牛胜利
教授
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论文成果
Thermogravimetric analysis of carbide slag A potential transesterification catalyst validation
  • 所属单位:
    能源与动力工程学院
  • 发表刊物:
    Journal of Thermal Analysis and Calorimetry
  • 关键字:
    Thermogravimetric; Carbide slag; Model-free method; Transesterification; Catalyst
  • 摘要:
    Potential of carbide slag as transesterification catalyst is validated. Combined with X-ray fluorescence for ingredient determination, X-ray diffraction for textural phase analysis, scanning electron microscope for surface morphology observation and Hammett indicator for basic strength mensuration, thermal event of carbide slag is investigated through thermogravimetric analysis to estimate the potential of this calcium-based industrial waste as transesterification catalyst. Further, kinetic parameters are calculated through model-free method, where the experiments are conducted at temperature heating rates of 5, 10, 15, and 20 K min(-1). As for activation energy and reaction order, Vyazovkin method and Avrami theory are respectively mentioned. Meanwhile, catalytic performance of carbide slag is labeled by transesterification efficiency and calcium hydroxide is conditionally mentioned for comparison. In conclusion, potential of carbide slag as transesterification catalyst is adequately validated.
  • 第一作者:
    Shengli Niu*
  • 论文类型:
    期刊论文
  • 论文编号:
    lw-153991
  • 学科门类:
    工学
  • 一级学科:
    动力工程及工程热物理
  • 文献类型:
    J
  • 卷号:
    115
  • 期号:
    1
  • 页面范围:
    73-79
  • 是否译文:
  • 发表时间:
    2014-01-01
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