|
个人信息Personal Information
副研究员 硕士生导师
性别：女
毕业院校：吉林大学
学历：博士研究生毕业
学位：理学博士学位
在职信息：在职
所在单位：化学与化工学院
入职时间：2022-02-18
学科：理论与计算化学
办公地点：山东大学青岛校区图书馆831室
联系方式：lixiaoxi@sdu.edu.cn
其他联系方式Other Contact Information
邮编 : 266237
通讯/办公地址 : 山东省青岛市即墨区滨海路72号山东大学（青岛）图书馆831
移动电话 : 13261811695
邮箱 : lixiaoxi@sdu.edu.cn
个人简介Personal Profile
电子邮箱：lixiaoxi@sdu.edu.cn
个人经历：
副研究员（山东大学，2022.02-至今）
研究教授(Research Professor)（韩国梨花女子大学，2020.12-2021.08）
博士后(Postdoctoral Fellow)（韩国梨花女子大学，2017.01−2020.11）
助理研究员（中科院 兰州化学物理研究所，2015.07−2016.12）
博士（吉林大学，2010.09-2015.06）
学士（云南大学，2006.09-2010.07）
研究方向：
仿生催化剂构效关系的理论研究及新型金属催化剂的理性设计
通过理论模拟，揭示金属酶的催化反应机理，充分认识催化反应过程中关键中间体的结构-性质关系，为新型、高效的仿生催化剂的理性设计提供理论指导。
代表性科研成果：
1) Panjie Hu, Bingxian Liu, Fen Wang, Ruijie Mi, Xiao-Xi Li,* Xingwei Li,* A Stereodivergent-Convergent Chiral Induction Mode in Atroposelec-tive Access to Biaryls via Rhodium-Catalyzed C-H Bond Activation-Annulation ACS Catal. 2022, 12, 13884-13896. (SCI一区, IF = 13.7)
2) Ranjana Gupta,# Xiao-Xi Li,# Youngseob Lee, Mi Sook Seo, Yong-Min Lee, Sachiko Yanagisawa, Minoru Kubo, Ritimukta Sarangi,* Kyung-Bin Cho,* Shunichi Fukuzumi,* Wonwoo Nam,* Heme compound II models in chemoselectivity and disproportionation reactions Chem. Sci. 2022, 13, 5707-5717. (SCI一区, IF = 9.969)
3) Xuanyu Cao,# Huiling Song,# Xiao-Xi Li,* Qing-An Qiao,* Yufen Zhao, Yong Wang,* Which is the real oxidant in competitive ligand self-hydroxylation and substrate oxidation—a biomimetic iron(II)-hydroperoxo species or an oxo-iron(IV)-hydroxy one? Dalton Trans. 2022, 51, 7571-7580. (SCI二区, IF = 4.569)
4) Xiao-Xi Li,# Xiaoyan Lu,# Kyung-Bin Cho,* Wonwoo Nam,* Nonheme Iron Imido Complexes Bearing a Non-Innocent Ligand: A Synthetic Chameleon Species in Oxidation Reactions Chem. Eur. J. 2021, 27, 17495-17503. (SCI二区(Top), IF = 5.02)
5) Xiao-Xi Li,# Shan-Shan Xue,# Xiaoyan Lu,# Mi Sook Seo, Yong-Min Lee, Won-Suk Kim, Kyung-Bin Cho,* Wonwoo Nam,* Ligand Architecture Perturbation Influences the Reactivity of Nonheme Iron(V)-Oxo Tetraamido Macrocyclic Ligand Complexes: A Combined Experimental and Theoretical Study Inorg. Chem. 2021, 60, 4058-4067. (SCI二区(Top), IF = 5.436)
6) Xiaoyan Lu,# Xiao-Xi Li,# Yong-Min Lee, Yuri Jang, Mi Sook Seo, Seungwoo Hong,* Kyung-Bin Cho,* Shunichi Fukuzumi* and Wonwoo Nam,* Electron-Transfer and Redox Reactivity of High-Valent Iron Imido and Oxo Complexes with the Formal Oxidation States of Five and Six J. Am. Chem. Soc. 2020, 142, 3891-3904. (SCI一区, IF = 16.383)
7) Xiao-Xi Li, Kyung-Bin Cho,* Wonwoo Nam,* A Theoretical Investigation into the First-Row Transition Metal-O2 Adducts Inorg. Chem. Front. 2019, 6, 2071-2081. (SCI二区(Top), IF = 7.779)
8) Xiao-Xi Li, Mian Guo, Bin Qiu, Kyung-Bin Cho,* Wei Sun,* Wonwoo Nam,* High-Spin Mn(V)-Oxo Intermediate in Nonheme Manganese-Catalyzed Alkane Hydroxylation Reaction: Experimental and Theoretical Approach Inorg. Chem. 2019, 58, 14842-14852. (SCI二区(Top), IF = 5.436)
9) Yiran Kang,# Xiao-Xi Li,# Kyung-Bin Cho, Wei Sun, Chungu Xia, Wonwoo Nam,* Yong Wang,* Mutable Properties of Noheme Iron(III)-Iodosylarene Complexes Result in the Elusive Multiple-Oxidant Mechanism J. Am. Chem. Soc. 2017, 139, 7444-7447. (SCI一区, IF = 16.383; 此工作被《Nature Reviews Chemistry》作为研究亮点进行了报道)
10) Chengxia Miao,# Xiao-Xi Li,# Yong-Min Lee, Chungu Xia, Yong Wang, Wonwoo Nam,* Wei Sun,* Manganese Complex-Catalyzed Oxidation and Oxidative Kinetic Resolution of Secondary Alcohols by Hydrogen Peroxide Chem. Sci. 2017, 8, 7476-7482. (SCI一区, IF = 9.969)
11) Xiao-Xi Li, Verònica Postils, Wei Sun, Abayomi S. Faponle, Miquel Solà, Yong Wang,* Wonwoo Nam,* Sam P. de Visser,* Reactivity Patterns of (Protonated) Compound II and Compound I of Cytochrome P450: Which Is the Better Oxidant? Chem. Eur. J. 2017, 23, 6406-6418. (SCI二区(Top), IF = 5.02)
12) Xiaoqian Zhang, Xiao-Xi Li,* Yufang Liu, Yong Wang,* Suicide Inhibition of Cytochrome P450 Enzymes by Cyclopropylamines via a Ring-opening Mechanism: Proton-Coupled Electron Transfer Makes a Difference Front. Chem. 2017, 5. (SCI二区, IF = 5.545)
13) Xiao-Xi Li, Yong Wang, Qing-Chuan Zheng,* Hong-Xing Zhang, Detoxification of 1-Methyl-4-Phenyl-1,2,3,6-Tetrahydropyridine (MPTP) by Cytochrome P450 Enzymes: A Theoretical Investigation J. Inorg. Biochem. 2016, 154, 21-28. (SCI三区, IF = 4.336)
14) Xiao-Xi Li, Xiaoqian Zhang, Qing-Chuan Zheng, Yong Wang,* Bio-activation of 4-Alkyl Analogues of 1,4-Dihydropyridine Mediated by Cytochrome P450 Enzymes J. Biol. Inorg. Chem. 2015, 20, 665-673. (SCI三区, IF = 3.862)
15) Xiao-Xi Li, Qing-Chuan Zheng,* Yong Wang,* Hong-Xing Zhang, Theoretical Insights into the Reductive Metabolism of CCl4 by Cytochrome P450 Enzymes and the CCl4-dependent Suicidal Inactivation of P450 Dalton Trans. 2014, 43, 14833-14840. (SCI二区, IF = 4.569)