牛胜利
教授
访问次数:
论文成果
Thermogravimetric analysis of the relationship among calcium magnesium acetate, calcium acetate and magnesium acetate
  • 所属单位:
    能源与动力工程学院
  • 发表刊物:
    Applied energy
  • 关键字:
    Thermogravimetric (TG); Calcium magnesium acetate (CMA); Activation energy; Reaction order
  • 摘要:
    Thermal decomposition characteristic of calcium magnesium acetate (CMA), calcium acetate (CA) and magnesium acetate (MA) are investigated through thermogravimetric (TG) analysis at the heating rates of 5K min(-1), 7.5 K min(-1), 10 K min(-1) and 15K min(-1). After dehydration, the evaporation of carboxylic radical and carbon dioxide of CMA and CA exist in two separate segments, but for MA, this occurs together in just one segment without clear borderline. The curves of calculated CMA (C-CMA) and the deduced characteristic parameters illustrate the different characteristic of CA and MA from the corresponding components in CMA which may be the reason for the different performances of these sorbents in SO2 and NOx reduction. Also, the kinetic parameters of activation energy and reaction order of the three sorbents are calculated through Vyazovkin method and Avrami theory, respectively.
  • 第一作者:
    牛胜利
  • 论文类型:
    期刊论文
  • 通讯作者:
    路春美
  • 论文编号:
    lw-107712
  • 学科门类:
    工学
  • 一级学科:
    动力工程及工程热物理
  • 文献类型:
    J
  • 卷号:
    87
  • 期号:
    7
  • 页面范围:
    2237-2242
  • 是否译文:
  • 发表时间:
    2010-07-01
  • 收录刊物:
    SCI、EI
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