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Quantitative study on fast kinetics of hydrodynamic liquid absorption of CO2 microbubbles enabled by microfluidic visualization and computational fluid dynamics method
发布时间：2025-11-04
  • 发表刊物：
    Analytical Chemistry
  • 关键字：
    Liquid absorption, CO2 microbubbles, microfluidics, absorption efficiency, mass transfer
  • 摘要：
    Liquid absorption is one of the mainstream approaches to carbon capture in response to the global warming crisis. Its performance is fundamentally subjected to the interphase mass transfer whose kinetics are determined and regulated by various factors including absorbent types, surface-to-volume ratios, and transfer distance, etc. Here, we report on a quantitative study of the fast kinetics of hydrodynamic liquid absorption of CO2 microbubbles. In a microfluidic platform, three types of aqueous absorbents, namely, isophorone diamine (IPDA), monoethanolamine (MEA), and potassium hydroxide (KOH) are utilized as a continuous fluidic phase for absorbing gaseous CO2 dispersed into flow-focused channels and a train of microbubbles are formed. The flowing bubbles are visualized using an inverted microscope equipped with a high-speed camera. Their velocity and morphology are then quantitatively analyzed. The results show that the size of CO2 bubbles decreases rapidly within 100 miliseconds since the contact with the absorbent and is approaching equilibrium at a constant minimum size. Overall, the volume shrinkage and the translated mass loss can be up to 99% within 200 ms. Absorption efficiency (mm/s), defined as the volume change of a gas bubble with unit cubic meter per unit surface area and per unit time, is positively correlated with the volume fraction (vol.%) of the absorbent in solution. Yet as the latter reaches 20%, no differences in the absorption efficiency among the absorbents are observed. Computational fluid dynamics analysis reveals that flow vortices are constantly formed in both the bubbles and the liquid solution slug. The local convection of the fluid elements near the gas-liquid interface dominates over diffusion in the mass transfer of the gas molecules (Peclet number: 25,000- 42,500). Intensified convection-diffusion processes near the interface strongly contributes to enhancing the dissolution of CO2. Our findings are firm evidence that engineered mini bubbles flowing in liquid solution can drastically expedite the interphase mass transfer as well as the associated chemical processes.
  • 第一作者：
    Qinglin Chen,Zhennan He
  • 通讯作者：
    Ning Qin,Pei Zhao
  • 全部作者：
    Yinglong Zhang,Jie Hu,Bo Liu,Zeyad Almutairi,Gongming Xin
  • 论文类型：
    期刊论文
  • 卷号：
    97
  • 期号：
    45
  • 页面范围：
    24984-24994
  • 影响因子：
    6.7
  • DOI码：
    10.1021/acs.analchem.5c03041
  • 是否译文：
    否
  • 发表时间：
    2025-11
  • 收录刊物：
    SCI
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