 Publications
Highly stereoselective α-glycosylation with GalN3 donors enabled collective synthesis of mucin-related tumor associated carbohydrates antigens Kunxiu Shou, Yunqin Zhang, Yujie Ji, Bin Liu, Qingli Zhou, Qiang Tan, Fuying Li, Xiufang Wang, Gang Lu* and Guozhi Xiao*
Chem. Sci. 2024, Accepted Manuscript (Link)
Origin of site-selectivity of hydrogen atom transfer in carbohydrate C–H alkylations via photoredox catalysis Yujie Ji, Lingfei Hu, Han Gao, Yan-Bo Wu, Xiangying Lv* and Gang Lu*
Org. Chem. Front. 2024, Advance Article (Link)
Rhodium(I)-Catalyzed Asymmetric Hydroarylative Cyclization of 1,6-Diynes to Access Atropisomerically Labile Chiral Dienes Panjie Hu, Lingfei Hu, Xiao-Xi Li, Mengxiao Pan, Gang Lu,* and Xingwei Li*
Angew. Chem. Int. Ed. 2024, 63, e202312923. (Link)
Carbon-Bonding Metal Catalysis (CBMC): A Supramolecular Complex Directs Structural-Isomer Selection in Gold-Catalyzed Reactions Xinxin Li, Lingfei Hu, Gang Lu*, and Yao Wang*
J. Am. Chem. Soc. 2023, 145, 39, 21554–21561. (Link)
Deciphering the Timing of Naphthalenic Ring Formation in the Biosynthesis of 8-Deoxyrifamycins Feng Ye, Xia Zhao, Yanrong Shi, Yanlei Hu, Yanjiao Ding, Chunhua Lu, Yaoyao Li, Haoxin Wang, Gang Lu*, and Yuemao Shen*
Org. Lett. 2023, 25, 35, 6474–6478. (Link)
Nickel-catalysed enantioselective hydrosulfenation of alkynes Ya-Qian Zhang, Lingfei Hu, Liyan Yuwen, Gang Lu*, Qing-Wei Zhang*
Nat. Catal. 2023, DOI: 10.1038/s41929-023-00966-9. (Link)
Divergent Rh Catalysis: Asymmetric Dearomatization Versus C–H Activation Initiated by C–C Activation Xiaotong Li, Lingfei Hu, Shuo Ma, Haiyong Yu, Gang Lu*, Tao Xu*
ACS Catal. 2023, 13, 7, 4873–4881. (Link)
How hexafluoroisopropanol solvent promotes Diels–Alder cycloadditions: ab initio metadynamics simulations Xia Zhao, Xinmin Hu, Xiangying Lv, Yan-Bo Wu, Yuxiang Bu, Gang Lu*
Phys. Chem. Chem. Phys. 2023, 25, 14695–14699. (Link)
Ab Initio Metadynamics Simulations of Hexafluoroisopropanol Solvent Effects: Synergistic Role of Solvent H-Bonding Networks and Solvent-Solute C−H/π Interactions Xinmin Hu, Xia Zhao, Xiangying Lv, Yan-Bo Wu, Yuxiang Bu, Gang Lu* Chem. Eur. J. 2023, 29, e202203879. (Link)
Origins of Regioselectivity in CuH-Catalyzed Hydrofunctionalization of Alkenes Lingfei Hu, Han Gao, Yanlei Hu, Yan-Bo Wu, Xiangying Lv*, Gang Lu* J. Org. Chem. 2023, 88, 5, 2750–2757 (Link)
Mechanism of Co(iii)-catalyzed annulation of N-chlorobenzamide with styrene and origin of cyclopentadienyl ligand-controlled enantioselectivity Han Gao,‡ Wujie Wang,‡ Xiangying Lv, Gang Lu*, Yuliang Li* Org. Chem. Front. 2023, Advance Article (Link)
Weak Electrostatic Interactions with Bisphosphine Ligands Facilitate Reductive Elimination of PhCF3 from Pd(II) Complexes Han Gao, Lingfei Hu, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Chem. Asian J. 2023, 18, e202201219. (Link)
Stereoretentive Regio- and Enantioselective Allylation of Isoxazolinones by a Planar Chiral Palladacycle Catalyst Xin Yu, Lingfei Hu, Wolfgang Frey, Gang Lu*, René Peters* Angew. Chem. Int. Ed. 2022, e202210145. (Link)
Origins of regioselectivity in Ni-catalyzed hydrofunctionalization of alkenes via ligand-to-ligand hydrogen transfer mechanism Han Gao, Lingfei Hu, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Chem. Commun. 2022, 58, 8650-8653. (Link)
Computational insights into strain-increase allylborations for alkylidenecyclopropanes Lingfei Hu, Han Gao, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Chem. Commun. 2022, 58, 7034-7037. (Link)
Total synthesis of Lentinus giganteus glycans with antitumor activities via stereoselective α-glycosylation and orthogonal one-pot glycosylation strategies Yunqin Zhang, Yanlei Hu, Shanshan Liu, Haiqing He, Roujing Sun, Gang Lu*, Guozhi Xiao* Chem. Sci. 2022, 13, 7755-7764. (Link)
Site-Divergent Alkenyl C–H Fluoroallylation of Olefins Enabled by Tunable Rhodium Catalysis Yaxin Zeng, Han Gao, Yulei Zhu, Zhong-Tao Jiang, Gang Lu*, Ying Xia* ACS Catal. 2022, 12, 15, 8857-8867. (Link)
Computational study of Cu-catalyzed 1,2-hydrocarboxylation of 1,3-dienes with CO2: Pauli repulsion-controlled regioselectivity of Cu–Bpin additions Yanlei Hu, Lingfei Hu, Han Gao, Xiangying Lv, Yan-Bo Wu, Gang Lu* Org. Chem. Front. 2022, 9, 2240-2248. (Link)
Palladium-Catalyzed Stagewise Strain-Release-Driven C-C Activation of Bicyclo[1.1.1]pentanyl Alcohols Songjie Yu*, Yinan Ai, Lingfei Hu, Gang Lu*, Chunying Duan, Yue Ma Angew. Chem. Int. Ed. 2022, 61, e202200052. (Link)
Origins of regio- and stereoselectivity in Cu-catalyzed alkyne difunctionalization with CO2 and organoboranes Lingfei Hu, Han Gao, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Org. Chem. Front. 2022, 9, 1033-1039. (Link)
How electron-deficient Cp ligand facilitates Rh-catalyzed annulations with alkynes Han Gao, Lingfei Hu, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Org. Chem. Front. 2022, 9, 979-988. (Link)
Origin of Ligand Effects on Stereoinversion in Pd-Catalyzed Synthesis of Tetrasubstituted Olefins Lingfei Hu, Han Gao, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* J. Org. Chem. 2021, 86, 24, 18128-18138. (Link)
Multiple Reaction Pathways of Eight-Membered Rhodacycles in Rh-Catalyzed Annulations of 2-Alkenyl Phenols/Anilides with Alkynes Tao Liu*, Lingli Han, Jing Zhang*, Gang Lu* J. Org. Chem. 2021, 86, 15, 10484-10491. (Link)
Electrostatic repulsion-controlled regioselectivity in nitrene-mediated allylic C–H amidations Fang Huang*, Xiaoxiao Tian, Fangao Hou, Yaping Xu, Gang Lu* Org. Chem. Front. 2021, 8, 6038-6047. (Link)
Rh-Catalyzed Cascade C–C/Colefin–H Activations and Mechanistic Insight Yuxi Wang, Bo Qiu, Lingfei Hu, Gang Lu*, Tao Xu* ACS Catal. 2021, 11, 15, 9136-9142. (Link)
Origins of Lewis acid acceleration in nickel-catalysed C–H, C–C and C–O bond cleavage Han Gao, Lingfei Hu, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Catal. Sci. Technol. 2021, 11, 4417-4428. (Link)
Computational study of silver-catalyzed stereoselective hydroalkylation of alkynes: Pauli repulsion controlled Z/E selectivity Lingfei Hu, Han Gao, Yanlei Hu, Xiangying Lv, Yan-Bo Wu, Gang Lu* Chem. Commun. 2021, 57, 6412-6415. (Link)
Merging Reagent Modulation and Remote Anchimeric Assistance for Glycosylation: Highly Stereoselective Synthesis of α-Glycans up to a 30-mer Yunqin Zhang, Dr. Haiqing He, Zixi Chen, Yingying Huang, Guisheng Xiang, Penghua Li, Xingkuan Yang, Gang Lu*, Guozhi Xiao* Angew. Chem. Int. Ed. 2021, 60, 22, 12597-12606. (Link)
Para‐Selective Cyanation of Arenes by H‐Bonded Template Sandeep Pimparkar, Trisha Bhattacharya, Arun Maji, Argha Saha, Ramasamy Jayarajan, Uttam Dutta, Gang Lu*, David W Lupton*, Debabrata Maiti* Chem. Eur. J. 2020, 26, 11558-11564. (Link) Density Functional Theory Mechanistic Study of Ni-Catalyzed Reductive Alkyne–Alkyne Cyclodimerization: Oxidative Cyclization versus Outer-Sphere Proton Transfer Xiaojian Ren, Yu Lu, Gang Lu*, Zhi-Xiang Wang* Org. Lett. 2020, 22, 6, 2454–2459. (Link)
Ruthenium-Catalyzed Reductive Cleavage of Unstrained Aryl–Aryl Bonds: Reaction Development and Mechanistic Study Jun Zhu, Peng-hao Chen, Gang Lu*, Peng Liu*, Guangbin Dong* J. Am. Chem. Soc. 2019, 141, 46, 18630-18640. (Link)
Chiral acid-catalysed enantioselective C−H functionalization of toluene and its derivatives driven by visible light Fuyuan Li, Dong Tian, Yifan Fan, Richmond Lee, Gang Lu, Yanli Yin, Baokun Qiao, Xiaowei Zhao, Ziwei Xiao and Zhiyong Jiang* Nat. Commun. 2019, 10, 1774. Catalytic enantioselective oxidative coupling of saturated ethers with carboxylic acid derivatives Gang Wang, Xiaodong Xin, Zehua Wang, Gang Lu, Yudao Ma and Lei Liu* Nat. Commun. 2019, 10, 559. Computational exploration of substrate and ligand effects in nickel-catalyzed C–Si bond carboxylation with CO2 Xiangying Lv*, Xiaotian Zhang, Rongjian Sa*, Fang Huang and Gang Lu* Org. Chem. Front. 2019, 6, 3629–3635. (Link)
Selected publications before SDU: 30) Tuning the Reactivity of Cyclopropenes from Living Ring‐Opening Metathesis Polymerization (ROMP) to Single‐Addition and Alternating ROMP Jessica K. Su, Zexin Jin, Rui Zhang, Gang Lu, Peng Liu* and Yan Xia* Angew. Chem. Int. Ed. 2019, 58, 17771–17776. 29) On The Kinetics and Inverse Temperature-Dependence of a Tsuji-Trost Reaction in Aqueous Buffer Ivanna Pohorilets, Ivanna Pohorilets, Matthew Patrick Tracey, Michael J LeClaire, Emily M Moore, Gang Lu, Peng Liu* and Kazunori Koide* ACS Catal. 2019, 9, 12, 11720–11733. 28) "Issues Particular to Organometallic Reactions" in "Applied Theoretical Organic Chemistry" Gang Lu, Huiling Shao, Humair Omer and Peng Liu* World Scientific, 2018. (Book Chapter) 27) A general strategy for synthesis of cyclophane-braced peptide macrocycles via palladium-catalysed intramolecular sp3 C−H arylation Xuekai Zhang, Gang Lu, Meng Sun, Madhu Mahankali, Yanfei Ma, Mingming Zhang, Wangde Hua, Yuting Hu, Qingbing Wang, Jinghuo Chen, Gang He*, Xiangbing Qi*, Weijun Shen*, Peng Liu* and Gong Chen* Nat. Chem. 2018, 10, 540–548. 26) Modular ipso/ortho Difunctionalization of Aryl Bromides via Palladium/Norbornene Cooperative Catalysis Zhe Dong, Gang Lu, Jianchun Wang, Peng Liu* and Guangbin Dong* J. Am. Chem. Soc. 2018, 140, 8551–8562. 25) H-Bonded Reusable Template Assisted para-Selective Ketonisation using Soft Electrophilic Vinyl Ethers Arun Maji, Amit Dahiya, Gang Lu, Trisha Bhattacharya, Massimo Brochetta, Giuseppe Zanoni*, Peng Liu* and Debabrata Maiti* Nat. Commun. 2018, 9, 3582. 24) Origin of ligand effects on reactivities of pincer-Pd catalyzed hydrocarboxylation of allenes and alkenes with formate salts: a computational study Xiangying Lv, Fang Huang, Yan-Bo Wu and Gang Lu* Catal. Sci. Technol. 2018, 8, 2835–2840. 23) Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins Gang Lu, Richard Y. Liu, Yang Yang, Cheng Fang, Daniel S. Lambrecht*, Stephen L. Buchwald* and Peng Liu* J. Am. Chem. Soc. 2017, 139, 16548–16555. 22) Computational exploration of ligand effects in copper-catalyzed boracarboxylation of styrene with CO2 Xiangying Lv, Yan-Bo Wu and Gang Lu * Catal. Sci. Technol. 2017, 7, 5049–5054. 21) Computational studies on the Rh-catalyzed carboxylation of a C(sp2)–H bond using CO2 Xiangying Lv, Linhui Zhang, Beibei Sun, Zhi Li, Yan-Bo Wu and Gang Lu* Catal. Sci. Technol. 2017, 7, 3539–3545. 20) Tridentate Directing Groups Stabilize 6-Membered Palladacycles in Catalytic Alkene Hydrofunctionalization Miriam L. O'Duill, Rei Matsuura, Yanyan Wang, Joshua L. Turnbull, John A. Gurak, Jr., De-Wei Gao, Gang Lu, Peng Liu* and Keary M. Engle* J. Am. Chem. Soc. 2017, 139, 15576–15579. 19) NHC Ligands Tailored for Simultaneous Regio- and Enantiocontrol in Nickel-Catalyzed Reductive Couplings Hengbin Wang, Gang Lu, Grant J. Sormunen, Hasnain A. Malik, Peng Liu* and John Montgomery* J. Am. Chem. Soc. 2017, 139, 9317–9324. 18) Computationally-Guided Catalyst Design in the Type I Dynamic Kinetic Asymmetric Pauson−Khand Reaction of Allenyl Acetates Lauren C. Burrows, Luke T. Jesikiewicz, Gang Lu, Steven J. Geib, Peng Liu* and Kay M. Brummond* J. Am. Chem. Soc. 2017, 139, 15022–15032. 17) Computational Evidence for Lewis Base-Promoted CO2 Hydrogenation to Formic Acid on Gold Surfaces Xiangying Lv, Gang Lu*, Zhi-Qiao Wang, Zhong-Ning Xu* and Guo-Cong Guo* ACS Catal. 2017, 7, 4519–4526. 16) A Photoswitchable Olefin Metathesis Catalyst Aaron J. Teator, Huiling Shao, Gang Lu, Peng Liu* and Christopher W. Bielawski* Organometallics 2017, 36, 490–497. 15) A Ring-Opening Metathesis Polymerization Catalyst That Exhibits Redox-Switchable Monomer Selectivities Dominika N. Lastovickova, Huiling Shao, Gang Lu, Peng Liu* and Christopher W. Bielawski* Chem. Eur. J. 2017, 23, 5994–6000. 14) Catalytic activation of carbon–carbon bonds in cyclopentanones Ying Xia, Gang Lu, Peng Liu* and Guangbin Dong* Nature 2016, 539, 546–550. 13) Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones Yang Yang, Ian B. Perry, Gang Lu, Peng Liu* and Stephen L. Buchwald* Science 2016, 353, 144–150. 11) Benzazetidine synthesis via palladium-catalysed intramolecular C−H amination Gang He*, Gang Lu, Zhengwei Guo, Peng Liu* and Gong Chen* Nat. Chem. 2016, 8, 1131–1136. 10) Reductive Lithiation in the Absence of Aromatic Electron Carriers. A Steric Effect Manifested on the Surface of Lithium Metal Leads to a Difference in Relative Reactivity Depending on Whether the Aromatic Electron Carrier Is Present or Absent Nicole Kennedy*, Gang Lu, Peng Liu* and Theodore Cohen* J. Org. Chem. 2015, 80, 8571–8582. 9) Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C–C Bond Functionalization of Benzocyclobutenones Gang Lu, Cheng Fang, Tao Xu, Guangbin Dong and Peng Liu* J. Am. Chem. Soc. 2015, 137, 25, 8274–8283. 8) Origins of Initiation Rate Differences in Ruthenium Olefin Metathesis Catalysts Containing Chelating Benzylidenes Keary M. Engle, Gang Lu, Shao-Xiong Luo, Lawrence M. Henling, Michael K. Takase, Peng Liu*, K. N. Houk* and Robert H. Grubbs* J. Am. Chem. Soc. 2015, 137, 5782–5792. 7) Gold catalyzed hydrogenations of small imines and nitriles: enhanced reactivity of Au surface toward H2 via collaboration with a Lewis base Gang Lu, Peng Zhang, Dongqing Sun, Lei Wang, Kebin Zhou, Zhi-Xiang Wang* and Guo-Cong Guo* Chem. Sci. 2014, 5, 1082–1090. 6) Manipulation of the Reducibility of Ceria‐Supported Au Catalysts by Interface Engineering Lei Wang, Gang Lu, Dan Yang, Jin Wang, Zhibin Zhu, Zhixiang Wang and Kebin Zhou* ChemCatChem 2013, 5, 1308–1312. 5) Designing Metal‐Free Catalysts by Mimicking Transition‐Metal Pincer Templates Gang Lu#, Haixia Li#, Lili Zhao, Fang Huang, Paul von Ragué Schleyer and Zhi‐Xiang Wang* (# equal contribution) Chem. Eur. J. 2011, 17, 2038–2043. 4) The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study Fang Huang, Gang Lu, Lili Zhao, Haixia Li and Zhi-Xiang Wang* J. Am. Chem. Soc. 2010, 132, 12388–12396. 3) Reversible Heterolytic Methane Activation of Metal‐Free Closed‐Shell Molecules: A Computational Proof‐of‐Principle Study Gang Lu, Lili Zhao, Haixia Li, Fang Huang and Zhi‐Xiang Wang* Eur. J. Inorg. Chem. 2010, 2010, 2254–2260. 2) Computationally Designed Metal-Free Hydrogen Activation Site: Reaching the Reactivity of Metal−Ligand Bifunctional Hydrogenation Catalysts Gang Lu, Haixia Li, Lili Zhao, Fang Huang and Zhi-Xiang Wang* Inorg. Chem. 2010, 49, 295–301. 1) Encumbering the intramolecular pi donation by using a bridge: a strategy for designing metal-free compounds to hydrogen activation Zhi-Xiang Wang*, Gang Lu, HaiXia Li and LiLi Zhao Chin. Sci. Bull. 2010, 55, 239–245. |
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