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The research interest of our group focuses on the transitional metal catalyzed synthetic methodology development. To mimic the enzyme catalysis, we develop new synthetic strategy and also asymmetric reactions based on cooperative catalysis, including acid base bifunctional catalysis and acid acid cooperative catalysis. More importantly, we wish to apply these synthetic methods to the synthesis of organic materials and bioactive products.
1. Tandem Metal Relay Catalysis (Lewis acid & Lewis acid combination)
1)Combination of Pi acid (Au) with σ acid (rare-earth metal)
2)Cascade reactions based on transmetallation (Cu-Pd relay)
2. Lewis acid & Lewis base bifunctional catalysis (Transition-metal catalysis & Organocatalysis combination )
- 张恒. 多学科融合背景下综合开放创新化学实验教学体系及平台建设与实践. 大学化学, 2024.
- 张璇. Neighboring group-directed asymmetric [2+2+2] cycloaddition to access C-N axially chiral indoles. Organic Chemistry Frontiers, 2024.
- 刘世利. Photoelectrochemical competitive detection of biotin. Chinese Journal of Analytical Chemistry, 41, 1477, 2023.
- . Asymmetric synthesis of tricyclic 6,5,5-fused polycycles by the desymmetric Pauson-Khand reaction. Organic Chemistry Frontiers, 9, 1680-1685, 2023.
- Interrupted Kinugasa allylic alkylation.. Trends in Chemistry 2021, 3, 984, 2022.
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