their solution chemistry being studied by means of electrospray ionization mass spectroscopy, 17O NMR, and vibrational spectroscopy. Furthermore, this

通讯作者：

Guanyun Zhang, Caiyun Liu, De-Liang Long, Leroy Cronin, Chen-Ho Tung, and Yifeng Wang*

卷号：

138

期号：

35

页面范围：

11097–11100

是否译文：

否

发表时间：

2016-08-01