牛胜利
Professor Supervisor of Doctorate Candidates Supervisor of Master's Candidates
Name (Simplified Chinese):牛胜利
Name (Pinyin):Niu Shengli
Date of Employment:2011-08-16
School/Department:核科学与能源动力学院
Education Level:Postgraduate (Doctoral)
Gender:Male
Degree:Doctoral Degree in Engineering
Status:Employed
Alma Mater:山东大学
Whether on the job:1
Discipline:Engineering Thermophysics
Thermal Power Engineering
Academic Honor:
Honors and Titles:
Hits:
Affiliation of Author(s):能源与动力工程学院
Journal:农业机械学报
Key Words:酯交换;钙基异相碱催化剂;电石渣;醋酸改性
Abstract:以醋酸为改性介质,从醇油摩尔比、催化剂质量分数、酯交换温度及时间等因素出发,并辅以热重分析仪、X射线衍射仪、N2吸附仪和哈米特指示剂等催化剂表征手段,通过酯交换实验系统研究改性电石渣催化酯交换的特性。酯交换原料油(花生油)脂肪酸中的碳原子长度主要为16~18碳;醋酸改性后,电石渣主要成分为(CH3COO)2Ca·0.5H2O,经800℃煅烧活化处理后转变为CaO,比表面积为19.07 m2/g、比孔容积为0.081 4 cm3/g,且能够表现出比未改性电石渣煅烧产物更强的催化酯交换性能。在醇油摩尔比15、催化剂质量分数4%、酯交换温度59℃、酯交换时间2 h的工况下,醋酸改性电石渣催化酯交换能取得甘油收率为96.79%,且重复使用5次时,甘油收率仍能达到92.90%。
All the Authors:路春美,李辉,霍梦佳
First Author:刘梦琪
Indexed by:Journal paper
Correspondence Author:牛胜利*
Document Code:lw-153950
Discipline:Engineering
First-Level Discipline:Power Engineering and Engineering Thermophysics
Document Type:J
Volume:45
Issue:8
Page Number:184-189
Translation or Not:no
Date of Publication:2014-08-01
Included Journals:EI