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    巩彦君

    • 研究员
    • 性别:男
    • 毕业院校:中国科学院大学
    • 学历:博士研究生毕业
    • 学位:理学博士学位
    • 在职信息:在职
    • 所在单位:化学与化工学院
    • 电子邮箱:yjgong@sdu.edu.cn

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    Long-Range Exciton Migration in Coassemblies: Achieving High Photostability without Disrupting the Electron Donation of Fluorene Oligomers.

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    发表刊物:Angew. Chem. Int. Ed.

    摘要:In this work, photostable coassemblies from a nonphotostable fluorene oligomer (the energy donor) and a photostable oligomer (the energy acceptor) are fabricated. Longrange exciton migration over a net distance of about 370
    energy-donor molecules to energy acceptors is demonstrated in
    such coassemblies. The fast and long energy migration allows
    harvesting of the excitation energy of energy donors by
    embedding a small number of energy acceptors for photostability enhancement. Importantly, embedding a small
    number of energy acceptors in coassemblies causes a negligible
    negative influence on the electron donation of energy donors
    that are desired in practical applications. The advantages of the
    coassemblies fabricated, that is, high photostability without
    disrupting the electron donation of energy donors, are well
    illustrated in fluorescence detection of trace explosives where
    prolonged working life and improved detection capacity are
    achieved.

    第一作者:程传欣,巩彦君

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    发表时间:2021-02-01