赵翠华
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有机小分子发光材料由于发光效率高，结构明确、易于衍生化等特点一直以来是有机合成化学和材料科学研究的热点。随着科学的发展、社会的进步，人们对有机小分子发光材料的性能和用途逐渐提出了新的需求，我们课题组主要针对有机发光材料研究中存在的一些问题和需求，利用三价硼、氮元素的立体位阻效应和完全相反的电子效应，提出新的分子设计方法，构建新型的有机硼分子体系，研究构效关系，并探索在实际领域如电致发光器件、荧光探针以及生物成像等领域的应用。
2024
52. Min Wang, Fang-Kun Wang, Zhi-Qiang Liu, Cui-Hua Zhao,* Two-Photon-Excited Fluorescnet Triphenylborane Featuring the Cooperative Effect of Branching in Two-Photon Absorption, J. Org. Chem. Link
51. Lian-Feng Guo, Min Wang, Cui-Hua Zhao,* The Solid-state Multi-color Fluorescene Switching from a [2.2]Paracyclophane-base Triarylborane, Chem. Eur. J. Invited Contribution Link
2023
50. Shimin Zhou, Yang Liu, Wendong Jin, Tingting Qin, Xuguang Liu, Cuihua Zhao, Zhiqiang Liu,* Xiaoqiang Yu*, Synthesis, Structures, and Photophysical Properties of Zigzag BNBNB-Embedded Anthracene-Fused Fluoranthene, Org. Lett. 2023, 25, 1573-1577, Link
2022
49. Min Wang, Run-Ze Wang, Cui-Hua Zhao,* Temperature-Dependent Dual Fluorescence from Small Organic Molecules, Invited Minireview, Org. Mater. 2022, 4, 204-215. Link
48. Xing-Yu Chen, Zhi-Qiang Liu, Cui-Hua Zhao,* Two-photon Excited Fluorescent 3,3’-Diamino-5,5’-diboryl-2,2’-bithienyls Featuring a Quadrupolar Structure, Chem. Eur. J. 2024, 28, e202104432. Link
47. Zhen Jiang, Shimin Zhou, Wendong Jin, Cuihua Zhao, Zhiqiang Liu,* Xiaoqiang Yu,* Synthesis, Structure and Photophysical Properties of BN-Embedded Analogue of Coronene, Org. Lett. 2022, 4, 1017-1021. Link
46. Min Wang, Cui-Hua Zhao,* Chiral Triarylboranes-based Small Organic Molecules for Circularly Polarized Luminescence, Invited Personal Account, Chem. Record 2022, 22, e202100199. Link
2021
45. Huangxiang Yuan,* Zelin Li, Haotian Bai, Zhuo Chen, Chuang Yao, Shaochuan Jia, Ruilian Qi,* Cui-Hua Zhao* Aggregation-induced emission nanoparticles with NIR and photosensitizing characteristics for resistant bacteria elimination and real-time tracking, Material Frontier Chemistry, 2021, 5, 6611. Link
44. Han-Wei Li, Meng Li, Zheng-Hua Zhao, Chuan-Feng Chen, Qian Peng,* Cui-Hua Zhao,* Propeller Configuration Flipping of Trivalent Boron Inducing Substituent-dependence of Circularly Polarized Luminescence Sign in Triarylborane-based [7]Helicenes, Org. Lett. 2021, 23, 4759-4763. Link
43. Meng-Yuan Zhang, Qian Peng,* Cui-Hua Zhao*, High-contrast mechanochromic fluorescence from a highly solid-state emissive 2-(dimesitylboryl)phenyl-substituted [2.2]paracyclophane, J. Mater. Chem. C 2021, 9, 1740-1745. Link
42. Meng-Yuan Zhang, Xiao, Liang, Dan-Ning Ni, Di-Hong Liu, Qian Peng,* Cui-Hua Zhao,* 2-(Dimesitylboryl)phenyl-Substituted[2.2]Paracyclophanes Featureing Intense and Sign Invertible Circularly Polarized Luminescence, Org. Lett. 2021, 23, 2-7. Highlighted as Cover Link
2020
41. Jia-Liang Ma, Hao Liu, Sheng-Yong Li, Zhi-Yi Li, Hong-Yu Zhang, Cui-Hua Zhao,* Metal-Free Room-Temperature Phosphorescence from Amophous Triarylborane-Based Biphenyl, Organometallics, 2020, 39, 4153-4158. Link invited contribution for a Special Issue “Organometallic Chemistry of the Main-Group Elements,”
2019
40. Triarylborane-based [5]Helicenes with Full-color Circularly Polarized Luminescence, Zheng-Hua Zhao, Xiao Liang, Mao-Xia He, Meng-Yuan Zhang, Cui-Hua Zhao*, Org. Lett. 2019, 21, 9569-9573. Link
39. Circularly Polarized Luminescence in Small Organic Molecules, Jia-Liang Ma, Qian Peng,* Cui-Hua Zhao,* Chem. Eur. J. 2019, 25, 15441-15454. invited minireview, Link
38. 1,1'-Binaphthyl Consisting of Two Donor-π-acceptor Subunits: a General Skeleton for Temperature-Dependent Dual Fluorescence, Di-Hong Liu, Zuo-Bang Sun, Zheng-Hua Zhao, Qian Peng,* Cui-Hua Zhao,* Chem. Eur. J.2019, 25, 10179–10187. Link
37. 2,2'-Diamino-6,6'-diboryl-1,1'-binaphthyl: a Versatile Building Block for Temperature-dependent Dual Fluorescence and Switchable Circularly Polarized Luminescence, Zuo-Bang Sun, Jun-Kai Liu, Da-Fei Yuan, Zheng-Hua Zhao, Xiao-Zhang Zhu, Di-Hong Liu, Qian Peng,* Cui-Hua Zhao,* Angew. Chem. Int. Ed. Link
2018
36. Modification of [5]Helicene with Dimesityboryl: a Way to Enhance the Fluorescence Efficiency, Zheng-Hua Zhao, Meng-Yuan Zhang, Di-Hong Liu, Cui-Hua Zhao,* Org. Lett. 2018, 20, 7590-7593. Link 2018-12-7
35. Solid-state Emissive Triarylborane-based [2.2]Paracyclophanes Displaying Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence, Meng-Yuan Zhang, Zhi-Yi Li, Bo Lu, Ying Wang, Yu-Dao Ma, Cui-Hua Zhao,* Org. Lett. 2018, 20, 6868-6871. Link
34. Impact of 2,2'-Bithienyl Framework on the Charge-transfer Emission of Triarylborane-based o,o'-Substituted Biaryls, Sheng-Yong Li, Zuo-Bang Sun, Cui-Hua Zhao,* ACS Omega, 2018, 3, 12730–12736. Link
33. Highly Efficient White Light-Emitting Diodes with a bi-Component Emitting Layer Based on a Blue and Yellow Thermally Activated Delayed Fluorescence Emitters, Yongzhen Chen, Sheng-Yong Li, Taiping Hu, Xiaofang Wei, Zhiyi Li, Yanwei Liu, Jianjun Liu, Ruifang Wang, Yuanping Yi, Cui-Hua Zhao,* Ying Wang,* Pengfei Wang, J. Mater. Chem. C 2018, 6, 2951–2956. Link
2017
32. Sheng-Yong Li, Ya-Jun Hui, Zuo-Bang Sun, Cui-Hua Zhao,* A Triarylborane-based Biphenyl Exhibiting Abrupt Fluorescence Enhancement at a Specific High Temperature, Chem. Commun. 2017, 53, 3446-3449. Link
31. Sheng-Yong Li, Zuo-Bang Sun, Cui-Hua Zhao,* Charge-transfer Emitting Triarylborane p-Electron Systems, Accepted, Invited Overview for the Forum of “Advances in Main-Group Inorganic Chemistry” Inorg. Chem. 2017, 56, 8705-8717. Link
2016
30. Chen Wang, Zuo-Bang Sun, Qing-Wen Xu, Cui-Hua Zhao,* Chirality Relay in 2,2’-Substituted 1,1’-Binaphthyl: Access to Propeller Chirality of Tricoordinate Boron Center, Chem. Eur. J. 2016, 22, 16750-16754, selected as Frontispiece, Link
29. Zuo-Bang Sun, Sheng-Yong Li, Zhi-Qiang Liu, Cui-Hua Zhao,* Triarylborane pi-Electron Systems with Intramolecular Charge-Transfer Transitions, Chin. Chem. Lett. 2016, 27, 1131-1138. Invited Review Link
28. Chen Wang, Yi Yuan, Sheng-Yong Li, Zuo-Bang Sun, Zuo-Quan Jiang,* Cui-Hua Zhao,* A Highly Twisted Triarylborane-based Biphenyl as Efficient Hosts for Blue and Green Phosphorescent OLEDs, J. Mater. Chem. C. 2016, 4, 7607-7613, Link
27. Zuo-Bang Sun, Man Guo, Cui-Hua Zhao,* Synthesis and Properties of Benzothieno[b]-fused BODIPY Dyes, J. Org.Chem. 2016, 81, 229-237. Link
26. Huanxiang Yuan,* Lifang Wang, Shuhong Li, Haiyan Liang, Chichong Lu, Yibo Wang, Cui-Hua Zhao,* The Preparation of Organoboron-Based Stilbene Nanoparticles for Cell Imaging, J. Mater. Chem. B. 2016, 4, 5515-5518, Link
2015
25 Chen Wang, Qing-Wen Xu, Wei-Ning Zhang, Qian Peng, Cui-Hua Zhao,* Charge-transfer Emission in Organoboron-based Biphenyls: Effect of Substitution Position and Conformation, J. Org. Chem. Accepted, Link
24 Qing-Wen Xu, Chen, Wang, Zuo-Bang Sun, Cui-Hua Zhao,* A Highly Selective RatiometricBifunctional Fluorescence Probe for Hg2+ and F– Ions, Org. Biomol. Chem. 2015, 13, 3032–3039. Link
2014
23. Dong-Mei Chen, Sheng Wang, Hong-Xiang Li, Xiao-Zhang Zhu, Cui-Hua Zhao,* Solid-state Emissive B,S-bridged p-Terphenyls: Synthesis, Properties and Utility as Bifunctional Fluorescent Sensor for Hg2+and F–Ions, Inorg. Chem. 2014, 53, 12532–12539. Link
22. Chen Wang, Jion Jia, Wei-Ning Zhang, Hong-Yu Zhang, Cui-hua Zhao*, Triarylboranes Containing2-Dimesitylboryl-2'-(N,N-dimethylamino)biphenyl as a Core Unit:Structure-property Correlations and Sensing Abilities to Discriminate F–and CN– Ions, Chem. Eur. J. 2014, 20, 16590–16601. Link
21. Bin Wang, HongPan, Jiong Jia, Yan-Qing Ge, Wen-Qing Cai, Jian-Wu Wang*, Cui-HuaZhao*, Highly emissive dimesitylboryl-substituted 2,1,3-benzothiadiazole derivatives: photophysical properties and efficient fluorescent sensor for fluoride anions, Tetrahedron, 2014, 70, 5488.
20. LiangchunLi, Shuhong Li*, Cui-Hua Zhao, Caihong Xu*, Synthesis, PhotophysicalProperties, and Self-Organization of Difurobenzosilole Derivatives, Eur .J. Inorg. Chem. 2014, 1880
19. Dong-MeiChen, Qian Qin, Zuo-Bang Sun, Qian Peng, Cui-HuaZhao*, Synthesis and Properties of B,N-Bridged p-Terphenyls, Chem. Commun. 2014, 50,782-784, selected as back cover Link
2013
18. Yi-Qiao Yan, Yan-Bang Li, Jian-Wu Wang,* Cui-Hua Zhao,* Effect of Substitution Pattern on the Intramolecular Charge-transfer Emissions in Organoboron-based Biphenyls, Diphenylacetylenes and Stilbenes, Chem. Asian J. 2013, 8, 3164-3176. Link
17. Yang, B.; Niu, X.; Huang, Z.; Zhao, C.*; Liu, Y.; Ma, C.* “A novel kind ofdimmer(excimer)-induced-AIE compound 2-phenylisothiazolo[5,4-b]pyridin-3(2H)-oneashigh selective bisulfite anion probe” Tetrahedron, 2013, 69, 8250–8254.
16. Guang-Liang Fu, Cui-Hua Zhao*, An aggregation-induced emissive chromophore as a ratiometricfluorescent sensor for cyanide in aqueous media, Tetrahedron, 2013, 69, 1700-1704. Link
2012
15. Guang-Liang Fu,Hong-Yu Zhang, Yi-Qiao Yan, Cui-Hua Zhao, * para-QuarterphenylsLaterally Substituted with a Dimesitylboryl Group: A Promising Class ofSolid-state Blue Emitters, J. Org. Chem. 2012, 77,1983-1980. Link
2011
14. Guang-Liang Fu, Hong Pan, Yi-Hong Zhao, Cui-Hua Zhao,* Solid-state Emissive Triarylborane-based BODIPY Dyes: Photophysical Propertiesand Fluorescent Sensing for Fluoride and Cyanide Ions, Org. Biomol.Chem. 2011, 9, 9141. Link
13. Hong Pan, Guang-Liang Fu, Yi-Hong Zhao, Cui-Hua Zhao,* Through-Space Charge-Transfer Emitting Biphenyls Containing a Boryl and an Amino Group ato,o-Positions,Org. Lett.,2011, 13 , 4830–4833 Link
12. Yi-HongZhao, Hong Pan, Guang-Liang Fu, Ji-Mao Lin, Cui-Hua Zhao,* A HighlyEmissive Cruciform Triarylborane as a Ratiometric and Solid-state FluorescenceSensor for Fluoride Ions, Tetrahedron Lett., 2011, 52,3832-3835. Link
11. Cui-HuaZhao*, Yi-Hong Zhao, Hong Pan, Guang-Liang Fu, High Solid Statepara-Terphenyls Laterally Substituted with a Diphenylamino Group, Chem.Commun. 2011, 47(19), 5518-5520. Link highlighted by Prfo. Benzong Tang in "NoteworthyChemistry" Link
2011 以前
10. Cui-HuaZhao, Astsushi Wakamiya, Shigehiro Yamaguchi,* Highly EmissiveOligo(p-phenlyeneethynylene)s containing 2,5-Diboryl-1,4-phenylene Unit:Elucidation of Structure-Property Relationship and Efficient FluorescentFluoride Sensing, Chem. Eur. J. 2009, 15, 10603 Link
9. 赵翠华*，赵以红，林吉茂，有机硼pi-共轭光电功能材料研究进展，化学进展，2009，21，2605
8. Zhongqiu Liu, Shengxin Lu, Cuihua Zhao, Kai Ding, Zhaozhen Cao, JinhuaZhan, Chen Ma, Jinting iu,* Rimo Xi,* Preparation ofanti-danofloxacin antibody and development of an indirect competitiveenzyme-linked immunosorbent assay for detection of danofloxacin residue inchicken liver, J. Sci. Food Agr., 2009, 89, 1115.
7. Kai Ding, Cuihua Zhao, Zozhen Cao, Zhongqiu Liu, Jingting Liu, Jinhua Zhan, Chen Ma, Rimo Xi, Chemiluminescent Detection of Gatifloxacin Residue in Milk” Analytical Letters, 2009, 42, 505.
6. Cui-Hua Zhao, Astsushi Wakamiya, Shigehiro Yamaguchi,* Highly EmissivePoly(aryleneethynylene)s Containing 2,5-Diboryl-1,4-phenylene as aBuilding Unit, Macromolecules 2007, 40, 3898.
5. Cui-Hua Zhao, Astsushi Wakamiya, Yuko Inukai, Shigehiro Yamaguchi,* HighlyEmissive Organic Solids Containing 2,5-Diboryl-1,4-phenylene Unit, J.Am. Chem. Soc. 2006, 127, 15934
4. Cui-Hua Zhao, Li Liu, Dong Wang,* Yong-Jun Chen,* AsymmetricMannich-Type Reaction of Chiral N-(tert-Butylsulfinyl)ketimine with Imines:Application to the Synthesis of Chiral 1,3-Diamines, Eur. J. Org. Chem. 2006,2977
3. Cui-Hua Zhao, Li Liu, Dong Wang,* Yong-Jun Chen,* Synthesisof Enatiomerically Enriched Beta-Amino Alcohol Derivatives via Chiral BaseMediated-Asymmetric Deprotonation of (Benzyl MethylEther)tricarbonylchromium(0) Complex and Electrophilic Trapping, J. Chem.Res (S), 2004, 589
2. Rui Ding, Cui-Hua Zhao, Yong-Jun Chen, Dong Wang, Chao-Jun Li, Rhodium-Catalyzed andSonication-Accelerated Addition of Aryltin and Aryllead Reagents to Imines inAir and Water, Tetrahedron Lett. 2004, 45, 2995.
1. Yong-Jun Chen,* Cui-Hua Zhao, Li Liu, Dong Wang,* Synthesis of Diarylmethylaminesvia Electrophilic Trapping of Tricarbonyl Chromium Complexed AryllithiumIntermediates with Imines, J. Chem. Res (S), 2003, 740.
2019.10 赵翠华 第二届CPL圆偏振光谱仪应用研讨会 北京，邀请报告
2019.8 赵翠华 中国化学会第十六届全国有机合成化学学术研讨会，Circularly Polarized Luminescence-Active Triarylborons with Charge-transfer Characteristics, 河南 开封，邀请报告
2019.7 张梦媛 The 2nd International Conference on Boron Chemistry, Circularly Polarized Luminescence-Active Triarylborons with Charge-transfer Characteristics, 山西太原，墙报
