Scientific Research
个人简介
姓名:孔令兵
中组部青年拔尖人才、泰山学者青年专家,山东大学齐鲁青年学者
出生年月:1984年9月
学历:博士研究生
职称:教授
单位:有机化学研究所
研究方向:有机硼化学
地址:山东省济南市山东大学中心校区生命北楼516
Email: konglb@sdu.edu.cn
常年招收博士后和科研助理,欢迎联系。
学习及工作经历
2017. 11 – 至今 山东大学 教授
2012. 07 – 2016. 08 新加坡南洋理工大学 博士后 导师:Prof. Rei Kinjo
2007. 09 – 2012. 06 南开大学 博士 导师:崔春明教授
2002. 09 – 2007. 07 聊城大学 学士
研究领域和兴趣
不饱和硼化学
亲核性硼化学
功能硼杂共轭体系的构建
主要论著
近三年工作概览:https://www.x-mol.com/news/775847
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31. Yuyang Dai, Yu Wang, Liliang Wang,* Fan Qi,* Qianli Li, and Lingbing Kong*. Crystalline potassium boryl dithiolate and diselenolate. Chem. Commun. 2024, DOI: 10.1039/D4CC05240D.
30. Yu Mu, Yuyang Dai, David A. Ruiz, Liu Leo Liu, Li-Ping Xu,* Chen-Ho Tung, and Lingbing Kong*. Aromatic 1,4,2,3-Diazadiborole Featuring an Unsymmetrical B=B Entity: A Versatile Synthon for Unusual Boron Heterocycles. Angew. Chem. Int. Ed. 2024, 63, e202405905.
29. Xin Zhang, Hongyu Wang, Lingbing Kong*, and Liu Leo Liu*. Carbene-Stabilized Aluminacyclopropene-Cyclopropenylalane Rearrangement. Organometallics 2024, 43, 2392. (Front Cover)
28. Xiaofeng Mao,‡ Shuang Qiu,‡ Rui Guo, Yuyang Dai, Jie Zhang, Lingbing Kong*, and Zuowei Xie*. Cyclic (Alkyl)(Amino)Carbene-Iminoboryl Compounds with Three Formal Oxidation States. J. Am. Chem. Soc. 2024, 146, 10917. (‡Equal contribution)
27. Jixing Han, Chaopeng Hu, Qianli Li, Liu Leo Liu,* Chen-Ho Tung, Ping Cui,* and Lingbing Kong*. Derivatization of an Alkylideneborane with B=C Bond Cleavage. Inorg. Chem. 2023, 62, 18820.
26. Rui Guo, Chaopeng Hu, Qianli Li, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. BN Analogue of Butadiyne: A Platform for Dinitrogen Release and Reduction. J. Am. Chem. Soc. 2023, 145, 18767. (Highlighted by ChemistryViews: An Isolable Diiminoborane.)
25. Weiwei Lv, Yuyang Dai, Rui Guo, Yuanting Su,* David A. Ruiz, Liu Leo Liu, Chen-Ho Tung, and Lingbing Kong*. Geometrically Constrained Organoboron Species as Lewis Superacids and Organic Superbases. Angew. Chem. Int. Ed. 2023, 62, e202308467. (Selected as a HOT Paper by Angew. Chem.)
24. Shuang Qiu , Xin Zhang, Chaopeng Hu, Hongxu Chu, Qianli Li, David A. Ruiz, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. Unveiling Hetero-Enyne Reactivity of Aryliminoboranes: Dearomative Hetero-Diels-Alder-Like Reactions. Angew. Chem. Int. Ed. 2022, 61, e202205814. (Selected as a HOT Paper by Angew. Chem.)
23. Yu Wang, Xin Zhang, Jixing Han, Qianli Li, Rui Wei, David A. Ruiz, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. Crystalline Neutral Diboron Analogues of Cyclopropanes. Angew. Chem. Int. Ed. 2022, 61, e202117053. (Selected as a HOT Paper by Angew. Chem. Highlighted by ChemistryViews: Neutral Diboron Analogues of Cyclopropanes.)
22. Rui Guo, Xin Zhang, Tong Li, Qianli Li, David A. Ruiz, Liu Leo Liu, Chen-Ho Tung, and Lingbing Kong*. Unraveling the Reactivity of a Cationic Iminoborane: Avenues to Unusual Boron Cations. Chem. Sci. 2022, 13, 2303.
21. Yonghao Fan,Jingjing Cui,* and Lingbing Kong*. Recent Advances in the Chemistry of Iminoborane Derivatives. Eur. J. Org. Chem. 2022, e202201086. ('Boron Chemistry' Collection. Invited Review)
20. Ping Cui, Hao Gao, Yu Wang, Chen-Ho Tung, and Lingbing Kong*. The Cation-π Interactions in a Potassium Alkylideneborane Complex. Eur. J. Inorg. Chem. 2022, e202200400. (Part of the “EurJIC Talents” Special Collection.)
19. Ping Cui, Yu Mu, Hao Gao, Lingbing Kong*, and Chunming Cui. Bulky lithium amides for para-elementation of secondary m-terphenylamines. J. Organomet. Chem. 2022, 959, 122205.
18. Rui Guo, Tong Li, Rui Wei, Xin Zhang, Qianli Li, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. Boraiminolithium: An Iminoborane-Transfer Reagent. J. Am. Chem. Soc. 2021, 143, 13483. (Highlighted by ChemistryViews: Boraiminolithium Compound Can Transfer B≡N Units)
17. Hao Gao, Qianli Li, Ping Cui, Chen-Ho Tung, and Lingbing Kong*. Facile Access to Alkylideneborane and Diborabutadiene N-Heterocyclic Carbene Complexes. Inorg. Chem. 2021, 60, 8432. (Virture collections: Early-Career Researchers in Organic and Inorganic Chemistry)
16. Lingbing Kong* and Chunming Cui*. Perspective of Organoboron Chemistry. Synlett. 2021, 32, 1316. (Invited Perspective).
14. Rui Guo, Jingxing Jiang, Chenyang Hu, Liu Leo Liu, Ping Cui, Meihua Zhao, Zhuofeng Ke,* Chen-Ho Tung and Lingbing Kong*. BNN-1,3-dipoles: Isolation and Intramolecular Cycloaddition with Unactivated Arenes. Chem. Sci. 2020, 11, 7053. (2020 Chemical Science HOT Article Collection)
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7. Lingbing Kong, Rakesh Ganguly, Yongxin Li and Rei Kinjo*. Diverse Reactivity of A Tricoordinate Organoboron L2PhB: (L=oxazol-2-ylidene) towards Alkali Metal, Group 9 Metal, and Coinage Metal Precursors. Chem. Sci. 2015, 6, 2893. (Selected as one of the TOP 25 most downloaded articles between Apr-Jun 2015)
5. Liliang Wang,‡ Lingbing Kong,‡ Yongxin Li, Rakesh Ganguly and Rei Kinjo*. Anti-Markovnikov Hydroimination of Terminal Alkynes in Gold-Catalyzed Pyridine Construction using Ammonia. Chem. Commun. 2015, 12419. (‡Equal contribution)
4. Lingbing Kong, Yongxin Li, Rakesh Ganguly, Dragoslav Vidovic and Rei Kinjo*. Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile. Angew. Chem. Int. Ed. 2014, 53, 9280. (Selected as a HOT Paper by Angew. Chem.).
科研项目
主持国家自然科学基金4项,省部级校级项目7项。
1. 国家自然科学基金面上项目,22471142,主持,2025.1–2028.12.
2. 国家自然科学基金面上项目,22271174,主持,2023.1–2026.12.
3. 国家自然科学基金面上项目,21971144,主持,2020.1–2023.12.
4. 国家自然科学基金青年项目,21702228,主持,2018.1–2020.12.
5. 山东省重点研发计划(公益类专项),2019GGX102032,主持,2019.12–2021.12.
6. 山东省自然科学基金面上项目, ZR2017MB021,主持,2017.8–2020.6.
7. 齐鲁青年学者特聘教授启动经费,主持,2017–2022.
8. 南开大学元素有机化学国家重点实验室开放基金,201808,主持,2019.1-2019.12.
9. 南开大学元素有机化学国家重点实验室开放基金,202102,主持,2022.1-2022.12.
10. 山东省自然科学基金重大基础研究项目,ZR2019ZD46,核心成员,2019.12-2024.12.
11. 山东大学青年交叉科学创新群体,2020QNQT007,核心成员,2020.1-2023.12.
科研成果
聚焦硼杂不饱和体系的合成新方法开发、新结构创制以及新应用探索等方面,通过合理设计,成功开发了高效硼杂不饱和键构建新方法,并将其成功应用于非环共轭不饱和硼体系的构筑;稳定分离了离子型亚胺硼烷化合物,并系统研究了它们的基元反应性;通过硼杂烯烃的重排反应合成了中性二硼杂环丙烷类似物;发现BNN-1,3-偶极子在室温下即可完成对苯环的去芳构化偶极环加成反应。
代表性成果一:离子型亚胺硼烷的合成、表征及应用研究
利用大位阻芳基配位稳定了高活性的阴离子型亚胺硼烷(硼杂亚胺锂盐),发现了其硼氮三键转移功能 (J. Am. Chem. Soc. 2021, 143, 13483.); ii. 合成了高活性可分离的阳离子型亚胺硼烷(亚氨基硼正离子),揭示了其多重键和路易斯酸性硼中心双重反应位点 (Chem. Sci. 2022, 13, 2303.)。
代表性成果二:中性二硼杂环丙烷类似物的合成与性质研究
合成表征了中性二硼杂环丙烷类似物,探明了其范特霍夫-勒贝尔 (van’t Hoff-Le Bel) 构型,揭示了亲电开环、亲核开环、氢化开环以及氧化官能化等基元反应行为 (Angew. Chem. Int. Ed. 2022, 61, e202117053.)。
代表性成果三:硼杂不饱和键构筑新方法及应用拓展
开发了一步实现孤立硼杂多重键构筑和稳定的新方法 (Inorg. Chem. 2021, 60, 8432; Inorg. Chem. 2020, 59, 5261; Inorg. Chem. 2019, 58, 13370.),并将其成功拓展到新型硼杂共轭不饱和体系的构建,制备了BNN-1,3-偶极子 (Chem. Sci. 2020, 11, 7053; Chem. Commun. 2021, 57, 1226.), BNNB-, NBBN-, CNBC-以及CNBN-五个1,3-硼杂共轭体系。