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个人简介

姓名:孔令兵

出生年月:19849

学历:博士研究生

职称:齐鲁青年学者特聘教授

单位:有机化学研究所

研究方向:有机硼化学

地址:山东省济南市山东大学中心校区生命北楼516

Email: konglb@sdu.edu.cn

 

学习及工作经历

2017. 11 – 至今          山东大学  教授

2012. 07 – 2016. 08   新加坡南洋理工大学  博士后  导师:Prof. Rei Kinjo

2007. 09 – 2012. 06   南开大学  博士  导师:崔春明教授

2002. 09 – 2007. 07   聊城大学  学士

 

研究领域和兴趣

不饱和硼化学

亲核性硼化学

功能硼杂共轭体系的构建

 

主要论著

近三年工作概览:https://www.x-mol.com/news/775847 

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21. Qiu Shuang, Xin Zhang, Chaopeng Hu, Hongxu Chu, Qianli Li, David A. Ruiz, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. Unveiling Hetero-Enyne Reactivity of Aryliminoboranes: Dearomative Hetero-Diels-Alder-Like Reactions. Angew. Chem. Int. Ed. 2022, e202205814. (Selected as a HOT Paper by Angew. Chem.)

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20. Yu Wang, Xin Zhang, Jixing Han, Qianli Li, Rui Wei, David A. Ruiz, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*.  Crystalline Neutral Diboron Analogues of Cyclopropanes. Angew. Chem. Int. Ed. 2022, 61, e202117053. (Selected as a HOT Paper by Angew. Chem. Highlighted by ChemistryViews: Neutral Diboron Analogues of Cyclopropanes.)

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19. Rui Guo, Xin Zhang, Tong Li, Qianli Li, David A. Ruiz, Liu Leo Liu, Chen-Ho Tung, and Lingbing Kong*. Unraveling the Reactivity of a Cationic Iminoborane: Avenues to Unusual Boron Cations. Chem. Sci. 202213, 2303.

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18. Rui Guo, Tong Li, Rui Wei, Xin Zhang, Qianli Li, Liu Leo Liu,* Chen-Ho Tung, and Lingbing Kong*. Boraiminolithium: An Iminoborane-Transfer Reagent. J. Am. Chem. Soc. 2021, 143, 13483. (Highlighted by ChemistryViews: Boraiminolithium Compound Can Transfer B≡N Units)

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17. Hao Gao, Qianli Li, Ping Cui, Chen-Ho Tung, and Lingbing Kong*Facile Access to Alkylideneborane and Diborabutadiene N-Heterocyclic Carbene Complexes. Inorg. Chem2021, 60, 8432.

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16. Lingbing Kong* and Chunming Cui*. Perspective of Organoboron Chemistry. Synlett. 2021, 32, 1316. (Invited Perspective).

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15. Rui Guo, Jingxing Jiang, Zhuofeng Ke,* Chen-Ho Tung and Lingbing Kong*. Incorporation of H2O and CO2 into a BN-embedded 3aH-3a1H-acephenanthrylene derivative. Chem. Commun. 2021, 57, 1226.

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14. Rui Guo, Jingxing Jiang, Chenyang Hu, Liu Leo Liu, Ping Cui, Meihua Zhao, Zhuofeng Ke,* Chen-Ho Tung and Lingbing Kong*. BNN-1,3-dipoles: Isolation and Intramolecular Cycloaddition with Unactivated Arenes. Chem. Sci. 2020, 11, 7053. (2020 Chemical Science HOT Article Collection)

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13. Ping Cui, Rui Guo, Lingbing Kong* and Chunming Cui*. New Approaches to N-Heterocyclic-Carbene-Coordinated Iminoborane and Borenium Species. Inorg. Chem. 2020, 59, 5261.

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12. Rui Guo, Xiao Huang, Meihua Zhao, Yusheng Lei, Zhuofeng Ke,* and Lingbing Kong*. Bifurcated Hydrogen-Bond-Stabilized Boron Analogues of Carboxylic Acids. Inorg. Chem. 2019, 58, 13370.

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11. Lingbing Kong, Wei Lu, Yongxin Li, Rakesh Ganguly and Rei Kinjo*. Formation of Boron–Main Group Element Bonds by Reactions with a Tricoordinate Organoboron L2PhB:(L = Oxazol-2-ylidene). Inorg. Chem. 2017, 56, 5586.

10. Lingbing Kong, Wei Lu, Yongxin Li, Rakesh Ganguly and Rei Kinjo*. Azaborabutadienes: Synthesis by Metal-Free Carboboration of Nitriles and Utility as Building Blocks for B,N-Heterocycles. Angew. Chem. Int. Ed. 2016, 55, 14718.

9. Lingbing Kong, Wei Lu, Yongxin Li, Rakesh Ganguly and Rei Kinjo*. Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp3)–B(sp3) Bond. J. Am. Chem. Soc. 2016, 138, 8623.

8. Lingbing Kong, Rakesh Ganguly, Yongxin Li and Rei Kinjo*. Serendipitous Observationof Al(I) Insertion into a C–O Bond in L2PhB: (L=oxazol-2-ylidene). Chem. Eur. J. 2016, 22, 1922.

7. Lingbing Kong, Rakesh Ganguly, Yongxin Li and Rei Kinjo*. Diverse Reactivity of A Tricoordinate Organoboron L2PhB: (L=oxazol-2-ylidene) towards Alkali Metal, Group 9 Metal, and Coinage Metal Precursors. Chem. Sci. 2015, 6, 2893. (Selected as one of the TOP 25 most downloaded articles between Apr-Jun 2015)

6. Di Wu, Lingbing Kong, Yongxin Li, Rakesh Ganguly and Rei Kinjo*. 1,3,2,5-diazadiborinine featuring Nucleophilic and Electrophilic Boron Centers. Nat. Commun. 2015, 6, 7340. 

5. Liliang Wang, Lingbing Kong, Yongxin Li, Rakesh Ganguly and Rei Kinjo*. Anti-Markovnikov Hydroimination of Terminal Alkynes in Gold-Catalyzed Pyridine Construction using Ammonia. Chem. Commun. 2015, 12419. (Equal contribution)

4. Lingbing Kong, Yongxin Li, Rakesh Ganguly, Dragoslav Vidovic and Rei Kinjo*. Isolation of a Bis(oxazol-2-ylidene)-Phenylborylene Adduct and its Reactivity as a Boron-Centered Nucleophile. Angew. Chem. Int. Ed. 2014, 53, 9280. (Selected as a HOT Paper by Angew. Chem.).

3. Lingbing Kong, Chunming Cui*. Synthesis and Reactivity of a Base-Free N-Heterocyclic Silanimine. Organometallics 2010, 29, 5738.

2. Lingbing Kong, Jianying Zhang, Haibin Song and Chunming Cui*. N-Aryl Substituted Heterocyclic Silylenes. Dalton Trans., 2009, 5444.

1. Haiyan Cui, Yanjun Shao, Xiaofei Li, Lingbing Kong, and Chunming Cui*. Dehydrochlorination to Silylenes by N-Heterocyclic Carbenes. Organometallics 2009, 28, 5191.

 

科研项目

1. 国家自然科学基金面上项目,22271174,主持,2023.1–2026.12.

2. 国家自然科学基金面上项目,21971144,主持,2020.1–2023.12.

3. 山东省重点研发计划(公益类专项),2019GGX102032,主持,2019.12–2021.12.

4. 国家自然科学基金青年项目,21702228,主持,2018.1–2020.12.

5. 山东省自然科学基金面上项目, ZR2017MB021,主持,2017.8–2020.6.

6. 齐鲁青年学者特聘教授启动经费,主持,2017–2022.

7. 南开大学元素有机化学国家重点实验室开放基金,201808,主持,2019.1-2019.12.

8. 南开大学元素有机化学国家重点实验室开放基金,202102,主持,2022.1-2022.12.

9. 山东省自然科学基金重大基础研究项目,ZR2019ZD46,核心成员,2019.12-2024.12.

10. 山东大学青年交叉科学创新群体,2020QNQT007,核心成员,2020.1-2023.12.

 

科研成果

聚焦硼杂不饱和体系的合成新方法开发、新结构创制以及新应用探索等方面,通过合理设计,成功开发了高效硼杂不饱和键构建新方法,并将其成功应用于非环共轭不饱和硼体系的构筑;稳定分离了离子型亚胺硼烷化合物,并系统研究了它们的基元反应性;通过硼杂烯烃的重排反应合成了中性二硼杂环丙烷类似物;发现BNN-1,3-偶极子在室温下即可完成对苯环的去芳构化偶极环加成反应。

代表性成果一:离子型亚胺硼烷的合成、表征及应用研究

i. 利用大位阻芳基配位稳定了高活性的阴离子型亚胺硼烷(硼杂亚胺锂盐),发现了其硼氮三键转移功能 (J. Am. Chem. Soc. 2021, 143, 13483.); ii. 合成了高活性可分离的阳离子型亚胺硼烷(亚氨基硼正离子),揭示了其多重键和路易斯酸性硼中心双重反应位点 (Chem. Sci. 2022, 13, 2303.)

代表性成果二:中性二硼杂环丙烷类似物的合成与性质研究

合成表征了中性二硼杂环丙烷类似物,探明了其范特霍夫-勒贝尔 (van’t Hoff-Le Bel) 构型,揭示了亲电开环、亲核开环、氢化开环以及氧化官能化等基元反应行为 (Angew. Chem. Int. Ed. 2022, 61, e202117053.)

代表性成果三:硼杂不饱和键构筑新方法及应用拓展

开发了一步实现孤立硼杂多重键构筑和稳定的新方法 (Inorg. Chem. 2021, 60, 8432; Inorg. Chem. 2020, 59, 5261; Inorg. Chem. 2019, 58, 13370.),并将其成功拓展到新型硼杂共轭不饱和体系的构建,制备了BNN-1,3-偶极子 (Chem. Sci. 2020, 11, 7053; Chem. Commun. 2021, 57, 1226.), BNNB-, NBBN-, CNBC-以及CNBN-五个1,3-硼杂共轭体系。