点击次数：

发表刊物：Chemical Engineering Journal

摘要：Metal-organic framework (MOF)-derived carbon materials have drawn tremendous attention as activators of peroxymonosulfate (PMS) for the degradation of antibiotics. However, it is still challenging to construct MOF-derived materials with well-dispersed and highly-exposed metal active sites. Herein, the bimetallic Cobalt-Zinc-zeolite imidazolate framework and melamine co-derived double layer nitrogen-doped porous carbon matrix supported highly dispersed cobalt nanoparticles (Co NPs) (denoted as Co-NC-C) with the exposure of more Co NPs sites was developed by one-step pyrolysis method. The transmission electron microscopy results demonstrate that double layer carbon matrix as a dispersant can effectively inhibit the agglomeration of Co NPs, and Co-NC-C possessed more exposure of Co active sites compared with Co-NC without melamine. Co-NC-C efficiently activated PMS to remove over 96.67% of sulfamethoxazole (SMX) at a widespread range of pH within 120 min due to its the highly-exposed Co active sites and high graphitization degree. Additionally, the degradation mechanism dominated by the singlet oxygen was demonstrated. Finally, four products and two probable degradation pathways of SMX were confirmed. Half of the products were less toxic than SMX based on the ecological structure activity relationships analysis results. The study provides valuable insights for the development of MOF-derived catalysts with well-dispersed and highly-exposed metal active sites.

全部作者：Zuoli He,Shuguang Wang

第一作者：Hao Liu

论文类型：期刊论文

通讯作者：Shan Zhao

论文编号：144054

学科门类：工学

一级学科：环境科学与工程

文献类型：J

卷号：469

页面范围：144054

字数：8

是否译文：否

发表时间：2023-06-01

收录刊物：SCI