王文光 

1982年出生，教授，博士生导师，高层次青年人才

电话：0531-88365545

E-mail: wwg@sdu.edu.cn

地址：老数学楼101-2

课题组主页：http://faculty.sdu.edu.cn/WWGgroup/en/index/924429/list/index.htm

研究领域：

有机光化学，金属有机化学, 物理有机化学

研究兴趣：

1. 模拟生物金属酶如氢化酶、固氮酶等活性中心的催化过程

2. 研究模型配合物的反应活性及相关反应过程与机制，旨在发展反应条件温和、高效的均相催化转化体系

科研项目：

1. “基于金属Fe配合物为催化剂的光催化加氢体系”, 国家自然科学基金（青年项目21402107），2015-2017

2. “基于高效电子、质子和能量迁移的功能组装体”，国家自然科学基金（国家重大研究计划-集成项目91427303），2015-2017

3. “基于金属Fe配合物为催化剂的水氧化产氧体系”，山东省自然科学基金（面上项目，ZR2014BM011），2015-2017

4. “廉价金属-配体协同催化剂的设计及其催化的有机反应”，国家自然科学基金 （面上项目，21871166），2019-2022

拟招收研究生情况：

欢迎感兴趣的同学参观或加入本课题组。我们与中国科学院理化技术研究所光化学转换与功能材料实验室、美国伊利诺伊大学香槟分校（UIUC）化学系Thomas B. Rauchfuss 教授等有良好的合作关系。

发表论文：

2020年

[1] Maofu Pang, Jia-Yi Chen, Shengjie Zhang, Ron-Zhen Liao*, Chen-Ho Tung, Wenguang Wang*, “Controlled partial transfer hydrogenation of quinolines by cobalt-amido cooperative catalysis” Nature Communications 2020, 11 (1), 1249.

[2] Xiangyu Liu, Heng Song, Xiaofang Zhai,  Chen-Ho Tung, Wenguang Wang*, “Cobalt-catalyzed regioselective hydrohydrazination of epoxides” Organic & Biomolecular Chemistry 2020, 18 (8), 1572-1576.

2019年

[1] Shu-Fen Hou, Jia-Yi Chen, Minghui Xue, Mengjing Jia, Xiaofang Zhai, Ron-Zhen Liao*, Chen-Ho Tung, Wenguang Wang*, “Cooperative Molybdenum-Thiolate Reactivity for Transfer Hydrogenation of Nitriles”, 

ACS Catal., 2019, doi:10.1021/acscatal.9b04455.

[2] Heng Song, Zhuoyi Yang, Chen-Ho Tung, Wenguang Wang*, “Iron-Catalyzed Reductive Coupling of Nitroarenes with Olefins: Intermediate of Iron-Nitroso Complex”, ACS Catal., 2019, doi:10.1021/acscatal.9b03604.

[3] Xuewen Zhuang,  Jia-Yi Chen, Zhuoyi Yang, JMengjing Jia,  Chengjuan Wu, Ron-Zhen Liao*, Chen-Ho Tung, Wenguang Wang*, “Sequential Transformation of Terminal Alkynes to 1,3-Dienes by a Cooperative Cobalt Pyridonate Catalyst”, Organometallics 2019, 38, 3752-3759.

[4] Shengnan Zhang,  Yike Song, Xueshan He, Raja Angamuthu*,  Chen-Ho Tung, Wenguang Wang*, “Reductive Coupling of Bridging Diaryl Ligands in Half-Sandwich Cobalt(II) Dimers: Revisiting Triple-Decker Cobalt(I) Complexes”, Organometallics 2019, 38, 3610-3616.

[5] Jianguo Liu, Jiayi Chen, Mengjing Jia, Bangrong Ming, Jiong Jia, Rong-Zhen Liao*, Chen-Ho Tung and Wenguang Wang*, “Ni-O Cooperation versus Nickel(II) Hydride in Catalytic Hydroboration of N-Heteroarenes”, ACS Catal., 2019, 9, 3849-3857.

[6] Xiaoxiao Chu, Jihao Jin, Bangrong Ming, Maofu Pang, Xin Yu, Chen-Ho Tung, Wenguang Wang*, “Bimetallic Nickel–Cobalt Hydrides in H₂ Activation and Catalytic Proton Reduction”, Chem. Sci., 2019, 10, 761-767

[7] Zhennan Yang, Maofu Pang, Shu-Guang Xia, Xiao-Ya Gao, Qing Guo, Xu-Bing Li, Chen-Ho Tung, Li-Zhu Wu*, Wenguang Wang*, “Catalytic Hydrogen Production Using a Cobalt Catalyst Bearing a Phosphinoamine Ligand”, ChemPhotoChem, 2019, 3, 220-224..

2018年

[1] Xin Yu, Maofu Pang, Shengnan Zhang, Xinlong Hu, Chen-Ho Tung, Wenguang Wang*, “Terminal Thiolate-Dominated H/D Exchanges and H₂ Release: Diiron Thiol–Hydride”, J. Am. Chem. Soc., 2018, 140, 11454-11463.

[2] Ailing Zhang, Congxiao Wang, Xiaoyu Lai, Xiaofang Zhai, Maofu Pang, Chen-Ho Tung, Wenguang Wang*, “Reactivity of the Diphosphinodithio Ligated Nickel(0) Complex toward Alkyl Halides and Resultant Nickel(I) and Nickel(II)–Alkyl Complexes”, Dalton Trans., 2018, 47, 15757-15764.

[3] Xiangyu Liu, Chengjuan Wu*, Jing Zhang, Yihan Shi, Shengnan Zhang, Yan Geng, Chen-Ho Tung, Wenguang Wang*, “Cobalt-Catalyzed Radical Cyclization of Isocyanides Forming Phenanthridine Derivatives”, Org. Chem. Front., 2018, 5, 2997-3002.

[4] Maofu Pang, Chengjuan Wu, Xuewen Zhuang, Fanjun Zhang, Mincong Su, Qingxiao Tong*, Chen-Ho Tung, Wenguang Wang*, “Addition of a B–H Bond across an Amido–Cobalt Bond: Co^II–H-Catalyzed Hydroboration of Olefins”, Organometallics, 2018, 37, 1462-1467.

[5] Yingjie Zhao, Xin Yu, Huilan Hu, Xinlong Hu, Sakthi Raje, Raja Angamuthu, Chen-Ho Tung, Wenguang Wang*, “Synthetic [FeFe]-H₂ase Models Bearing Phosphino Thioether Chelating Ligands”, Chin. Chem. Lett., 2018, 29, 1651-1655.

[6] Jianguo Liu, Ailing Zhang, Heng Song, Qingxiao Tong*, Chen-Ho Tung, Wenguang Wang*, “Iron(II) Hydrides Bearing a Tetradentate PSNP Ligand”, Chin. Chem. Lett., 2018, 29, 949-953.

2017年

[1] Fanjun Zhang, Heng Song, Xuewen Zhuang, Chen-Ho Tung, Wenguang Wang*, “Iron-Catalyzed 1,2-Selective Hydroboration of N-Heteroarenes”, J. Am. Chem. Soc., 2017, 139, 17775-17778.

[2] Heng Song, Ke Ye, Peiyu Geng, Xiao Han, Rongzhen Liao*, Chen-Ho Tung, Wenguang Wang*, “Activation of Epoxides by a Cooperative Iron–Thiolate Catalyst: Intermediacy of Ferrous Alkoxides in Catalytic Hydroboration”, ACS Catal., 2017, 7709-7717.

[3] Xiaoxiao Chu, Xin Yu, Sakthi Raje, Raja Angamuthu, Jianping Ma, Chen-Ho Tung, Wenguang Wang*, “Synthetic [NiFe] Models with a Fluxional Co Ligand”, Dalton Trans., 2017, 46, 13681-13685.

[4] Ailing Zhang, Sakthi Raje, Jianguo Liu, Xiaoyan Li, Raja Angamuthu, Chen-Ho Tung, Wenguang Wang*, “Nickel-Mediated Stepwise Transformation of CO to Acetaldehyde and Ethanol”, Organometallics, 2017, 36, 3135-3141.

[5] Xin Yu, Chen-Ho Tung, Wenguang Wang*, Mioy T. Huynh, Danielle L. Gray, Sharon Hammes-Schiffer*, Thomas B. Rauchfuss*, “Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States”, Organometallics, 2017, 36, 2245-2253.

[6] Jia-Heng Xu, Ling-Yu Guo, Hai-Feng Su, Xiang Gao, Xiao-Fan Wu, Wen-Guang Wang*, Chen-Ho Tung, Di Sun*, “Heptanuclear Co^II₅Co^III₂ Cluster as Efficient Water Oxidation Catalyst”, Inorg. Chem., 2017, 56, 1591-1598.

[7] Fanjun Zhang, Xin Xu, Yingjie Zhao, Jiong Jia, Chen-Ho Tung, Wenguang Wang*, “Solvent Effects on Hydride Transfer from Cp*(P-P)FeH to BNA⁺ Cation”, Organometallics, 2017, 36, 1238-1244.

[8] Xiaoxiao Chu, Xin Xu, Hao Su, Sakthi Raje, Raja Angamuthu, Chen-Ho Tung, Wenguang Wang*, “Heteronuclear Assembly of Ni–Cu Dithiolato Complexes: Synthesis, Structures, and Reactivity Studies”, Inorg. Chem. Front., 2017, 4, 706-711.

[9] Ran Li, Wenyuan Xu, Jinqin Zhao, Xin Yu, Wenguang Wang*, Chen-Ho Tung, “Azo-bridged New Diiron Carbonyl Complex: Synthesis of Fe₂(NR)₂(CO)_6-x(PR₃)_x and the Derivatives”, Acta Chimica Sinica., 2017, 75, 92-98.

2016年

[1] Jiaheng Xu, Zhi Wang, Wenguang Yu, Di Sun*, Qing Zhang, Chen-Ho Tung, Wenguang Wang*, “Kagóme Cobalt(II)-Organic Layers as Robust Scaffolds for Highly Efficient Photocatalytic Oxygen Evolution”, ChemSusChem, 2016, 9, 1146-1152.

[2] Jianguo Liu, Fanjun Zhang, Ailing Zhang, Qingxiao Tong*, Chen-Ho Tung, Wenguang Wang*, “New Class of Hydrido Iron(II) Compounds with cis-Reactive Sites: Combination of Iron and Diphosphinodithio Ligand”, Chem. Asian J., 2016, 11, 2271-2277.

[3] Fanjun Zhang, Jiong Jia, Shuli Dong, Wenguang Wang*, Chen-Ho Tung, “Hydride Transfer from Iron(II) Hydride Compounds to NAD(P)⁺ Analogues”, Organometallics, 2016, 35, 1151-1159.

2015年以前 (进入山大前）

[1] Wenguang Wang, Thomas B. Rauchfuss*, Lingyang Zhu, and Giuseppe Zampella*, “New Reactions of Terminal Hydrides on a Diiron Dithiolate”, J. Am. Chem. Soc., 2014, 136, 5773-5782.

[2] Wenguang Wang, Thomas B. Rauchfuss*, Curtis E. Moore, Arnold L. Rheingold*, Luca De Gioia, and Giuseppe Zampella*, “Crystallographic Characterization of a Fully Rotated, Basic Diiron Dithiolate: Model for the H_red State”, Chem. Eur. J. 2013, 19, 15476-15479.

[3] Wenguang Wang, Mark J. Nilges, Thomas B. Rauchfuss*, and Matthias Stein*, “Isolation of a Mixed Valence Diiron Hydride: Evidence for a Spectator Hydride in Hydrogen Evolution Catalysis”, J. Am. Chem. Soc. 2013, 135, 3633-3639.

[4] Wenguang Wang, Thomas B. Rauchfuss*, Luca Bertini, and Giuseppe Zampella, “Unsensitized Photochemical Hydrogen Production Catalyzed by Diiron Hydrides”, J. Am. Chem. Soc. 2012, 134, 4525-4528.

[5] Wen-Guang Wang, Feng Wang, Hong-Yan Wang, Chen-Ho Tung, and Li-Zhu Wu*, “Electron Transfer and Hydrogen Generation from a Molecular Dyad: Platinum(II) Alkynyl Complex Anchored to [FeFe] Hydrogenase Subsite Mimic”, Dalton Trans. 2012, 41 , 2420-2426.

[6] Wen-Guang Wang, Feng Wang, Hong-Yan Wang, Gang Si, Chen-Ho Tung, and Li-Zhu Wu*, “Photocatalytic Hydrogen Evolution by [FeFe] Hydrogenase Mimics in Homogeneous Solution”, Chem. Asian J. 2010, 5, 1796-1803.

[7] Wen-Guang Wang, Hong-Yan Wang, Gang Si, Chen-Ho Tung, and Li-Zhu Wu*, “Fluorophenyl-Substituted Fe-Only Hydrogenases Active Site ADT Models: Different Electrocatalytic Process for Proton Reduction in HOAc and HBF₄/Et₂O’, Dalton Trans. 2009, 2712-2720.