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发表刊物：
Journal of the Energy Institute
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关键字：
Co-pyrolysis; Waste biomass; Dechlorinated polyvinyl chloride; Synergistic effec
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摘要：
With the combination of stepwise dechlorination and co-pyrolysis techniques, this study conducted polyvi-nyl chloride (PVC) dechlorination experiments and co-pyrolysis experiments of poplar wood (PW) with dechlorinated polyvinyl chloride (DPVC) by thermogravimetric analysis and a fixed bed reactor. Stepwise pyrolysis effectively removed Cl from PVC with a dechlorination efficiency of 99.84% at 360 °C for 30 minutes. Thermogravimetric tests and thermokinetic variables were employed to describe the co-pyrolysis process's thermodynamic behavior, where co-pyrolysis significantly diminished the activation energy of the initial pyrolysis stage (9.65-21.62 kJ/mol) and increased the reaction rate (0.02-0.09 %/°C). The synergistic effect of co-pyrolysis enhanced the yield and quality of liquid oil and reduced the solid residue rate, with the maximum change in solid residue rate (-2.36%) occurring at PW:DPVC=3:7. The optimal conditions for the synergistic effect are a raw material ratio of 3:7 at 500 °C. Co-pyrolysis efficiently reduced the content of oxygen-containing compounds of phenols, ketones, and acids in oil, and elevated the selectivity of aromat-ics. The research methods avoid the drawbacks of bio-oil and plastic oil and improve the quality of pyrolysis oil in a concise and efficient manner, which provides some new ideas for the resource and clean utilization of municipal waste.
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全部作者：
Jie Zhu,Jie Geng,Jisen Liu,Kuihua Han,Yongzheng Wang,Sunwen Xia
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第一作者：
Zihao Yang
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论文类型：
期刊论文
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通讯作者：
Shengli Niu* (* the corresponding author)
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学科门类：
工学
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一级学科：
动力工程及工程热物理
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文献类型：
J
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卷号：
117
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页面范围：
101819
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是否译文：
否
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发表时间：
2024-09-01
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收录刊物：
SCI
