Alkali Halide Cubic Cluster Anions ([Cs8X27]19–, X = Cl, Br) Isolated from Water
Release time:2019-06-12
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- Abstract:
- A series of [Cs8X27]19− (X = Cl, Br) cubic cluster anions, which feature the structure of four unit cells of CsCl type, were obtained by precipitating the prenucleation octacesium chloride anionic clusters from water solutions and using [M4(OH)8(OH2)16]8+ (M = ZrIV or HfIV) as the counter cations to form intercluster compounds.
- Correspondence Author:
- Qing Sun, Guanyun Zhang, Chen-Ho Tung, and Yifeng Wang*
- Volume:
- 55
- Issue:
- 21
- Page Number:
- 11125–11130
- Translation or Not:
- no
- Date of Publication:
- 2016-10-01