个人简介
孙頔(Sun Di),男,1983年9月生,博士生导师,教授。
山东大学齐鲁青年学者
山东省泰山学者青年专家
山东省杰出青年基金获得者
国家自然科学基金优秀青年基金获得者
课题组一直致力于功能配(簇)合物的设计合成、可控制备与性能研究;在合成方法学的探索、结构调变机制、组装机理、构效关系阐明等方面取得了多项具有创新性的科研成果。自2016至今,以通讯作者在CCS Chem. (2篇), Proc. Natl. Acad. Sci. U.S.A. (1篇), Nat. Commun. (6篇), J. Am. Chem. Soc. (12篇), Angew. Chem. Int. Ed. (13篇), Sci. Adv. (1篇), Adv. Mater. (2篇), ACS Nano (5篇) , Chem. Mater. (2篇), Adv. Opt. Mater. (2篇), Adv. Energy Mater. (1篇), Coord. Chem. Rev. (2篇) 等杂志发表高水平SCI论文100余篇。研究工作被Science, Nat Rev Chem., ChemViews等学术组织或网站撰写专文亮点评述。论文被引1万余次,H指数=63, 单篇引用大于100次的20余篇(数据来源Web of Science, 2023.5.28)
课题组招收博士后多名,欢迎申请(详情见本网页末尾部分,联系微信号:sd71469190)!
Fully-funded post-doc positions are available for application, especially for organic catalysis using metal cluster and theoretical calculation for metal cluster.
欢迎对无机化学及团簇催化化学和计算化学感兴趣的本科生、硕士生、博士生、博士后加入本课题组.
联系电话: 0531-88364218
地址:山东省济南市历城区山大南路27号化学新楼415室(实验室),335室(办公室)
教育经历:
2008.9-2011.6 厦门大学 无机化学 (含银功能配合物的合成及性质) 博士 导师:黄荣彬、郑兰荪 教授
2005.9-2009.9 厦门大学 无机化学(氯气燃烧法合成氯化富勒烯) 硕士 导师:谢素原、黄荣彬、郑兰荪 教授
2001.9-2005.6 聊城大学 化学 学士 导师:窦建民、李大成 教授
工作经历:
2017.9-至今 山东大学化学与化工学院 教授(破格)
2014.9-2017.8 山东大学化学与化工学院 副教授
2011.7-2014.8 山东大学化学与化工学院 师资博士后(合作导师:孙道峰、钱逸泰教授)、讲师
学术团体兼职:
中国化学会高级会员
National Science Open 副编辑
Chinese Chemical Letter 青年编委
Chinese Journal of Structural Chemistry 青年编委
Polyoxometalates 青年编委
研究领域和兴趣:
高核金属簇化学(合成、结构、组装机理及光电性能)
配位化学及晶体工程(晶体结构可控合成及相关性质)
X-射线单晶结构解析(超大分子体系的结构解析及结构阐述)
超分子化合物(共晶化合物,主-客体化合物)
溶剂分子簇(水分子簇,阴离子水簇)
异金属簇合物及聚合物(基于银簇分子的杂金属化合物)
压、热致荧光变色配(簇)合物及构效关系阐述
多酸簇合物分子结构、组装及相关性质研究
主持科研项目(在研):
2、国家自然科学基金国际(地区)合作与交流项目(52261135637),2023.1-2025.12,负责人 150 W
1、国家自然科学基金面上项目(22171164),2022.1-2025.12,负责人 60 W
主持科研项目(已结题):
12、霍英东教育基金会第十七届高等院校青年教师基金(171009),2020.1-2022.12,负责人 18 W
11、国家自然科学基金委员会优秀青年基金项目(21822107),2019.1-2021.12,负责人 130 W
10、国家自然科学基金委员会重大研究计划培育项目(91961105),2020.1-2022.12,负责人 80 W
9、国家自然科学基金面上项目(21571115),2016.1-2019.12,负责人 60 W
8、国家自然科学基金青年基金(21201110), 2013.1-2015.12,负责人 25W
7、山东省自然科学基金杰出青年基金项目(JQ201803),2018.3-2021.6,负责人 80 W
6、山东大学青年学者未来计划(2015WLJH24),2015.6-2019.6,负责人 50W
5、山东大学基本科研业务费交叉学科培育项目(2015JC045),2015.6-2017.6,负责人 30W
4、中国博士后基金面上项目(第51批)(2012M511492),2012.6-2014.7,负责人 5W
3、中国博士后基金特别资助(第六批)(2013T60663),2013.6-2015.7,负责人 15W
2、山东省博士后创新项目专项资金(201101007), 2012年-2013年,负责人 8W
1、山东省优秀中青年科学家科研奖励基金(BS2013CL010),2013.10-2015.10,负责人 6W
科研获奖:
1、2022年山东省优秀博士论文指导教师(指导学生:王芝)
2、2021年山东省自然科学奖二等奖(第壹位)
3、入选爱思唯尔 2021年(化学)、2022年(化学)中国高被引学者
4、2021年京博科技奖-化学化工与材料京博优秀博士论文奖提名奖(指导教师)
5、2021年卢嘉锡优秀导师奖
6、2021年山东大学优秀研究生指导教师
7、2014年山东省优秀学士学位论文指导教师 (指导学生:袁帅)
8、2016年山东省优秀硕士学位论文指导教师 (指导学生:韩璐璐)
9、2018年山东省优秀硕士学位论文指导教师 (指导学生:王芝)
10、2019年山东省优秀硕士学位论文指导教师 (指导学生:张闪闪)
11、2014年山东高等学校优秀科研成果奖二等奖(第壹位)
12、2012年山东高等学校优秀科研成果奖一等奖(第贰位)
13、2019年山东省高等学校科学技术奖一等奖(第壹位)
14、2010年厦门大学研究生科研成果特等奖
15、2010年厦门大学邓子基奖学金
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主要论著:
全部论文详见:
My Research ID: http://www.researcherid.com/rid/G-3352-2010
(Total ISI citations : 5650; H-index: 43, last updated on Feb. 26, 2019)
金属团簇的研究创新成果简介:
首次利用几何多面体策略,实现哥德堡多面体银笼的合成(Proc. Natl. Acad. Sci. U.S.A. 2017, 114, 12132),并利用质谱确认了多个金属团簇体系的组装机理,提出了“银三角”、“平面外延生长”等组装机理,并对掺杂金属簇的合成提供了成功的指导(J. Am. Chem. Soc., 2016, 138, 1328; J. Am. Chem. Soc., 2017, 139, 14033);利用阴离子模板等策略实现了包括各向异性银簇在内的多个系列新型银簇的合成(Angew. Chem. Int. Ed., 2020, 59, 12659; Angew. Chem. Int. Ed., 2019, 58, 12280; J. Am. Chem. Soc. 2018, 140, 1600; Angew. Chem. Int. Ed., 2019, 58, 6276),结合酸诱导策略实现了内部阴离子模板和外部银壳层的协同成长,建立了“破碎-生长-再组装”的转变机理(Nat. Commun., 2018, 9, 4407);硫属离子诱导实现了银簇内核膨胀和单一手性团簇的结晶分离(J. Am. Chem. Soc. 2019, 141, 17884);利用弱还原性溶剂合成系列纳米银簇,并从原子层面上认识离散原子聚集成为纳米尺寸银簇的演变过程(Angew. Chem. Int. Ed., 2019, 58, 195; J. Am. Chem. Soc., 2019, 141, 4460; Nat. Commun., 2018, 9, 2094; Angew. Chem. Int. Ed., 2020, DOI: 10.1002/anie.202013681);基于杯芳烃的最高核银簇的成功组装为大环螯合配体参与构建银簇开辟了新途径(Nat. Commun., 2020, 11, 308);梯度还原构建纳米铜簇,并为精准调控合成多晶态团簇提供了重要依据(J. Am. Chem. Soc., 2020, 142, 5834);利用超分子组装和共价组装手段实现银簇的多级组装,优化银簇晶体材料的功能表现 (Angew. Chem. Int. Ed. 2020, 59, 9922; Angew. Chem. Int. Ed. 2020, 59, 20031),并利用金属团簇为前体合成制备了新型金属氧化物复合材料,作为锂电池负极表现出优异的电池性能(Adv. Mater. 2018, 30, 704244)。
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近五年代表性论文(2018-2023):
[A1] J. W. Liu, L. Feng, H. F. Su, Z. Wang, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Anisotropic Assembly of Ag52 and Ag76 Nanoclusters, J. Am. Chem. Soc., 140, (2018) 1600-1603, DOI: 10.1021/jacs.7b12777. link
(ChemViews以“Making the Perfect Silver Nanocluster”为题亮点评述各向异性组装银簇的研究工作, DOI: 10.1002/chemv.201800005. http://www.chemistryviews.org/details/ezine/10840025/Making_the_Perfect_Silver_Nanocluster.html)
[A2] S. S. Zhang, F. Alkan, H. F. Su, C. M. Aikens,* C. H. Tung, D. Sun,* [Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands, J. Am. Chem. Soc., 141, (2019) 4460-4467. DOI: 10.1021/jacs.9b00703. link
(Science以“A core-shell silver cluster”为题亮点评述, Science, 6433, (2019) 1297-1298. http://science.sciencemag.org/content/363/6433/1297.4?rss=1; ChemViews以“Ag Nanocluster with Both Inorganic and Organic Ligands”为题进行了新闻报道. https://www.chemistryviews.org/details/news/11139228/Ag_Nanocluster_with_Both_Inorganic_and_Organic_Ligands.html)
[A3] Z. Wang, J. W. Liu, H. F. Su, Q. Q. Zhao, M. Kurmoo, X. P. Wang, C. H Tung, D. Sun,* L. S. Zheng, Chalcogens-Induced Ag6Z4@Ag36 (Z = S or Se) Core–Shell Nanoclusters: Enlarged Tetrahedral Core and Homochiral Crystallization, J. Am. Chem. Soc. 141, (2019) 17884-17890. DOI: 10.1021/jacs.9b09460. link
[A4] B. L. Han, Z. Liu, L. Feng, Z. Wang, R. K. Gupta, C. M. Aikens,* C. H. Tung, D. Sun,* Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel, J. Am. Chem. Soc., 142, (2020) 5834-5841. DOI: 10.1021/jacs.0c01053. link
[A5] Y. M. Su, Z. Wang, C. H. Tung, D. Sun,* S. Schein, Keplerate Ag192 Cluster with 6 Silver and 14 Chalcogenide Octahedral and Tetrahedral Shells, J. Am. Chem. Soc., 143, (2021), 13235-13244. DOI: 10.1021/jacs.1c05664. link
[A6] S.-S. Zhang, S. Havenridge, C. K. Zhang, Z. Wang, L. Feng, Z.-Y. Gao, C. M. Aikens, C.-H. Tung, Di Sun,* Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster, J. Am. Chem. Soc., 144, (2022), 18305-18314. DOI: 10.1021/jacs.2c06093. link
[A7] W. Chen,# Z. Wang,# Q. Wang, K. El-Yanboui, K. Tan, H. M. Barkholtz, D.-J. Liu, P. Cai, L. Feng, Y. Li, J.-S. Qin, S. Yuan,* D. Sun,* H.-C. Zhou,* Monitoring the Activation of Open Metal Sites in [FexM3–x(μ3-O)] Cluster-Based Metal–Organic Frameworks by Single-Crystal X-ray Diffraction. J. Am. Chem. Soc., 145, (2023), 4736-4745. link
[A8] T. Jia,# Z. J. Guan,# C. Zhang,# X. Z. Zhu, Y. X. Chen, Q. Zhang, Y. Yang,* D. Sun,* An Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission, J. Am. Chem. Soc., 145, (2023), 10355-10363. DOI: 10.1021/jacs.3c02215. link
[A9] K. Sheng,# Z. Wang,# L. Li, Z.-Y. Gao, C.-H. Tung, D. Sun,* Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4– Templated 48-Nuclei Silver(I) Cluster, J. Am. Chem. Soc., 145, (2023), 10595-10603. DOI: .10.1021/jacs.3c00321. link
[A10] Z. Wang,# H. F.Su,# C. H. Tung, D. Sun,* L. S. Zheng, Deciphering synergetic core-shell transformation from [Mo6O22@Ag44] to [Mo8O28@Ag50], Nat. Commun., 9, (2018) 4407. DOI: 10.1038/s41467-018-06755-4. link
[A11] Z. Wang, H. F. Su, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel, Nat. Commun., 9, (2018) 2094. DOI: 10.1038/s41467-018-04499-9. link
[A12] Z. Wang, H. F. Su, Y. W. Gong, Q. P. Qu, Y. F. Bi, C. H. Tung, D. Sun,* L. S. Zheng, A Hierarchically Assembled 88-Nuclei Silver-Thiacalix[4]arene Nanocluster, Nat. Commun., 11, (2020) 308. DOI: 10.1038/s41467-019-13682-5. link
[A13] Y. M. Su,# Z. Wang,# S. Schein,* C. H. Tung, D. Sun,* A Keplerian Ag90 Nest of Platonic and Archimedean Polyhedra in Different Symmetry Groups, Nat. Commun., 11, (2020) 3316. DOI: 10.1038/s41467-020-17198-1. link (英国著名科普杂志Research Outreach以“Keplerian nest of polyhedral structures in different symmetry groups”为题全文评述:https://researchoutreach.org/articles/keplerian-nest-polyhedral-structures-different-symmetry-groups/)
[A14] X. Q. Liang, Y. Z. Li, Z. Wang, S. S. Zhang, Y. C. Liu, Z. Z. Cao, L. Feng, Z. Y. Gao, Q. W. Xue, C. H. Tung, D. Sun,* Revealing the Chirality Origin and Homochirality Crystallization of Ag14 Nanocluster at the Molecular Level, Nat. Commun., 12, (2021), 4966. DOI: 10.1038/s41467-021-25275-2. link
[A15] Z. Wang, Y. J. Zhu, Y. Z. Li, G. L. Zhuang, K. P. Song, Z. Y. Gao, J. M. Dou, M. Kurmoo, C. H. Tung, D. Sun,* Nuclearity Enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D Network Formation Driven by Bipyridines, Nat. Commun., 13, (2022) 1802. DOI: 10.1038/s41467-022-29370-w. link
[A16] J. Y. Liu, F. Alkan, Z. Wang, Z. Y. Zhang, M. Kurmoo, Z. Yan, Q. Q. Zhao, C. M. Aikens*, C. H. Tung, D. Sun*, Different Silver Nanoparticles in One Crystal: Ag210(iPrPhS)71(Ph3P)5Cl and Ag211(iPrPhS)71(Ph3P)6Cl, Angew. Chem. Int. Ed., 58 (2019) 195-199. DOI: 10.1002/anie.201810772. link
[A17] J. W. Liu,# Z. Wang,# Y. M. Chai, M. Kurmoo, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun*, Core Modulation of 70-Nuclei Core-Shell Silver Nanoclusters, Angew. Chem. Int. Ed., 58 (2019) 6276-6279. DOI: 10.1002/anie.201900568. link
[A18] Y. Yang*, T. Jia, Y.-Z. Han, Z.-A. Nan, S.-F. Yuan, F.-L. Yang , D. Sun*, An Unprecedented All-Alkynyl Protected 74-Nuclei Silver(I)-Copper(I)-Oxo Nanocluster: Oxo-Induced Hierarchical Bimetal Aggregation and Anisotropic Surface, Angew. Chem. Int. Ed., 58 (2019) 12280-12285. DOI: 10.1002/anie.201906538. link
[A19] Z. Xie,# P. Sun,# Z. Wang, H. Li,* L. Yu, D. Sun*, M. Chen, Y. Bi, X. Xin,* J. Hao, Metal-Organic Gels from Silver Nanoclusters with Aggregation-Induced Emission and Fluorescence-to-Phosphorescence Switching, Angew. Chem. Int. Ed., 59 (2020) 9922-9927. DOI: 10.1002/anie.201912201. link
[A20] C. Deng,# C. Sun,# Z. Wang,# Y. Tao, Y. Chen, J. Lin, G. Luo,* B. Lin, D. Sun,* L. Zheng, A Sodalite-Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster, Angew. Chem. Int. Ed., 59 (2020) 12659-12663. DOI: 10.1002/anie.202003143. link
[A21] M. Zhao, S. Huang, Q. Fu, W. Li, R. Guo, Q. Yao, F. Wang, P. Cui,* C. H. Tung, D. Sun,* Ambient Chemical Fixation of CO2 Using a Robust Ag27 Cluster-Based Two-Dimensional Metal-Organic Framework, Angew. Chem. Int. Ed., 59 (2020) 20031-20036. DOI: 10.1002/anie.202007122. link
[A22] W. J. Zhang, Z. Liu, K. P. Song, C. M. Aikens, S. S. Zhang, Z. Wang, C. H. Tung, D. Sun,* A 34-Electron Superatom Ag78 Cluster with Regioselective Ternary Ligands Shells and Its 2D Rhombic Superlattice Assembly, Angew. Chem. Int. Ed., 60, (2021) 4231-4237. DOI: 10.1002/anie.202013681. link
[A23] P. P. Sun, B. L. Han, H. G. Li, C. K. Zhang, X. Xin, J. M. Dou, Z. Y. Gao, D. Sun,* Real-Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self-Assembly of Atom-Precise Cu8 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022), e202200180. DOI: 10.1002/anie.202200180. link
[A24] Z. Wang,# L. Li,# L. Feng, Z. Y. Gao, C. H. Tung, L. S. Zheng, D. Sun,* Solvent-Controlled Condensation of [Mo2O5(PTC4A)2]6- Metalloligand in Stepwise Assembly of Hexagonal and Rectangular Ag18 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022), e202200823. DOI: 10.1002/anie.202200823. link
[A25] Z. Wang, F. Alkan, C. M. Aikens, M. Kurmoo, Z. Y. Zhang, K. P. Song, C. H. Tung, D. Sun,* An Ultrastable 155-Nuclei Silver Nanocluster Protected by Thiacalix[4]arene and Cyclohexanethiol for Photothermal Conversion, Angew. Chem. Int. Ed., 61, (2022), e202206742. DOI: 10.1002/anie.202206742. link
[A26] Z.-R. Yuan, Z. Wang, B.-L. Han, C.-K. Zhang, S.-S. Zhang, Z.-Y. Zhu, J.-H. Yu, T.-D. Li, Y.-Z. Li,* C.-H. Tung, D. Sun,* Ag22 Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification, Angew. Chem. Int. Ed., 61, (2022), e202211628. DOI: 10.1002/anie.202211628. link
[A27] Q. Hu,*,# C. Zhang,# X. Wu, G. Liang, L. Wang, X. Niu, Z. Wang, W.-D. Si, Y. Han, R. Huang, J. Xiao,* D. Sun,* Highly Effective Hybrid Copper(I) Iodide Cluster Emitter with Negative Thermal Quenched Phosphorescence for X-Ray Imaging, Angew. Chem. Int. Ed., 62, (2023), e202217784. DOI: 10.1002/anie.202217784. link
[A28] G. L. Dong#, Z. H. Pan#, B. L. Han#, Y. W. Tao, X. Chen, G. G. Luo*, P. P. Sun, C. F. Sun, D. Sun,* Multi-layer 3D Chirality and Double-Helical Assembly in a Copper Nanocluster with a Triple-Helical Cu15 Core, Angew. Chem. Int. Ed., (2023). Accepted article.
[A29] W. D. Si,# C. Zhang,# M. Zhou, W. D. Tian, Z. Wang, Q. Hu, K. P. Song, L. Feng, X. Q. Huang, Z. Y. Gao, C. H.Tung, D. Sun,* Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au20 nanocluster, Sci. Adv. 9, (2023), eadg3587. DOI: 10.1126/sciadv.adg3587.link
[A30] Y. Chu, L. Guo, B. Xi, Z. Feng, F. Wu, Y. Lin*, J. Liu, D. Sun*, J. Feng, Y. Qian, S. Xiong,*, Embedding MnO@Mn3O4 Nanoparticlesin an N-Doped-Carbon Framework Derived from Mn-Organic Clusters for Efficient Lithium Storage, Adv. Mater., 30, (2018) 1704244. link
[A31] P. Wang, T. Xu, B. Xi, J. Yuan, N. Song, D. Sun,* S. Xiong,* A Zn8 Double-Cavity Metallacalix[8]arene as Molecular Sieve to Realize Self-Cleaning Intramolecular Tandem Transformation of Li−S Chemistry, Adv. Mater., 34, (2022), 2207689. DOI: 10.1002/adma.202207689. link
其他代表性论文(2018之前):
[A32] Z. Wang,# H. F.Su,# Y. Z. Tan, S. Schein,* S. C.Lin, W. Liu, S. A. Wang,W. G. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Assembly of silver Trigons into a buckyball-like Ag180 nanocage, Proc Natl Acad Sci USA 114, (2017) 12132-12137. DOI:10.1073/pnas.1711972114. link
[This article is a PNAS Direct Submission]
(Nature Comm 副主编Ariane在Nature Review Chemistry 以“Polynuclear complexes: Buckyball's silver cousin”为题专刊亮点评述哥德堡银笼的研究工作; Nature Reviews Chemistry, doi:10.1038/s41570-017-0102.https://www.nature.com/articles/s41570-017-0102.)
[A33] Y. K. Deng,# H. F.Su,# J. H. Xu,W. G. Wang, M. Kurmoo, S. C. Lin, Y. Z. Tan, J. Jia, D. Sun,* L. S. Zheng, Hierarchical Assembly of a {MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism. J. Am. Chem. Soc., 138, (2016) 1328-1334. DOI: 10.1021/jacs.5b11736. link
[A34] L. Y. Guo,# H. F.Su,# M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Core−Shell {Mn7⊂(Mn,Cd)12} Assembled from Core {Mn7} Disc, J. Am. Chem. Soc., 139, (2017) 14033-14036. DOI: 10.1021/jacs.7b08679. link
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2023年
[1] W. Chen,# Z. Wang,# Q. Wang, K. El-Yanboui, K. Tan, H. M. Barkholtz, D.-J. Liu, P. Cai, L. Feng, Y. Li, J.-S. Qin, S. Yuan,* D. Sun,* H.-C. Zhou,* Monitoring the Activation of Open Metal Sites in [FexM3–x(μ3-O)] Cluster-Based Metal–Organic Frameworks by Single-Crystal X-ray Diffraction. J. Am. Chem. Soc., 145, (2023), 4736-4745.
[2] T. Jia,# Z. J. Guan,# C. Zhang,# X. Z. Zhu, Y. X. Chen, Q. Zhang, Y. Yang,* D. Sun,* An Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission, J. Am. Chem. Soc., 145, (2023), 10355-10363. DOI: 10.1021/jacs.3c02215.
[3] K. Sheng,# Z. Wang,# L. Li, Z.-Y. Gao, C.-H. Tung, D. Sun,* Solvent-Mediated Separation and Reversible Transformation of 1D Supramolecular Polymorphs Built from [W10O32]4– Templated 48-Nuclei Silver(I) Cluster, J. Am. Chem. Soc., 145, (2023), 10595-10603. DOI: .10.1021/jacs.3c00321.
[4] Q. Hu,*,# C. Zhang,# X. Wu, G. Liang, L. Wang, X. Niu, Z. Wang, W.-D. Si, Y. Han, R. Huang, J. Xiao,* D. Sun,* Highly Effective Hybrid Copper(I) Iodide Cluster Emitter with Negative Thermal Quenched Phosphorescence for X-Ray Imaging, Angew. Chem. Int. Ed., 62, (2023), e202217784. DOI: 10.1002/anie.202217784.
[5] W. D. Si,# C. Zhang,# M. Zhou, W. D. Tian, Z. Wang, Q. Hu, K. P. Song, L. Feng, X. Q. Huang, Z. Y. Gao, C. H.Tung, D. Sun,* Two triplet emitting states in one emitter: Near-infrared dual-phosphorescent Au20 nanocluster, Sci. Adv. 9, (2023), eadg3587. DOI: 10.1126/sciadv.adg3587.
[6] K. Sheng, X. Q. Huang, R. Wang, W. Z. Wang, Z. Y. Gao, C. H. Tung, D, Sun,* Decagram-Scale Synthesis of Heterometallic Ag/Ti Cluster as Sustainable Catalyst for Selective Oxidation of Sulfides, J. Catal., 417, (2023), 185-193. DOI: 10.1016/j.jcat.2022.12.007.
[7] R. K. Gupta, L. Li, Z. Wang, B. L. Han, L. Feng, Z. Y. Gao, C. H. Tung, D, Sun,* Regulating the assembly and expansion of the silver cluster from the Ag37 to Ag46 nanowheel driven by heteroanions, Chem. Sci., 14, (2023), 1138-1144. DOI: 10.1039/d2sc06436g.
[8] X. Huang,* S. Liu, G. Liu, Y. Tao, C. Wang, Y. Zhang, Z. Li, H. Wang, Z. Zhou,* G. Shen, Z. Xue, D. Sun,* An Unprecedented 2-fold Interpenetrated lvt Open Framework Built from Zn6 Ring Seamed Trivacant Polyoxotungstates Used for Photocatalytic Synthesis of Pyridine Derivatives, Appl. Catal. B Environ., 323, (2023), 122134. DOI: 10.1016/j.apcatb.2022.122134.
[9] X. Huang,*,# S. Liu,# Z. Zhou, H. Zhang, Z. Gao, G. Shen, H. Wang, Z. Wang,* Q. Yao, D. Sun,* Tail of imidazole regulated assembly of two robust sandwich-type polyoxotungstates-based open frameworks with efficient visiblewhite-light-driven catalytic oxidation of sulfides, Inorg. Chem. Front., 10, (2023), 1465-1474. DOI:10.1039/D3QI00018D.
[10] G. L. Dong#, Z. H. Pan#, B. L. Han#, Y. W. Tao, X. Chen, G. G. Luo*, P. P. Sun, C. F. Sun, D. Sun,* Multi-layer 3D Chirality and Double-Helical Assembly in a Copper Nanocluster with a Triple-Helical Cu15 Core, Angew. Chem. Int. Ed., (2023). Accepted article.
[11] R. Wang, K. Sheng,* X. Huang,* M. Azam, C.-H. Tung, D. Sun,* A Robust Ag/Ti Nanocluster as an Efficient Heterogeneous Lewis Acid-Base Catalyst for C-C Bond Formation, J. Catal., (2023) Accepted article. DOI: 10.1016/j.jcat.2023.05.013.
2022年
[1] Z. Wang, F. Alkan, C. M. Aikens, M. Kurmoo, Z. Y. Zhang, K. P. Song, C. H. Tung, D. Sun,* An Ultrastable 155-Nuclei Silver Nanocluster Protected by Thiacalix[4]arene and Cyclohexanethiol for Photothermal Conversion, Angew. Chem. Int. Ed., 61, (2022), e202206742. DOI: 10.1002/anie.202206742.
[2] Z. Wang,# L. Li,# L. Feng, Z. Y. Gao, C. H. Tung, L. S. Zheng, D. Sun,* Solvent-Controlled Condensation of [Mo2O5(PTC4A)2]6- Metalloligand in Stepwise Assembly of Hexagonal and Rectangular Ag18 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022), e202200823. DOI: 10.1002/anie.202200823.
[3] P. P. Sun, B. L. Han, H. G. Li, C. K. Zhang, X. Xin, J. M. Dou, Z. Y. Gao, D. Sun,* Real-Time Fluorescent Monitoring of Kinetically Controlled Supramolecular Self-Assembly of Atom-Precise Cu8 Nanoclusters, Angew. Chem. Int. Ed., 61, (2022), e202200180. DOI: 10.1002/anie.202200180.
[4] Z. Wang, Y. J. Zhu, Y. Z. Li, G. L. Zhuang, K. P. Song, Z. Y. Gao, J. M. Dou, M. Kurmoo, C. H. Tung, D. Sun,* Nuclearity Enlargement from [PW9O34@Ag51] to [(PW9O34)2@Ag72] and 2D and 3D Network Formation Driven by Bipyridines, Nat. Commun., 13, (2022) 1802. DOI: 10.1038/s41467-022-29370-w.
[5] S.-S. Zhang, S. Havenridge, C. K. Zhang, Z. Wang, L. Feng, Z.-Y. Gao, C. M. Aikens, C.-H. Tung, Di Sun,* Sulfide Boosting Near-Unity Photoluminescence Quantum Yield of Silver Nanocluster, J. Am. Chem. Soc., 144, (2022), 18305-18314. DOI: 10.1021/jacs.2c06093.
[6] Z.-R. Yuan, Z. Wang, B.-L. Han, C.-K. Zhang, S.-S. Zhang, Z.-Y. Zhu, J.-H. Yu, T.-D. Li, Y.-Z. Li,* C.-H. Tung, D. Sun,* Ag22 Nanoclusters with Thermally Activated Delayed Fluorescence Protected by Ag/Cyanurate/Phosphine Metallamacrocyclic Monolayers through In-Situ Ligand Transesterification, Angew. Chem. Int. Ed., 61, (2022), e202211628. DOI: 10.1002/anie.202211628.
[7] P. Wang, T. Xu, B. Xi, J. Yuan, N. Song, D. Sun,* S. Xiong,* A Zn8 Double-Cavity Metallacalix[8]arene as Molecular Sieve to Realize Self-Cleaning Intramolecular Tandem Transformation of Li−S Chemistry, Adv. Mater., 34, (2022), 2207689. DOI: 10.1002/adma.202207689.
[8] R. -K. Gupta, M. Riaz, M. Ashafaq, Z. Y. Gao, R. S. Verma, D. C. Li, P. Cui, C. H. Tung, D. Sun,* Adenine-incorporated metal-organic frameworks, Coord. Chem. Rev., 428, (2022), 214558. DOI: 10.1016/j.ccr.2020.214558.
[9] Z. Wang, H. F. Su, L. P. Zhang, J. M. Dou, C. H. Tung, D. Sun,* L. S Zheng, Stepwise Assembly of Ag42 Nanocalices Based on a MoVI-Anchored Thiacalix[4]arene Metalloligand, ACS Nano., 16, (2022), 4500-4507. DOI: 10.1021/acsnano.1c10905.
[10] C. Zhang, Z. Wang, W. D. Si, L. Wang, J. M. Dou, Z. Y. Gao, C. H. Tung, D. Sun,* Solvent-Induced Isomeric Cu13 Nanoclusters: Chlorine to Copper Charge Transfer Boosting Molecular Oxygen Activation in Sulfide Selective Oxidation, ACS Nano., 16, (2022), 9598-9607. DOI: 10.1021/acsnano.2c02885.
[11] S. S. Zhang, J. Y. Chen, K. Li, J. D. Yuan, H. F. Su, Z. Wang, M. Kurmoo, Y. Z. Li, Z. Y. Gao, C. H. Tung, D. Sun,* L. S. Zheng, Janus Cluster: Asymmetric Coverage of a Ag43 Cluster on the Symmetric Preyssler P5W30 Polyoxometalate, Chem. Mater., 33, (2022),9708-9714. DOI: 10.1021/acs.chemmater.1c03418.
[12] K. Sheng,# W. D. Si,# R. Wang, W. Z. Wang, J, Dou, Z. Y. Gao, L. K. Wang, C. H. Tung, D. Sun,* Keggin-Type Tridecanuclear Europium-Oxo Nanocluster Protected by Silsesquioxanes, Chem. Mater., 34, (2022), 4186-4194. DOI: 10.1021/acs.chemmater.2c00627.
[13] Y. F. Hou,# Y. Q. Wang,# T. Y. Xu,# Z. Wang, W. D. Tian, D. Sun,* X. Y. Yu, P. Y. Xing,* J. L. Shen, X. Xin,* J. C. Hao, Synergistic Multiple Bonds Induced Dynamic Self-Assembly of Silver Nanoclusters into Lamellar Frameworks with Tailored Luminescence, Chem. Mater., 34, (2022), 8013-8021. DOI: 10.1021/acs.chemmater.2c01939.
[14] N. Feng, Z. Wang, D. Sun,* P. P. Sun, X. Xin,* X. Cheng, H. Li,* Circularly Polarized Phosphorescence from Cocrystallization of Atomic Precise Silver Nanoclusters with Tartaric Acid, Adv. Optical Mater., 2022, 2102319. DOI: 10.1002/adom.202102319.
[15] Y. M. Su, Z. Z. Cao, L. Feng, Q. W. Xue, C. H. Tung, Z. Y. Gao, D. Sun,* Thermally Hypsochromic or Bathochromic Emissions? The Silver Nuclei Does Matter, Small, 18, (2022), 2104524. DOI: 10.1002/smll.202104524.
[16] W. D. Si,# K. Sheng,# C. Zhang, Z. Wang, S. S. Zhang, L. Feng, Q. W. Xue, Z. Y. Gao,C. H. Tung, D. Sun,* Bicarbonate Insertion Triggered Self-Assembly of Chiral Octa-Gold Nanoclusters into Helical Superstructures in the Crystalline State, Chem. Sci., 13, (2022),10523-10531. DOI: 10.1039/d2sc03463h.
[17] Z. Wang, M. D. Li, J. Y. Shi, H. F. Su, J. W. Liu, L. Feng, Z. Y. Gao, Q. W. Xue, C. H. Tung, D. Sun,* L. S Zheng, In Situ Capture of a Ternary Supramolecular Cluster in a 58-Nuclei Silver Supertetrahedron, CCS Chem, 4, (2022), 1788-1795. DOI: 10.31635/ccschem.021.202100880.
[18] H. Zhao,# R. -K. Gupta,# W. Zhang, J. Jia, Q. Yu, Z. Y. Gao, G. L. Zhuang,* D. C. Li, X. P. Wang,* C. -H. Tung, D. Sun,* Facile one-pot synthesis of a novel all-carbon stair containing dimerized pentalene core from alkyne, Chin. Chem. Lett., 33, (2022), 2047-2051. DOI: 10.1016/j.cclet.2021.10.036.
[19] T. Li, P. Cui,* D. Sun,* Uncoordinated Hexafluorosilicates in a Microporous Metal-Organic Framework Enabled C2H2/CO2 Separation, Inorg. Chem., 61, (2022) 4251-4256. DOI: 10.1021/acs.inorgchem.2c00409.
[20] K. Sheng,∗ R. Wang, A. Bilyachenko, V. Khrustalev, M. Jagodič, Z. Jagličić,∗ Z. Li, L. Wang, C. Tung, D. Sun,∗ Tridecanuclear Gd(III)-Silsesquioxane: Synthesis, Structure, and Magnetic Property, ChemPhysMater, 1, (2022), 247-251. DOI: 10.1016/j.chphma.2022.04.008.
[21] J. Zheng, S. Fan, S. Liu, G. Shen, W.-D. Si, X. Dong, X. Huang,∗ Y. Zhang,∗ Q. Yao, Z. Li, D. Sun,∗ In situ Ball-Milling Gram-Scale Preparation of Polyoxoniobate-Intercalated MgAl-layered Double Hydroxides for Selective Aldol and Michael Addition Cascade Reactions, Inorg. Chem. Front., 9, (2022), 5607. DOI:10.1039/d2qi01167k.
2021年
[1] W. J. Zhang, Z. Liu, K. P. Song, C. M. Aikens, S. S. Zhang, Z. Wang, C. H. Tung, D. Sun,* A 34-Electron Superatom Ag78 Cluster with Regioselective Ternary Ligands Shells and Its 2D Rhombic Superlattice Assembly, Angew. Chem. Int. Ed., 60, (2021) 4231-4237. DOI: 10.1002/anie.202013681. (Dedicated to the 100th anniversary of Xiamen University)
[2] Y. M. Su, Z. Wang, C. H. Tung, D. Sun,* S. Schein, Keplerate Ag192 Cluster with 6 Silver and 14 Chalcogenide Octahedral and Tetrahedral Shells, J. Am. Chem. Soc., 143, (2021), 13235-13244. DOI: 10.1021/jacs.1c05664.
[3] X. Q. Liang, Y. Z. Li, Z. Wang, S. S. Zhang, Y. C. Liu, Z. Z. Cao, L. Feng, Z. Y. Gao, Q. W. Xue, C. H. Tung, D. Sun,* Revealing the Chirality Origin and Homochirality Crystallization of Ag14 Nanocluster at the Molecular Level, Nat. Commun., 12, (2021), 4966. DOI: 10.1038/s41467-021-25275-2.
[4] C. Sun, B. K. Teo, C. Deng, J. Lin, G. Luo,* C. H. Tung, D. Sun,* Hydrido-coinage-metal clusters: rational design, synthetic protocols and structural characteristics, Coord. Chem. Rev., 427, (2021), 213576. DOI: 10.1016/j.ccr.2020.213576.
[5] B. L. Han, Z. Wang, R. K. Gupta, L. Feng, S. N. Wang, M. Kurmoo, Z. Y. Gao, S. Schein, C. H. Tung, and D. Sun,* Precise Implantation of an Archimedean Ag@Cu12 Cuboctahedron into a Platonic Cu4(bis(diphenylphosphino)hexane)6 Tetrahedron. ACS Nano., 15, (2021), 8733-8741. DOI: 10.1021/acsnano.1c00942.
[6] W. D. Si,# Y. Z. Li,# S. S. Zhang, S. Wang, L. Feng, Z. Y. Gao, C. H. Tung, D. Sun,* Toward Controlled Syntheses of Diphosphine-Protected Homochiral Gold Nanoclusters through Precursor Engineering. ACS Nano., 15, (2021), 16019-16029. DOI: 10.1021/acsnano.1c04421.
[7] Y. Bi,# Z. Wang,# T. Liu, D. Sun,* N. Godbert, H. Li,* J. Hao, X. Xin*, Supramolecular Chirality from Hierarchical Self-Assembly of Atomically Precise Silver Nanoclusters Induced by Secondary Metal Coordination. ACS Nano., 15, (2021), 15910-15919. DOI: 10.1021/acsnano.1c03824.
[8] Z.-L. Qiu, M.-B. He, K.-S. Chu, C. Tang, X.-W. Chen, L. Zhu, L.-P. Zhang, D. Sun,* J. Qian,* and Y.-Z. Tan*, Well-defined Segment of Carbon Nanotube with Bright Red Emission for Three-Photon Fluorescence Imaging of Cerebrovascular, Adv. Optical Mater. (2021), 2100482. DOI: 10.1002/adom.202100482.
[9] Y. M. Su, B. Q. Ji, F. Shao,* S. S. Zhang, M. Jagodič, Z. Jagličić, Z. Y. Gao, J. M. Dou, D. Sun,* Carboxylic Acid Tuned Nickel(II) Clusters: Syntheses, Structures, Solution Behaviours and Magnetic Properties, Dalton. Trans., 50, (2021) 4355-4362. DOI: 10.1039/d1dt00165e.
[10] Y. M. Su, B. Q. Ji, Z. Wang, S. S. Zhang, L. Feng, Z. Y. Gao, Y. W. Li, C. H. Tung, D. Sun,* L. S. Zheng, Anionic Passivation Layer Assisted Trapping of an Icosahedral Ag13 Kernel in a Truncated Tetrahedral Ag89 Nanocluster, Sci. China Chem., 64, (2021) 1482-1486. DOI: 10.1007/s11426-021-1025-8.
[11] Z. Wang,# M. Ashafaq,# Y. F. Lu, L. Feng, M. Kurmoo, H. Liu,* Z. Y. Gao, Y. W. Li, D. Sun,* Silica-Organometallic One-Dimensional Hybrid Employing a Ag-πC═C Bond Connecting Alternating Ag4(NO3)4 and Octavinylsilsesquioxane, Inorg. Chem., 60, (2021) 2899-2904. DOI: 10.1021/acs.inorgchem.1c00160.
[12] S. S. Zhang,# Y. Z. Li,# L. Feng, Q. W. Xue, Z. Y. Gao, C. H. Tung, D. Sun,* Octagold selenido nanoclusters: Significance of surface ligands on tuning geometric and electronic structure of Au8Se2 kernel, Nano. Res., 14, (2021), 3343-3351. DOI: 10.1007/s12274-021-3558-x. (Dedicated to Professor Yitai Qian on the occasion of his 80th birthday)
[13] Y. Yuan,# K. Sheng,# G. Zhuang,# Q. Li,# C. Dou, Q.-J. Fang, W.-W. Zhan, H. Gao, D. Sun,* and X. Han* Collaboratively Boosting Charge Transfer and CO2 Chemisorption of SnO2 to Selectively Reduce CO2 to HCOOH, Chem. Commun., 57, (2021), 8636-8639. DOI: 10.1039/d1cc01818c.
[14] S. S. Zhang, R. C. Liu, X. C. Zhang, L. Feng, Z. Y. Gao, C. H. Tung and D. Sun,* Core engineering of paired core-shell silver nanoclusters. Sci. China Chem., 64, (2021), 2118-2124. DOI: 10.1007/s11426-021-1060-3.
[15] K. Sheng, R. Wang, X. Tang, M. Jagodič,* Z. Jagličić, L. Pang, J.-M. Dou, Z.-Y. Gao, H.-Y. Feng,* C.-H. Tung, D. Sun,* A Carbonate-Templated Decanuclear Mn Nanocage with Two Different Silsesquioxane Ligands, Inorg. Chem., 60, (2021) 14866-14871. DOI: 10.1021/acs.inorgchem.1c02190.
[16] Y. M. Su,# X. Y. Li,# Z. Wang, Z. Y. Gao, X. Q. Huang, C. H. Tung, D. Sun,* Structural rearrangement of Ag60 nanocluster endowing different luminescence performances, J. Chem. Phys., 155, (2021) 234303. DOI: 10.1063/5.0070138.
[17] K. Sheng, Y.-N. Liu, R. K. Gupta,* M. Kurmoo, D. Sun,* Arylazopyrazole-Functionalized Photoswitchable Octanuclear Zn(II)-Silsesquioxane Nanocage, Sci. China Chem., 64, (2021), 419-425. DOI: 10.1007/s11426-020-9886-5.
[18] Q. L. Guo,# B. L. Han,# C. F. Sun,# Z. Wang, Y. Tao,* J. Q. Lin, G. G. Luo,* C. H. Tung, Z. Y. Gao, D. Sun,* Observation of a bcc-like framework in polyhydrido copper nanoclusters, Nanoscale, 13, (2021), 19642-19649. DOI: 10.1002/D1NR05567D.
2020年
[1] Z. Xie,# P. Sun,# Z. Wang, H. Li,* L. Yu, D. Sun*, M. Chen, Y. Bi, X. Xin,* J. Hao, Metal-Organic Gels from Silver Nanoclusters with Aggregation-Induced Emission and Fluorescence-to-Phosphorescence Switching, Angew. Chem. Int. Ed., 59 (2020) 9922-9927. DOI: 10.1002/anie.201912201.
[2] Z. Wang, H. F. Su, Y. W. Gong, Q. P. Qu, Y. F. Bi, C. H. Tung, D. Sun,* L. S. Zheng, A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster, Nat. Commun., 11, (2020) 308. DOI: 10.1038/s41467-019-13682-5.
[3] B. L. Han, Z. Liu, L. Feng, Z. Wang, R. K. Gupta, C. M. Aikens,* C. H. Tung, D. Sun,* Polymorphism in Atomically Precise Cu23 Nanocluster Incorporating Tetrahedral [Cu4]0 Kernel, J. Am. Chem. Soc., 142, (2020) 5834-5841. DOI: 10.1021/jacs.0c01053.
[4] C. Deng,# C. Sun,# Z. Wang,# Y. Tao, Y. Chen, J. Lin, G. Luo,* B. Lin, D. Sun,* L. Zheng, A Sodalite-Type Silver Orthophosphate Cluster in a Globular Silver Nanocluster, Angew. Chem. Int. Ed., 59 (2020) 12659-12663. DOI: 10.1002/anie.202003143.
[5] Y. M. Su,# Z. Wang,# S. Schein,* C. H. Tung, D. Sun,* A Keplerian Ag90 Nest of Platonic and Archimedean Polyhedra in Different Symmetry Groups, Nat. Commun., 11, (2020) 3316. DOI: 10.1038/s41467-020-17198-1. (英国著名科普杂志Research Outreach以“Keplerian nest of polyhedral structures in different symmetry groups”为题全文评述: https://researchoutreach.org/articles/keplerian-nest-polyhedral-structures-different-symmetry-groups/)
[6] M. Zhao, S. Huang, Q. Fu, W. Li, R. Guo, Q. Yao, F. Wang, P. Cui,* C. H. Tung, D. Sun,* Ambient Chemical Fixation of CO2 Using a Robust Ag27 Cluster-Based Two-Dimensional Metal-Organic Framework, Angew. Chem. Int. Ed., 59 (2020) 20031-20036. DOI: 10.1002/anie.202007122.
[7] H. T. Chen,# G. L. Zhuang,# L. M. Fan, X. T. Zhang,* L. N. Gao, D. Sun,* A highly robust heterometallic TbIII/NiII–organic framework for C2 hydrocarbon separation and capture, Chem. Commun., 56, (2020) 2047-2050. DOI:10.1039/c9cc09425c.
[8] Z. Wang, Q. P, Qu, H. F. Su, P. Huang,* R. K. Gupta, Q. Y. Liu, C. H Tung, D. Sun,* L. S Zheng, A novel 58-nuclei silver nanowheel encapsulating a subvalent Ag64+ kernel, Sci. China Chem., 63, (2020), 16-20. DOI: 10.1007/s11426-019-9638-3.
[9] K. Sheng,# L.M. Fan,# X.F. Tian, R.K. Gupta,* L. Gao, C. H. Tung, D. Sun,* Temperature-induced Sn(II) supramolecular isomeric frameworks as promising heterogeneous catalysts for cyanosilylation of aldehydes, Sci. China Chem., 63 (2020) 182-186. DOI: 10.1007/s11426-019-9621-x.
[10] Z. Wang, L. M. Zheng, M. Jagodič, Z. Jagličić,* H. F. Su,* J. X. Zhuang, X. P. Wang,* C. H. Tung, D. Sun,* L. S. Zheng, An Unprecedented Polyoxochromate [CrIII4CrVI8O36]12- Templated 56-Nuclei Silver Nanocluster, Inorg. Chem., 59, (2020) 3004-3011. DOI: 10.1021/acs.inorgchem.9b03365.
[11] X.-Q. Liang,# R. K. Gupta,# Y.-W. Li,* H.-Y. Ma, L.-N. Gao, C.-H. Tung, D. Sun,* Structural Diversity of Copper(I) Cluster-Based Coordination Polymers with Pyrazine-2-thiol Ligand, Inorg. Chem., 59, (2020) 2680-2688. DOI: 10.1021/acs.inorgchem.9b02919.
[12] Y.-N. Liu,# J.-L. Hou,# Z. Wang,# R. K. Gupta,* Z. Jagličić, M. Jagodič, W. G. Wang, C. H. Tung, D. Sun,* An Octanuclear Cobalt Cluster Protected by Macrocyclic Ligand: In Situ Ligand-Transformation-Assisted Assembly and Single-Molecule Magnet Behavior, Inorg. Chem., 59, (2020) 5683-5693. DOI: 10.1021/acs.inorgchem.0c00449.
[13] Y. Yuan,# K. Sheng,# S. Zeng, X. Han,* L. Sun, I. Loncaric,* W. Zhan, D. Sun,* Engineering Cu/TiO2@N-Doped C Interfaces Derived from an Atom-Precise Heterometallic CuII4TiIV5 Cluster for Efficient Photocatalytic Hydrogen Evolution, Inorg. Chem., 59, (2020) 5456-5462. DOI: 10.1021/acs.inorgchem.0c00084.
[14] P. Sun, Z. Wang, D. Sun,* H. Bai, Z. Zhu, Y. Bi, T. Zhao, X. Xin,* pH-guided self-assembly of silver nanoclusters with aggregation-induced emission for rewritable fluorescent platform and white light emitting diode application. J. Colloid Interf. Sci., 567, (2020), 235-242. DOI: 10.1016/j.jcis.2020.02.016.
[15] P. Sun,# Z. Wang,# Y. Bi, D. Sun,* T. Zhao, F. Zhao, W. Wang, X. Xin,* Self-Assembly-Driven Aggregation-Induced Emission of Silver Nanoclusters for Light Conversion and Temperature Sensing. ACS Appl. Nano Mater. 3, (2020), 2038-2046. DOI: 10.1021/acsanm.0c00135.
[16] Y. Zhang, D. Sun,* J. Shen, X. Xin,* Dynamic self-assembly of silver nanoclusters into luminescent nanotubes with controlled surface roughness: Scaffold of superhydrophobic materials. Appl. Surf. Sci. 514 (2020) 145913. DOI: 10.1016/j.apsusc.2020.145913.
[17] W. Muhammad , J. Ni, Z. Jagodič,* P. Cui,* L. N. Gao, D. Sun,* Synthesis, structure and magnetic properties of a decanuclear Fe(III)/oxo cluster. Chin. Chem. Lett., 31 (2020) 2503-2506. DOI: 10.1016/j.cclet.2020.01.031.
[18] G. G. Luo,* Q. L. Guo, Z. Wang, C. F. Sun, J. Q. Lin, D. Sun,* New Protective Ligands for Atomically Precise Silver Nanoclusters, Dalton. Trans., 49, (2020) 5406-5415. DOI: 10.1039/d0dt00477d. (Invited Frontiers Paper)
[19] Z. H. Pan, C. L. Deng, Z. Wang, J. Q. Lin, G. G. Luo,* D. Sun,* Silver clusters templated by homo- and hetero-anions, CrystEngComm, 22, (2020) 3736-3748. DOI: 10.1039/d0ce00489h. (Invited Highlight Paper)
[20] K. Sheng,# B. Q. Ji,# L. Feng, Y. M. Su, M. Jagodič,* Z. Jagličić and D. Sun,* A rod-like hexanuclear nickel cluster based on a bi(pyrazolyl-alcohol) ligand: structure, electrospray ionization mass spectrometry, magnetism and photocurrent response. New J. Chem., 44, (2020) 7152-7157. DOI: 10.1039/d0nj00959h.
[21] F. Yu,# B. Q. Ji,# M. Jagodič, Y. M. Su, S. S. Zhang, L. Feng, M. Kurmoo,* Z. Jagličić, D. Sun,* Copper(II)-assisted ligand fragmentation leading to three families of metallamacrocycle, Inorg. Chem., 59, (2020) 13524-13532. DOI: 10.1021/acs.inorgchem.0c01915.
[22] X. F. Tian, B. Q. Ji, L. Feng, K. Sheng,* Y. M. Su, M. Jagodič,* Z. Jagličić, Chen-Ho Tung, Di Sun,* Self-assembly of a nonanuclar NiII cluster via atmospheric CO2 fixation: synthesis, structure, collision-induced dissociation mass spectrometry and magnetic property, Dalton. Trans., 49, (2020) 10977-10982. DOI: 10.1039/D0DT01573C.
2019年
[1] J. Y. Liu, F. Alkan, Z. Wang, Z. Y. Zhang, M. Kurmoo, Z. Yan, Q. Q. Zhao, C. M. Aikens*, C. H. Tung, D. Sun*, Different Silver Nanoparticles in One Crystal: Ag210(iPrPhS)71(Ph3P)5Cl and Ag211(iPrPhS)71(Ph3P)6Cl, Angew. Chem. Int. Ed., 58 (2019) 195-199. DOI: 10.1002/anie.201810772.
[2] S. S. Zhang, F. Alkan, H. F. Su, C. M. Aikens,* C. H. Tung, D. Sun,* [Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands, J. Am. Chem. Soc., 141, (2019) 4460-4467. DOI: 10.1021/jacs.9b00703.
(Science以“A core-shell silver cluster”为题亮点评述, Science, 6433, (2019) 1297-1298. http://science.sciencemag.org/content/363/6433/1297.4?rss=1; ChemViews以“Ag Nanocluster with Both Inorganic and Organic Ligands”为题进行了新闻报道. https://www.chemistryviews.org/details/news/11139228/Ag_Nanocluster_with_Both_Inorganic_and_Organic_Ligands.html)
[3] J. W. Liu,# Z. Wang,# Y. M. Chai, M. Kurmoo, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* Core Modulation of 70-Nuclei Core-Shell Silver Nanoclusters, Angew. Chem. Int. Ed., 58 (2019) 6276-6279. DOI: 10.1002/anie.201900568. (Dedicated to Professor Lan-Sun Zheng on the occasion of his 65th birthday)
[4] Y. Yang*, T. Jia, Y.-Z. Han, Z.-A. Nan, S.-F. Yuan, F.-L. Yang , D. Sun*, An Unprecedented All-Alkynyl Protected 74-Nuclei Silver(I)-Copper(I)-Oxo Nanocluster: Oxo-Induced Hierarchical Bimetal Aggregation and Anisotropic Surface, Angew. Chem. Int. Ed., (2019) DOI: 10.1002/anie.201906538.
[5] Z. Wang, J. W. Liu, H. F. Su, Q. Q. Zhao, M. Kurmoo, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Chalcogens-Induced Ag6Z4@Ag36 (Z = S or Se) Core–Shell Nanoclusters: Enlarged Tetrahedral Core and Homochiral Crystallization, J. Am. Chem. Soc. 141, (2019) 17884-17890. DOI: 10.1021/jacs.9b09460.
[6] Y. M. Su,# Z. Wang,# G. L. Zhuang, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun*, Unusual fcc-structured Ag10 kernels trapped in Ag70 nanoclusters, Chem. Sci., 10, (2019) 564-568. DOI: 10.1039/c8sc03396j.
[7] Z. Wang, H. T. Sun, M. Kurmoo, Q. Y. Liu, G. L. Zhuang,* Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun*, Carboxylic acid stimulated silver shell isomerism in triple core-shell Ag84 nanocluster, Chem. Sci., 10, (2019) 4862-4867. DOI: 10.1039/C8SC05666H.
[8] S. S. Zhang,# R. D. Senanayake,# Q. Q. Zhao, H. F. Su,* C. M. Aikens,* X. P. Wang,* C. H. Tung, D. Sun,* L. S. Zheng, [Au18(dppm)6Cl4]4+: Phosphine-protected gold nanocluster with rich charge states, Dalton. Trans., 48, (2019) 3635-3640. DOI: 10.1039/C9DT00042A.
[9] B. Q. Ji,# H. F. Su,# M. Jagodič,# Z. Jagličić,* M. Kurmoo,* X. P. Wang,* C. H. Tung, Z. Z. Cao,* D. Sun,* Self-Organization into Preferred Sites by MgII, MnII , and MnIII in Brucite-Structured Mn19 Cluster, Inorg. Chem., 58, (2019) 3800-3806. DOI: 10.1021/acs.inorgchem.8b03406.
[10] A. Xie,# Z. H. Pan,# M. Yu, G. G. Luo,* D. Sun,* Photocatalytic hydrogen production from acidic aqueous solution in BODIPY-cobaloxime-ascorbic acid homogeneous system, Chin. Chem. Lett., 30, (2019) 225-228. DOI:10.1016/j.cclet.2018.05.003.
[11] K. Sheng, H. F. Lu,* A. B. Sun, Y. M. Wang,* Y. T. Liu, F. Chen, W. C. Bian, Y. Li, R. Kuang, D. Sun,* A naked-eye colorimetric sensor for chloroform, Chin. Chem. Lett., 30 (2019) 895-898. DOI:10.1016/j.cclet.2019.01.027.
[12] J. L. Shen, Z. Wang, C. X. Xia, D. Sun,* S. L. Yuan,* and X. Xin,* Amphiphilicity Regulation of AgI Nanoclusters: Self-Assembly and Its Application as a Luminescent Probe, Chem. Eur. J., 25, (2019) 4713-4721. DOI: 10.1002/chem.201805815.
[13] Y. N. Liu, H. F. Su, Y. W. Li,* Q. Y. Liu, Z. Jagličić, W. G. Wang,* C. H. Tung, D. Sun,* Space Craft-like Octanuclear Co(II)-Silsesquioxane Nanocages: Synthesis, Structure, Magnetic Properties, Solution Behavior, and Catalytic Activityfor Hydroboration of Ketones, Inorg. Chem., 58, (2019) 4574-4582. DOI: 10.1021/acs.inorgchem.9b00137.
[14] Z. Wang, Y. M. Sun, Q. P. Qu, Y. X. Liang, X. P. Wang,* Q. Y. Liu, M. Kurmoo, H. F. Su,* C. H. Tung, D. Sun,* Enclosing classical polyoxometallates in silver nanoclusters, Nanoscale, 11, (2019) 10927-10931. DOI: 10.1039/c9nr04045e.
[15] P. P. Sun, S. S. Zhang, Z. Y. Xiang, T. Zhao, D. Sun,* G. P. Zhang, M. J. Chen, K. K. Guo, X. Xin,* Photoluminescent sensing vesicle platform self-assembled by polyoxometalate and ionic-liquid-type imidazolium gemini surfactants for the detection of Cr3+ and MnO4- ions, J. Colloid Interf. Sci., 547, (2019) 60-68. DOI: 10.1016/j.jcis.2019.03.085.
[16] X. H. Cheng,# P. P. Sun,# S. S. Zhang, D. Sun,* B. L. Jiang, W. S. Wang, X. Xin,* Self-assembly of m-phenylelnediamine and polyoxometalate into hollow-sphere and core-in-hollow-shell nanostructures for selective adsorption of dyes, J. Mol. Liq., 287, (2019) 110982. DOI: 10.1016/j.molliq.2019.110982.
[17] Z. Wang, F.L. Yang, Y. Yang,* Q.Y. Liu, D. Sun,* Hierarchical multi-shell 66-nuclei silver nanoclusters trapping subvalent Ag6 kernels, Chem. Commun., 55, (2019) 10296. DOI: 10.1039/c9cc05044b.
[18] K. Sheng, X. F. Tian, M. Jagodič,* Z. Jagličić, N. Zhang,* Q. Y. Liu, C. H. Tung, D. Sun,* Synthesis, structure and magnetism of a novel CuII4TiIV5 heterometallic cluster, Chin. Chem. Lett., (2019) DOI: 10.1016/j.cclet.2019.05.050.
[19] Z. Wang,# H. Y. Zhuo,# A. Y. Hu, H. F. Su,* Q. Q Zhao,* X. P. Wang,* C. H. Tung, D. Sun,* Self-Assembly of A Novel Ag48 Cluster Encapsulating an Unprecedented [Mo8O28]8- Anion Template, Isr. J. Chem. 59, (2019), 59, 280-285. DOI: 10.1002/ijch.201800148.
[20] Z. Wang, R. K. Gupta,* G. G. Luo,* D. Sun,* Recent Progress in Inorganic Anions Templated Silver Nanoclusters: Synthesis, Structures and Properties, Chem. Rec. 20, (2019), 389-402. DOI: 10.1002/tcr.201900049.
[21]A. Xie,# Z. Wang,# L. P. Cheng, G. G. Luo*, Q. Y. Liu, D. Sun,* Cluster Linked Polyoxometalate including Ag(I)···H-C Anagostic Interactions , Eur. J. Inorg. Chem., 2019. 496-501. DOI: 10.1002/ejic.201800744.
[22] Z. Wang, H. F. Su, G. L. Zhuang, M. Kurmoo, C. H. Tung, D. Sun,* L. S Zheng, Carbonate–Water Supramolecule Trapped in Silver Nanoclusters Encapsulating Unprecedented Ag11 Kernel, CCS Chem., 1, (2019), 663-672. DOI: 10.31635/ccschem.019.20190058.
2018年
[1] J. W. Liu, L. Feng, H. F. Su, Z. Wang, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Anisotropic Assembly of Ag52 and Ag76 Nanoclusters, J. Am. Chem. Soc., 140, (2018) 1600-1603, DOI:10.1021/jacs.7b12777.
(ChemViews以“Making the Perfect Silver Nanocluster”为题亮点评述各向异性组装银簇的研究工作, DOI: 10.1002/chemv.201800005. http://www.chemistryviews.org/details/ezine/10840025/Making_the_Perfect_Silver_Nanocluster.html)
[2] Z. Wang, H. F. Su, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Trapping an octahedral Ag6 kernel in a seven-fold symmetric Ag56 nanowheel, Nat. Commun., 9, (2018) 2094. DOI: 10.1038/s41467-018-04499-9.
[3] Z. Wang,# H. F. Su,# C. H. Tung, D. Sun,* L. S. Zheng, Deciphering synergetic core-shell transformation from [Mo6O22@Ag44] to [Mo8O28@Ag50], Nat. Commun., 9, (2018) 4407. DOI: 10.1038/s41467-018-06755-4
[4] Y. Chu, L. Guo, B. Xi, Z. Feng, F. Wu, Y. Lin*, J. Liu, D. Sun*, J. Feng, Y. Qian, S. Xiong*, Embedding MnO@Mn3O4Nanoparticles in an N-Doped-Carbon Framework Derived from Mn-Organic Clustersfor Efficient Lithium Storage, Adv. Mater., 30, (2018) 1704244. DOI:10.1002/adma.201704244.
[5] F. Wu, S. S. Zhang, B. Xi, Z. Feng, D. Sun*, X. J. Ma, J. Zhang, J.Feng, S. Xiong*, Unusual Formation of CoO@C “Dandelions” Derived from Two-Dimensional Kagóme MOLs for Efficient Lithium Storage, Adv. Energy Mater., 8 (2018) 1703242.
[6] S. S. Zhang,# L. Feng,# R. D.Senanayake,# C. M. Aikens, X. P. Wang, Q. Q. Zhao, C. H. Tung, D. Sun*, Diphosphine-protected ultrasmall gold nanoclusters: opened icosahedral Au13 andheart-shaped Au8 clusters, Chem. Sci., 9, (2018) 1251-1258. DOI: 10.1039/c7sc03566g.
[7] Z. Wang, H. F. Su, X. P. Wang, Q. Q. Zhao, C. H. Tung, D. Sun*, L. S. Zheng, Johnson solids:Anion-Templated Silver Thiolate Clusters Capped by Sulphonate, Chem. Eur. J. 24, (2018) 1640-1650. DOI: 10.1002/chem.201704298.
[8] S. S. Zhang, H. F. Su, Z. Wang, X. P. Wang,* W. X. Chen, Q. Q. Zhao,* C. H. Tung, D. Sun*, L. S. Zheng, Elimination-fusionself-assembly of a nanometer-scale 72-nucleus silver cluster caging a pair of [EuW10O36]9-polyoxometalates, Chem. Eur. J. 24, (2018) 1998-2003. DOI: 10.1002/chem.201705264 (HOT PAPER).
[9] Y. M. Su,# W. Liu,# Z. Wang, S. A.Wang, Y. A. Li, F. Yu, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun*, Benzoates-Induced High-Nuclearity Silver Thiolate Clusters, Chem. Eur. J. 24, (2018) 4967-4972. DOI: 10.1002/chem.201800007.
[10] J. Shen, Z. Wang, D. Sun*, C. Xia, S. L. Yuan,* P. Sun, X. Xin*, pH-Responsive Nanovesicles with Enhanced Emission Co-Assembled by Ag(I) Nanoclusters and Polyethyleneimine as a Superior Sensor for Al3+, ACS Applied Materials & Interfaces, 10 (2018) 3955-3963. DOI: 10.1021/acsami.7b16316.
[11] L. P. Cheng,# Z. Wang,# Q. Y. Wu, H. F. Su, T. Peng, G. G. Luo,* Y. A. Li, D. Sun,* L. S. Zheng, Small size yet big action: a simple sulfate anion templated a discrete 78-nuclearity silver sulfur nanocluster with a multishell structure, Chem. Commun., 54, (2018) 2361-2364. DOI: 10.1039/C8CC00014J.
[12] J. W. Liu,# H. F. Su,# Z. Wang, Y. A. Li, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, A giant 90-nucleus silver cluster templated by hetero-anions, Chem. Commun., 54, (2018) 4461-4464. DOI:10.1039/c8cc01767k.
[13] C. X. Xia, S. S. Zhang, D. Sun,* B. L. Jiang, W. S. Wang, X. Xin*, Coassembly of Mixed Weakley-Type Polyoxometalates to Novel Nanoflowers with Tunable Fluorescence for the Detection of Toluene, Langmuir, 34, (2018), 6367−6375. DOI: 10.1021/acs.langmuir.8b00283.
[14] X. Gao, S. S. Zhang, H. Yan, Y. W. Li,* Q. Y. Liu, X. P. Wang,* C. H. Tung, H. Y. Ma and D. Sun,* A pillar-layered porous CoII-MOF with dual active sites for selective gas adsorption, CrystEngComm, 20, (2018) 4905–4909. DOI: 10.1039/c8ce01118d.
[15] P. P. Sun, S. S. Zhang, Z. Y. Xiang, J. Y. Pang, Y. B. Tan, D. Sun,* C. X. Xia, X. H. Cheng, X. Xin,* Self-assembly of Ionic-Liquid-Type Imidazolium Gemini Surfactant with Polyoxometalates into Supramolecular Architectures for Photocatalytic Degradation of Dye, J. Mol. Liq., 272, (2018) 180-187. DOI: 10.1016/j.molliq.2018.08.016.
[16] Y. M. Su, H. F. Su, Z. Wang, Y. A. Li, S. Schein, Q. Q. Zhao, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, Three Silver Nests Capped by Thiolate/Phenylphosphonate, Chem. Eur. J., 24 (2018) 15096-15103. DOI: 10.1002/chem.201803203. (HOT PAPER)
[17] H. Y. Zhuo, A. Y. Hu, L. Feng*, Q. Y. Liu, X. P. Wang*, D. Sun,* A Tetradecanuclear Organometallic Copper(I)-Alkynide Cluster: Synthesis, Crystal Structure, and Luminescent Property, J. Clust. Sci., 29, (2018) 1017-1022. DOI: 10.1007/s10876-018-1413-3.
[18] X. G. Han,* L. M. Sun, F. Wang, D. Sun,* Nitrogen doped Carbon Honeycomb-like Structure Assembled by Mesoporous Nanosheets with Superior Performance in Lithium-Ion Batteries, J. Mater. Chem. A, 6, (2018) 18891-18897. DOI: 10.1039/C8TA07682K.
[19] X. Xin,# Y. Y. Gao,# Q. Y. Zhang, Z. Wang, D. Sun,*S. L. Yuan, H. B. Xia*, Realizing Enhanced Luminescence of Silver Nanoclusters-Peptide Soft Hydrogels by PEI Reinforcement, Soft Matter, 14, (2018) 8352–8360 DOI:10.1039/C8SM01734D.
[20] G. G. Luo*, Z. H. Pan, J. Q. Lin, D. Sun,* Tethered sensitizer-catalyst noble-metal-free molecular devices for solar-driven hydrogen generation, Dalton Trans, 47 (2018) 15633-15645. DOI: 10.1039/C8DT02831A. (Invited Frontier Paper)
[21] S. S. Zhang, H. F. Su, G. L. Zhuang, X. P. Wang, C. H. Tung, D. Sun,* L. S. Zheng, A Hexadecanuclear Silver Alkynyl Cluster Based NbO Framework with Triple Emissions from Visible to Near-Infrared II Region, Chem. Commun., 54, (2018) 11905-11908 . DOI:10.1039/C8CC06683C.
[22] B. Q. Ji,# M. Jagodič,# H. Y. Ma, H. F. Su*, Y. W. Li*, C. H. Tung and D. Sun,* Solution behavior and magnetic properties of a novel nonanuclear copper(II) cluster, New J. Chem., 42, (2018) 17884-17888. DOI: 10.1039/c8nj04230f.
[23] C. X. Xia, S. S. Zhang, Y. B. Tan, D. Sun,* P. P. Sun, X. H. Cheng, X. Xin*, Self-assembly of europium-containing polyoxometalates/tetra-n-alkyl ammonium with enhanced emission for Cu2+ detection, ACS Omega, 3, (2018) 14953-14961. DOI: 10.1021/acsomega.8b01636.
[24] A. Xie,# Z. Wang,# Q. Wu, L. P. Cheng, G. G. Luo*, D. Sun,* [Ag25(SC6H4Pri)18(dppp)6](CF3SO3)7·CH3CN (HSC6H4Pri = 4-t-isopropylthiophenol, and dppp = 1, 3-bis(diphenyphosphino)propane) Cluster Containing a Sandwich-like Skeleton: Structural Characterization and Optical Properties, Acta Phys.-Chim. Sin. (物理化学学报), 34, (2018), 776-780. DOI: 10.3866/PKU.WHXB201711091.
2017年
[1] Z. Wang,# H. F.Su,# Y. Z. Tan, S.Schein,* S. C.Lin, W. Liu, S. A. Wang, W. G. Wang, C. H. Tung, D.Sun,* L. S. Zheng, Assembly of silver Trigons into a buckyball-like Ag180 nanocage, Proc Natl Acad Sci USA 114, (2017) 12132-12137. DOI:10.1073/pnas.1711972114.
[This article is a PNAS DirectSubmission]
(Nature Comm 副主编Ariane在Nature Review Chemistry 以“Polynuclear complexes: Buckyball's silver cousin”为题专刊亮点评述哥德堡银笼的研究工作; Nature Reviews Chemistry, doi:10.1038/s41570-017-0102. https://www.nature.com/articles/s41570-017-0102.)
[2] L. Y.Guo,# H. F. Su,# M. Kurmoo, C.H. Tung, D.Sun,* L. S. Zheng, Core−Shell {Mn7⊂(Mn,Cd)12}Assembled from Core {Mn7} Disc, J. Am. Chem. Soc., 139, (2017)14033-14036.
[3] X. Chen,# Z. Wang,# R. Zhang, L. Xu,* D. Sun,* A novel polyoxometalate-based hybrid containing 2D [CoMo8O26]∞structure as anode for lithium-ion batteries, Chem. Commun., 53, (2017) 10560-10563.
[4] S. S. Zhang,# X.Wang,# H. F. Su, L. Feng, Z. Wang, W. Q. Ding, V. A. Blatov, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, A Water-Stable Cl@Ag14 Cluster Based Metal−Organic Open Framework for Dichromate Trapping and Bacterial Inhibition, Inorg. Chem., 56 (2017) 11891-11899.
[5] X. P. Wang,# W .M. Chen,# H. Qi, X. Y. Li, C. Rajnak, Z. Y. Feng, M. Kurmoo,* R. Boca, C. J.Jia, C.-H. Tung, D.Sun,* Solvent-Controlled Phase Transition of a CoII-Organic Framework:From Achiral to Chiral and Two to Three Dimensions, Chem. Eur. J. 23, (2017) 7990-7996. (Selected as Very Important Paper).
[6] S. S. Zhang, H. F. Su, Z. Wang, L. Wang, Q. Q. Zhao, C.-H. Tung, D.Sun,* L. S. Zheng, Anion-Templated Nanosized Silver Alkynyl Clusters: Cluster Engineering and Solution Behavior, Chem. Eur. J. 23, (2017) 3432-3437.
[7] Y. W. Li, L. Y. Guo, H. F. Su, M. Jagodic, M. Luo, X. Q. Zhou, S. Y. Zeng, C. H. Tung, D. Sun,* L. S. Zheng, Two Unprecedented POM-Based Inorganic Organic Hybrids with Concomitant Heteropolytungstate and Molybdate, Inorg. Chem., 56 (2017) 2481-2489.
[8] J. H. Xu,# L. Y.Guo,# H. F. Su, X.Gao, X. F. Wu, W. G. Wang,* C. H. Tung, D.Sun,* L. S. Zheng, A Heptanuclear CoII5CoIII2 Cluster as Efficient Water Oxidation Catalyst, Inorg. Chem., 56 (2017) 1591-1598.
[9] X. Y. Li,# Z. Wang,# H. F. Su,# S. Feng, M. Kurmoo, C. H. Tung, D. Sun,* L. S. Zheng, Anion-Templated Nanosized Silver Clusters Protected by Mixed Thiolate and Diphosphine, Nanoscale 9 (2017)3601-3608.
[10] X. Y. Li,# H. F. Su,# M. Kurmoo, C. H. Tung, D.Sun,* L. S. Zheng, Structure, Solution Assembly, Electroconductivity of Nanosized Argento-Organic-Cluster/Framework Templated by Chromate, Nanoscale 9(2017) 5305-5314.
[11] Y. W. Li,# L. Y.Guo,# L. Feng, Z. Jaglicic,* S. Y. Zeng, D. Sun,* Self-assembly, structures, magnetic properties and solution behaviors of six mixed-valence cobalt clusters, CrystEngComm, 19, (2017)5897-5906.
[12] W. M. Chen, X. L. Meng, G. L. Zhuang, Z. Wang, M. Kurmoo, Q. Q. Zhao, X. P. Wang, B. Shan, C. H. Tung, D. Sun,* A superior fluorescent sensor forAl3+ and UO22+ based on Co(II) metal-organic framework with exposed pyrimidyl Lewis base site, J. Mater. Chem. A, 5 (2017) 13079-13085.
[13] L. Y. Guo,# H. F. Su,# M. Kurmoo, X. P. Wang, Q. Q. Zhao, S. C. Lin, C. H. Tung, D. Sun,* L. S. Zheng, Multifunctional Triple-Decker Inverse 12-Metallacrown-4 Sandwiching Halides, ACS Applied Materials & Interfaces, 9 (2017) 19980-19987.
[14] H. Zhang, L.-Y.Guo, J. Jiao, X. Xin,* D.Sun,* S. L. Yuan,* Ionic Self-assembly of Polyoxometalate-Dopamine Hybrid Nanoflowers with Excellent Catalytic Activityfor Dyes, ACS Sustainable Chemistry & Engineering 5 (2017)1358-1367.
[15] G. G. Luo,# * H. F. Su,# A.Xiao,# Z. Wang, Y. Zhao, Q. Y. Wu, J. H. Wu, D.Sun,* L. S. Zheng, Silver-sulfur Hybrid Supertetrahedral Clusters: The Hitherto Missing Members in the Metal-chalcogenide Tetrahedral Clusters, Chem. Eur. J. 23 (2017)14420-14424.
[16] F. Wang,# H. Y. Zhuo,# X. G. Han,* W. M. Chen, D.Sun,* Foam-like CoO@N,S-codoped carboncomposites derived from a well-designed N,S-rich Co-MOF for lithium-ionbatteries, J. Mater. Chem. A, 5 (2017) 22964-22969.
[17] J. Shen, Z. Wang, D. Sun,* G. Liu, S. Yuan,* M. Kurmoo, X. Xin*, Self-assembly of water-solublesilver nanoclusters: superstructure formation and morphological evolution, Nanoscale 9 (2017) 19191-19200.
[18] L. Tong, Z. Wang, C. Xia, Y. Yang, S. L. Yuan, D. Sun,* X. Xin*, Self-Assembly of Peptide-Polyoxometalate Hybrid Sub-Micrometer Spheres for Photocatalytic Degradation of Methylene Blue, J. Phys. Chem. B 121 (2017) 10566−10573.
[19] C. Xia, Z. Wang, D. Sun,* B. Jiang, X. Xin*, Hierarchical Nanostructures Self-Assembled by Polyoxometalate and Alkylamine for Photocatalytic Degradation of Dye, Langmuir 33 (2017) 13242−13251.
[20] 骆耿耿,王芝,程丽萍,赵全芹,王兴坡,孙頔*,银硫纳米簇合物的阴离子模板法合成、结构与发光性能,中国科学: 化学, 2017, 47,695-704. (特邀综述).
2016年
[1] Y. K. Deng,# H. F.Su,# J. H. Xu, W. G. Wang, M. Kurmoo, S. C. Lin, Y. Z. Tan, J. Jia, D. Sun,* L. S. Zheng, Hierarchical Assembly of a{MnII15MnIII4} Brucite Disc: Step-by-Step Formation and Ferrimagnetism. J. Am. Chem. Soc., 138, (2016) 1328-1334.
[2] X. Y. Li, H. F.Su, R. Q. Zhou, S. Feng, Y. Z. Tan, X. P. Wang, J. Jia, M. Kurmoo, D. Sun,* L. S. Zheng, General Assembly of Twisted Trigonal-Prismatic Nonanuclear Silver(I) Clusters, Chem.Eur. J. 22 (2016) 3019-3028.
[3] Z. Wang, X. Y. Li, L. W. Liu, S. Q. Yu, Z. Y. Feng, C.-H. Tung, D.Sun,* Beyond Cluster: Supramolecular Networks Self-Assembled from Nanosized Silver Clusters and Inorganic Anions, Chem. Eur. J. 22,(2016) 6830-6836. (HOT PAPER and Inside Cover)
[4] H. Y. Zhuo,# H. F.Su,# Z. Z. Cao, W. Liu, S. A. Wang, L. Feng, G. L. Zhuang, S. C. Lin, M. Kurmoo, C.H. Tung, D.Sun,* L. S. Zheng, High-Nuclear Organometallic Copper(I)–Alkynide Clusters:Thermochromic Near-Infrared Luminescence and Solution Stability, Chem. Eur. J. 22,(2016) 17619-17626. (HOT PAPER and Inside Cover)
[5] Z. H. Yan, X. Y.Li, L. W. Liu, S. Q.Yu, X. P. Wang, D. Sun,* Single-crystal to single-crystal phase transitionand segmented thermochromic luminescence in a dynamic 3D interpenetrated AgI coordination network. Inorg. Chem., 55 (2016) 1096-1101.
[6] Z. Wang, G. L. Zhuang, Y. K. Deng, Z. Y. Feng, Z. Z. Cao, M. Kurmoo, C. H. Tung, D. Sun,* Near-Infrared Emitters: Stepwise Assembly of Two Heteropolynuclear Clusters with Tunable AgI:ZnII Ratio, Inorg.Chem., 55(2016) 4757-4763.
[7] L. Y. Guo, S.-Y. Zeng, M. Jagodic, Q. D. Hu, S. X. Wang, Z. Wang, D.Sun,* A Pyridazine-Bridged Sandwiched Cluster Incorporating Planar Hexanuclear Cobalt Ring and Bivacant Phosphotungstate, Inorg. Chem., 55 (2016) 9006-9011.
[8] Z. Wang, Z. Jaglicic, L. L. Han, G. L. Zhuang, G. G. Luo, S.-Y.Zeng, C. H. Tung, D. Sun,* Octanuclear Ni(II) cubes based on halogen-substituted pyrazolates: Synthesis, structure, electrochemistry and magnetism, CrystEngComm, 18,(2016) 3462-3471.
[9] L. Y. Guo, M. Jagodic, S.-Y. Zeng, Z. Wang, Z. Q. Shi, X. P. Wang, C. H. Tung, D. Sun,* pH-Controlled Assembly of Two Novel Dawson-Sandwiched Clusters Involving In Situ Reorganization of Trivacant α-[P2W15O56]12- intoDivacant α-[P2W16O57]8-, Dalton. Trans., 45,(2016) 8404-8411.
[10] F. Yang, Y.-K. Deng, L.-Y. Guo, H.-F. Su, Z. Jaglicic,* Z.-Y. Feng, G.-L. Zhuang,* S.-Y. Zeng, D.Sun,* Structural, electrochemical,and magnetic analyses of a newoctanuclear MnIII2MnII6 cluster withlinked-defect cubane topology, CrystEngComm, 18,(2016) 1329 - 1336.
[11] W. F. Xie, L. Y. Guo, J. H. Xu, M.Jagodic, Z. Jaglicic, W. G. Wang, G. L. Zhuang, Z. Wang, C. H. Tung, D. Sun,* Multifaceted Bicubane Co4 Clusters: Magnetism, Photocatalytic Oxygen Evolutionand Electrical Conductivity, Eur. J. Inorg. Chem., 2016, 3253-3261.
[12] J. H. Xu, Z. Wang, W. G. Yu, D. Sun,* Q. Zhang, C. H.Tung, W. G. Wang,* Kagome Cobalt(II)-Organic Layers as Robust Scaffolds for Highly Efficient Photocatalytic Oxygen Evolution, ChemSusChem, 6(2016)1146-1152.
[13] X. Han, W. M. Chen, X. G. Han,* Y. Z. Tan, D. Sun,* Nitrogen-rich MOF Derived Porous Co3O4/N-C Composite with Superior Performance in Lithium-Ion Batteries, J. Mater. Chem. A, 4(2016) 13040-13045.
[14] Z. Wang, R. Senanayake, C. M. Aikens, W. M. Chen, C. H. Tung, D. Sun,* Gold-Doped Silver Nanocluster[Au3Ag38(SCH2Ph)24X5]2- (X= Cl or Br), Nanoscale 8 (2016) 18905-18911. (Selected as Inside Cover and chosen for “2016 Nanoscale HOT ArticleCollection” based on referee reviews. http://pubs.rsc.org/en/content/articlelanding/2016/nr/c6nr06615a#!divAbstract)
[15] X.-P. Wang, L.-L. Han, Z. Wang, L.-Y. Guo, D.Sun,* Microporous Cd(II) metal-organic framework asfluorescent sensor for nitroaromatic explosives at the sub-ppm level, J.Mol. Struct., 1107 (2016) 1-6.
[16] X.-P. Wang, L.-L. Han, S.-J. Lin,X.-Y. Li, K. Mei, D. Sun,* Synthesis, structure and photoluminescence ofthree 2D Cd(II) coordination polymers based on varied dicarboxylate ligand, J.Coord. Chem, 69 (2016) 286-289.
[17] H. Zhang, L.-Y. Guo, Z. Xie, X. Xin,* D. Sun,* S. L. Yuan,* Tunable Aggregation-Induced Emission of Polyoxometalates via Amino Acid-Directed Self-Assembly and Their Application in Detecting Dopamine, Langmuir 32 (2016) 13736−13745.
2015年
[1] F. L. Liu, B. Kozlevcar, P. Strauch, G. L. Zhuang, L. Y. Guo, Z. Wang, D.Sun,* Robust Cluster Building Unit(CBU): Icosanuclear Heteropolyoxocopperate Templated by Carbonate, Chem. Eur. J. 21,(2015) 18847-18854.
[2] Z. H. Xu, L. L.Han, G. L. Zhuang, J. Bai, D.Sun,* In Situ Construction of Three Anion-Dependent Cu(I)Coordination Networks as Promising Heterogeneous Catalysts for Azide−Alkyne“Click” Reactions, Inorg. Chem., 54 (2015) 4737-4743.
[3] T.-P. Hu, Y.-Q.Zhao, Z. Jaglicic, K. Yu,X.-P. Wang, D.Sun,* Four Hybrid Materials Based on Preyssler P5W30 Polyoxometalate and First-Row Transition-Metal Complex, Inorg. Chem., 54(2015) 7415-7423.
[4] X. Y. Li, H. F. Su,K. Yu, Y. Z. Tan,* X.-P. Wang, Y. Q. Zhao, D. Sun,* L. S. Zheng, Platonic solid templating Archimedean solid: An unprecedentednanometre-sized Ag37 cluster, Nanoscale 7 (2015) 8284-8288.
[5] Z. Bai,* Y. Zhang, Y. Zhang, C. Guo, B. Tang, D.Sun,* MOFs-derived porous Mn2O3 as high-performance anodematerial for Li-ion battery, J. Mater. Chem. A, 3 (2015) 5266-5269 (ESI高被引论文).
[6] X. Y. Li, Y. Z. Tan, K. Yu, X.-P.Wang, Y. Q. Zhao, D.Sun,* L. S. Zheng, Atom-precise polyoxometalate-Ag2S core-shell nanoparticle, Chem-Asian J, 10 (2015),1295-1298.
[7] X.-P. Wang, T.-P. Hu, D. Sun,* Luminescent silver(I) coordination architectures containing 2-aminopyrimidyl ligands, CrystEngComm,17(2015) 3393-3417.(Invited Highlight Paper & Inside Cover)
[8] L.-L. Han, T.-P. Hu, K. Mei, Z.-M. Guo, C. Yin, Y.-X. Wang, J. Zheng, X.-P. Wang, D. Sun,* Solvent-controlled three families of Zn(II) coordination compounds: synthesis, crystalstructure,solvent-induced structural transformation, supramolecular isomerismand photoluminescence, Dalton Trans, 44 (2015) 6052-6061.
[9] L.-L. Han, S.-N. Wang, Z. Jaglicic,S.-Y. Zeng, J. Zheng, Z.-H. Li, J.-S. Chen, D.Sun,* Synthesis, structural versatility and magnetic properties of a series of copper(II) coordinationpolymers based on bipyrazole and various dicarboxylate ligands, CrystEngComm, 17(2015)1405-1415.
[10] T.-P. Hu, Y.-Q. Zhao, K. Mei, S.-J. Lin, X.-P. Wang, D. Sun,* Anovel silver(I)-Keggin-polyoxometalate inorganic–organic hybrid: a Lewis acid catalyst for cyanosilylation reaction, CrystEngComm, 17(2015) 5947-5952.
[11] L.-L. Han, Y.-X. Wang, Z.-M. Guo, C. Yin, T.-P. Hu, X.-P. Wang, D. Sun,* Synthesis, crystal structure, thermal stability, and photoluminescence of a 3-D silver(I) network with two fold interpenetrated dia-ftopology, J. Coord. Chem, 68 (2015) 1754-1764.
[12] X.-P. Wang, Y.-Q. Zhao, Z. Jaglicic, S.-N. Wang, S.-J. Lin, X.-Y. Li, D.Sun,* Controlled in situ reaction for the assembly of Cu(II) mixed-ligand coordination polymers: synthesis, structure, mechanistic insights, magnetism and catalysis, Dalton Trans, 44(2015)11013-11020.
2014年
[1] S. Yuan, Y. K. Deng, D. Sun,* Unprecedented Second-Time scale Blue/Green Emissions and Iodine-Uptake-Induced Single-Crystal-to-Single-Crystal Transformation in Zn-II/Cd-II Metal-Organic Frameworks, Chem. Eur. J., 20(2014) 10093-10098.
[2] X. L. Zhao, F. L. Liu, L. L. Zhang, D. Sun,* R. M. Wang, Z. F. Ju, D. Q. Yuan,* D. F. Sun,* Achieving a Rare Breathing Behaviorin a Polycatenated 2D to 3D Net through a Pillar-Ligand Extension Strategy, Chem. Eur. J., 20(2014) 649-652.
[3] Y.-Q. Zhao, K. Yu, L.-W. Wang, Y. Wang, X.-P. Wang, D.Sun,* Anion-Induced Supramolecular Isomerism in Two Preyssler P5W30 Polyoxometalate-Based Hybrid Materials, Inorg. Chem., 53(2014) 11046-11050.
[4] F. L. Liu, Z. H. Xu, X. Y. Zhang, X. P. Wang, D. Sun,* Unusual N-H Activation of 2-Aminopyrimidine:Supramolecular Assembly into an Ag-I Metal-Organic Framework, Chem-Asian J, 9(2014) 452-456.
[5] L. L. Han, X. Y. Zhang, J. S. Chen, Z. H. Li, D. F. Sun,* X. P. Wang, D. Sun,* Silver(I)/Bipyrazole/Dicarboxylate Interpenetrated Coordination Networks: Spontaneous Chiral Resolution,Modulation of Topologies, Water Clusters, and Photoluminescences, CrystGrowthDes, 14 (2014) 2230-2239.
[6] L. L. Han, Z. H. Li, J .S. Chen, X. P. Wang, D.Sun,* Solution and Mechanochemical Syntheses of Two Novel Cocrystals: Ligand Length Modulated Interpenetration of Hydrogen-Bonded 2D6(3)-hcb Networks Based on a Robust Trimeric Heterosynthon, CrystGrowthDes, 14(2014) 1221-1226.
[7] S. Yuan, Y. K. Deng, W. M. Xuan, X. P. Wang, S. N. Wang, J. M. Dou, D. Sun,* Spontaneouschiral resolution of a 3D (3,12)-connected MOF with an unprecedented topology consisting of cubic Cd-4(mu(3)-OH)(4) clusters and propeller-like ligands, CrystEngComm,16(2014)3829-3833. (Inside Cover)
[8] S. Yuan, S. S. Liu, D. Sun*, Two isomeric Cu4I4 luminophores: solvothermal/mechanochemical syntheses, structuresand thermochromic luminescence properties, CrystEngComm,16(2014)1927-1933.
[9] Y. Q. Zhao, M. X. Fang, Z. H. Xu, X. P. Wang,* S. N. Wang, L. L. Han, X. Y. Li, D. Sun,* Construction of acrystalline Ag(I) coordination polymer based on a new ligand generated fromunusual in situ aza-Michael addition reaction, CrystEngComm,16 (2014)3015-3019.
[10] L. L. Han, T. P. Hu, J. S. Chen, Z. H. Li, X. P. Wang, Y. Q. Zhao, X. Y. Li, D. Sun,* Simultaneous encapsulationof an infinite T4(0)A(0)6(0) water tape and discrete water hexamers in ahydrogen-bonded Ag(I) supramolecular framework, Dalton Trans, 43(2014)8774-8780.
[11] S. S. Liu, S. Yuan, X. Y. Li, S. Miao, Z. W. Yu,* X. P. Wang, D. Sun,* A 'kagome dual' (kgd) sheet based ontriangular rigid ligand: Synthesis, structure, photoluminescence and anion exchangeproperties, Inorg. Chim. Acta, 416(2014) 195-199.
[12] S. S. Liu, S. Yuan, T. P. Hu, D. Sun,* A 3D Luminescent Metal-organic Framework Constructed from Cu4I4 Cubane Clustersand Triangular Imidazole Ligand, Z. Anorg. Allg. Chem., 640 (2014)2030-2034.
[13] F. L. Liu, X. P. Wang, D. Sun,* Synthesis and crystal structure of a novel cadmium sulfate coordination polymer based on multidentate 2-(3-(4-(pyridin-4-yl)phenyl)-1H-1,2,4-triazol-5-yl)pyridine, J. Struc.Chem. 55(2014)932-936.
[14] Z.-H. Yan, L.-L. Han, Y.-Q. Zhao,X.-Y. Li, X.-P. Wang, L. Wang, D. Sun,* Three mixed-ligand coordination networks modulated by flexible N-donor ligands: syntheses, topological structures, and temperature-sensitive luminescence properties, CrystEngComm, 16, (2014) 8747-8755.
2013年
[1] F. Sun,# Z. Yin,# Q. Q. Wang,# D.Sun,# M. H. Zeng,* M. Kurmoo,* Tandem Postsynthetic Modification of a Metal Organic Framework by Thermal Elimination and Subsequent Bromination: Effects on Absorption Properties and Photoluminescence, Angew. Chem. Int. Ed., 52(2013) 4538-4543.(#Co-first author)
[2] D. Sun,* S. Yuan, H. Wang,H.-F. Lu, S.-Y. Feng, D.-F. Sun,* Luminescence thermochromism of two entangled copper-iodide networks with a large temperature-dependent emission shift, Chem.Commun., 49(2013) 6152-6154. (ESI高被引论文)
[3] D. Sun,* L.-L. Han, S. Yuan,Y.-K. Deng, M.-Z. Xu, D.-F. Sun, Four New Cd(II) Coordination Polymers with Mixed Multidentate N-Donors and Biphenyl-Based Polycarboxylate Ligands: Syntheses,Structures, and Photoluminescent Properties, Cryst. Growth Des.,13(2013)377-385. (ESI高被引论文)
[4] L. Fan, X. Zhang,*D.Li, D. Sun,*W. Zhang, J. Dou,* Supramolecular isomeric flat and wavy honeycomb networks: additive agent effect on the ligand linkages, CrystEngComm,15(2013)349-355.
[5] D. Sun,* L. L. Zhang, H. F. Lu, S. Y. Feng, D. F. Sun, Bright-yellow to orange-red thermochromic luminescence of an Ag6I-Zn2II heterometallic aggregate, Dalton Trans.,42(2013)3528-3532.
[6] D. Sun,* M.-Z. Xu, S.-S. Liu, S. Yuan, H.-F. Lu, S.-Y. Feng, D.-F. Sun, Eight Zn(II) coordination networks based on flexible1,4-di(1H-imidazol-1-yl)butane and different dicarboxylates:crystal structures, water clusters, and topologies, Dalton Trans.,42(2013)12324-12333.
[7] D. Sun,* H. Wang, H.-F. Lu, S.-Y. Feng, Z.-W. Zhang, G.-X. Sun, D.-F. Sun, Two birds with one stone: anion templated ball-shaped Ag56 and disc-like Ag20 clusters, Dalton Trans.,42(2013)6281-6284.
[8] S. Yuan, H. Wang, D.-X. Wang, H.-F. Lu, S.-Y. Feng, D. Sun,* Reactant ratio-modulated six new copper(I)-iodide coordination complexes based on diverse [CumIm] aggregates and biimidazole linkers: syntheses, structures and temperature-dependent luminescence properties, CrystEngComm, 15 (2013) 7792-7802.
[9] S. Yuan, Y.-K. Deng, X.-P. Wang, D. Sun,* A temperature-sensitive luminescent Ag20 nanocluster templated bycarbonate in situ generated from atmospheric CO2 fixation, New J. Chem.,37(2013)2973-2977.
[10] D. Sun,* F.-J. Liu, R.-B. Huang, L.-S. Zheng, Structural diversity of Ag/3-nitrophthalate coordination polymers controlled by solvent and induction agent, CrystEngComm, 15(2013)1185-1193.
[11] D. Sun,* Z.-H. Y, V. A. Blatov,* L. Wang, D.-F. Sun, Syntheses, Topological Structures, and Photoluminescences of Six New Zn(II) Coordination Polymers Based on Mixed Tripodal Imidazole Ligand and Varied Polycarboxylates, Cryst. Growth Des.,13, (2013) 1277-1289.
2012年
[1] X. Zhao, L. Zhang, H. Ma, D. Sun,* D. Wang, S. Feng, D. F. Sun,* Solvent-controlled Cd(II) metal-organic frameworks constructed from a tetrapodal silicon-based linker, RSC Adv.,2(2012)5543-5549.
[2] X. Zhao, X. Wang, S. Wang, J. Dou, P. Cui, Z. Chen, D. Sun,*X. Wang, D. F. Sun,* Novel Metal-Organic Framework Based on Cubic and Trisoctahedral Supermolecular Building Blocks:Topological Analysis and Photoluminescent Property, Cryst.GrowthDes.,12(2012) 2736-2739.
[3] X.-T. Zhang, D. Sun,* B.Li,*L.-M. Fan, B. Li, P.-H. Wei, Unusual High Thermal Stability of a 2D-3D Polycatenated Fe(II) Metal-Organic Framework Showing Guest-Dependent Spin-Crossover Behaviorand High Spin-Transition Temperature, Cryst.Growth Des.,12(2012) 3845-3848.
[4] X.-T. Zhang, L.-M. Fan, X. Zhao,* D.Sun,* D.-C. Li, J.-M. Dou,* Syntheses, crystal structures, and properties of five mixed-ligand coordination polymers based on novel quaterphenyl-2,5,2,5-tetracarboxylic acidligand, CrystEngComm, 14(2012)2053-2061.
[5] F. Dai, D. Sun,* W. Sun, Y.-Q. Liu, D. F. Sun,* Conformation variation of tris(2-carboxyethyl)isocyanuric acidinduced by cocrystallized N-heterocyclic organic molecules, CrystEngComm, 14(2012)1376-1381.
[6] Y.-H. Li, D. Sun,* H.-J. Hao, Y. Zhao, R.-B. Huang,* L.-S. Zheng, Three novel organosilver(I) coordination networks constructed from diallylmelamine and polycarboxylates incorporating silver-vinyl bonding, Dalton Trans., 41 (2012)2289-2295.
[7] J. Sun, Y.-H. Wei,F.-L.Liu, D.Sun,* Syntheses, crystal structures and photoluminescent properties of silver(I) and cadmium(II)coordination polymers constructed from flexiblehexadentate di-Schiff base ligands, RSC Adv.,2 (2012) 10189-10194.
[8] D. Sun,* L. Zhang, Z. Yan, D. F. Sun,* Stepwise Construction of a AgI9-CuII4 Heterometallic Cluster Incorporating Two Unusual Vertex-Shared Trigonal-Bipyramidal Silver Polyhedra, Chem. Asian. J., 7(2012)1558-1561.
[9] D. Sun,* Z.-H. Yan, M. Liu, H. Xie, S. Yuan, H. Lu, S. Feng, D. F. Sun,* Three- and Eight-Fold Interpenetrated ThSi2 Metal-Organic Frameworks Fine-Tuned by the Length of Ligand, Cryst.GrowthDes.,12 (2012) 2902-2907.
[10] D. Sun,* Z.-H. Yan, Y.-K. Deng, S. Yuan, L. Wang,* D.-F. Sun, Two novel entangled metal-organic networks constructed from 4,4-bis(2-methylimidazol-1-ylmethyl)biphenyl and dicarboxylates: From polycatenated 2D+2D - 3D framework to polyrotaxane-like 2D+2D - 2D layer, CrystEngComm, 14(2012)7856-7860.
[11] F.-J. Liu, D. Sun,* H.-J. Hao,R.-B. Huang,* L.-S. Zheng, 3D - 3D interpenetrated and 2D - 3D polycatenated Ag(I) networks constructed from1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates, CrystEngComm,14 (2012)379-382.
[12] D. Sun,* F.-J. Liu, R.-B. Huang, L.-S. Zheng, Three guest-dependent nitrate-water aggregations encapsulated in silver(I)-bipyridine supramolecular frameworks, CrystEngComm,14(2012)7872-7876.
[13] F.-J. Liu, D. Sun,* H.-J. Hao,R.-B. Huang,*L.-S. Zheng, Anion-Controlled Assembly of Silver(I)/Aminobenzonitrile Compounds: Syntheses, Crystal Structures, and Photoluminescence Properties, Cryst.GrowthDes., 12(2012) 354-361.
2011年7月-12月
[1] D. Sun,* F.-J. Liu, R.-B.Huang,* L.-S. Zheng, Anionic Heptadecanuclear Silver(I) Cluster Constructed from in Situ Generated 2-Mercaptobenzoic Acid and a Sulfide Anion, Inorg. Chem.,50 (2011)12393-12395.
[2] D. Sun,* F.-J. Liu, H.-J.Hao, R.-B. Huang,*L.-S. Zheng, Different water clusters dependent on long-chain dicarboxylates in two Ag(I) coordination polymers: Synthesis, structure andthermal stability, J. Mol. Struct., 1004 (2011) 313-318.
[3] D. Sun,* R.-B. Huang, L.-S. Zheng, Halogen Bonds in Two Silver(I) Mixed-ligand Supramolecular Frameworks:Synthesis, Structure and Photoluminescence, Z. Naturforsch. B., 66(2011)1035-1041.
[4] T. Hu,* X. Zhao, X. Hu, Y. Xu, D. Sun,* D. F. Sun,*Two novel isomeric organic anion-water aggregations: 1D tape and 3D 2-fold interpenetrated diamond network, RSCAdv.,1 (2011)1682-1686.
[5] H.-J. Hao, D. Sun,* F.-J. Liu, R.-B. Huang,* L.-S. Zheng, Discrete Octamer Water Cluster and 1D T5(2) Water Tape Trapped in Two Luminescent Zn(II)/1,2-Bis(imidazol-1-yl)ethane/DicarboxylateHosts: From 2D(4,4) Net to 3D 5-Fold Interpenetrated Diamond Network, Cryst. GrowthDes., 11(2011) 5475-5482.
[6] P. Cui, J. Wu, X. Zhao, D. Sun,* L. Zhang, J. Guo, D. F. Sun,* Two Solvent-Dependent Zinc(II) SupramolecularIsomers: Rare kgd and Lonsdaleite Network Topologies Based on a Tripodal Flexible Ligand, Cryst.GrowthDes., 11(2011) 5182-5187.
2011年之前(攻读博士学位期间)
[1] D. Sun, G.-G. Luo, N. Zhang, R.-B. Huang,* L.-S. Zheng, Simultaneous self-assembly of a cage-like silver(I)complex encapsulating an Ag6 neutral cluster core and carbon dioxide fixation, Chem.Commun., 47(2011)1461-1463.
[2] D. Sun, D.-F. Wang, X.-G. Han, N. Zhang, R.-B. Huang,* L.-S. Zheng, Stepwise assembly of two 3d-4d heterometallic coordination polymers based on a hexanuclear silver(I) metallo ligand, Chem. Commun.,47 (2011) 746-748.
[3] D. Sun, C.-F. Yang, H.-R. Xu, H.-X. Zhao, Z.-H. Wei, N. Zhang, L.-J. Yu, R.-B. Huang,* L.-S. Zheng, Synthesis, characterization and property of a mixed-valent Ag-I/Ag-II coordinationpolymer, Chem.Commun.,46 (2010) 8168-8170.(Citation = 54)
[4] D. Sun, Y.-H. Li, H.-J. Hao,F.-J. Liu, Y.-M. Wen, R.-B. Huang,* L.-S. Zheng, Solvent-Controlled Rare Case of a Triple Helical Molecular Braid Assembled from Proton-Transferred Sebacic Acid, Cryst.GrowthDes.,11 (2011) 3323-3327.
[5] D. Sun, D.-F. Wang, N. Zhang,R.-B. Huang,* L.-S. Zheng, Nonamer Water Cluster Encapsulated in a Heterometallic Supramolecular Complex, Cryst.GrowthDes.,10 (2010) 5031-5033.
[6] D. Sun, Z.-H. Wei, D.-F. Wang, N. Zhang, R.-B. Huang,* L.-S. Zheng, Acetonitrile-Templated Assembly of a Laminar Silver(I) Phthalate Coordination Polymer, Cryst. Growth Des.,11 (2011)1427-1430.
[7] D. Sun, H.-R. Xu, C.-F. Yang,Z.-H. Wei, N. Zhang, R.-B. Huang,* L.-S. Zheng, Encapsulated Diverse Water Aggregatesin Two Ag(I)/4,4-Bipyridine/Dicarboxylate Hosts: 1D Water Tape and Chain, Cryst.GrowthDes.,10(2010)4642-4649.
[8] D. Sun, N. Zhang,R.-B. Huang,* L.-S. Zheng, Series of Ag(I) Coordination Complexes Derived from Aminopyrimidyl Ligands and Dicarboxylates: Syntheses, Crystal Structures,and Properties, Cryst. Growth Des., 10 (2010) 3699-3709.
[9] D. Sun, H.-J. Hao, F.-J. Liu, H.-F. Su, R.-B. Huang,* L.-S. Zheng, Syntheses, crystal structures and photoluminescent properties of two novel Ag(I) coordination polymers with benzoguanamine and pyrazine-carboxylate ligands: From 1D helix to1D - 2D interdigitation, CrystEngComm,14(2012)480-487.
[10] D. Sun, Y.-H. Li, H.-J. Hao,F.-J. Liu, Y. Zhao, R.-B. Huang,* L.-S. Zheng, Syntheses, structures and photoluminescent properties of a series of Ag(I) coordination architectures based on 2,4-diamino-6-methyl-1,3,5-triazineand dicarboxylates: from a 0D discretemolecule to a 3D infinite network, CrystEngComm, 13 (2011) 6431-6441.
[11] D. Sun, Y.-H. Li, S.-T. Wu, H.-J. Hao, F.-J. Liu, R.-B. Huang,* L.-S. Zheng, An unprecedented (4,24)-connectedmetal-organic framework sustained by nanosized Ag12 cuboctahedral node, CrystEngComm,13(2011)7311-7315.
[12] D. Sun, F.-J. Liu, H.-J.Hao, Y.-H. Li, N. Zhang, R.-B. Huang,* L.-S. Zheng, A novel arenedisulfonate-templated 1D silver ladder constructed from 4-aminobenzonitrile ligand, CrystEngComm,13(2011) 5661-5665.
[13] D. Sun, D.-F. Wang, F.-J. Liu, H.-J. Hao, N. Zhang, R.-B. Huang,* L.-S. Zheng, Design and synthesis of 3d-4d heterometallic coordination complexes based on a nonanuclear silver (I) metallatecton, CrystEngComm,13 (2011)2833-2836.
[14] D. Sun, Z.-H. Wei, C.-F. Yang, D.-F. Wang, N. Zhang, R.-B. Huang,* L.-S. Zheng, pH-Dependent Ag(I)coordination architectures constructed from 4-cyanopyridine and phthalic acid: from discretestructure to 2D sheet, CrystEngComm,13(2011) 1591-1601..(Citation= 94)
[15] D. Sun, Q.-J. Xu, C.-Y. Ma, N. Zhang, R.-B. Huang,* L.-S. Zheng, Self-assembly, thermal stability and photoluminescence of two mixed-ligand silver(I) networks via 2D-2D and 2D-3D parallelinterpenetration of (4,4) nets, CrystEngComm,12(2010) 4161-4167.
[16] D. Sun, D.-F. Wang, N. Zhang, F.-J. Liu, H.-J. Hao, R.-B. Huang,* L.-S. Zheng, Capture and activation of aerial CO2 by carbamoylation of L-threonine in a Ag(I) supramolecular framework, DaltonTrans,40(2011)5677-5679.
[17] D. Sun, Y.-H. Li, F.-J. Liu, H.-J. Hao, R.-B. Huang,* L.-S. Zheng, Characterization of an unprecedented (ethanol)4 cluster in a novel photoluminescent silver(I) coordination polymer, Inorg. Chem.Commun., 14(2011) 1871-1875.
[18] D. Sun, G.-G. Luo, Q.-J. Xu, N. Zhang, Y.-C. Jin, H.-X. Zhao, L.-R. Lin, R.-B. Huang,* L.-S.Zheng, A novellamella 2D Ag(I) coordination polymer of graphite-like structure featuring shortinterlayer distance, Inorg. Chem. Commun., 12(2009) 782-784.
[19] D. Sun, G.-G. Luo, N. Zhang,Q.-J. Xu, Y.-C. Jin, Z.-H. Wei, C.-F. Yang, L.-R. Lin, R.-B. Huang,*L.-S. Zheng, A lamella 2D silver(I) coordination polymer constructed from in situ generated 2-mercaptobenzoic acid, Inorg. Chem. Commun., 13 (2010) 306-309.
[20] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, C.-F. Yang, Z.-H. Wei, Y.-C. Jin, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A novel 3D silver(I) coordination polymer exhibiting unprecedented m3-and m4-bonding modes of 2-aminopyrazines, Inorg.Chem.Commun.,13 (2010)290-293.
[21] D. Sun, Z.-H. Wei, C.-F. Yang, N. Zhang, R.-B. Huang,* L.-S. Zheng, Synthesis and crystal structure of an Ag20 cluster incorporating in situ generated bipodal ArP(OEt)S2-and tripodal ArPOS22- ligands (Ar=4-methoxyphenyl), Inorg. Chem. Commun.,13(2010)1191-1194.
[22] D. Sun, N. Zhang, R.-B. Huang,* L.-S. Zheng, Ag3 triangle and Ag4 rectangle supported by deprotonated aminopyrimidylderivatives and bis(diphenylphosphino)methane, Inorg. Chem. Commun.,14 (2011)1039-1042.
[23] D. Sun, N. Zhang, Q.-J. Xu,R.-B. Huang,* L.-S. Zheng, A new clover-shaped trinuclear uranium(VI) complex: Synthesis,structure and photoluminescence property, Inorg. Chem. Commun.,13(2010)859-862.
[24] D. Sun, F.-J. Liu, H.-J. Hao, Y.-H. Li, R.-B. Huang,* L.-S. Zheng, Six low-dimensional silver(I)coordination complexes derived from 2-aminobenzonitrile and carboxylates, Inorg.Chim.Acta.,387(2012)271-276.
[25] D. Sun, N. Zhang, Q.-J. Xu, Z.-H. Wei, R.-B. Huang,*L.-S. Zheng, Assembly of 1D, 2D and 3D silver (I)coordination polymers with nitrilotriacetate and 2-aminopyrimidyl mixed ligands, Inorg.Chim. Acta.,368(2011) 67-73.
[26] D. Sun, F.-J. Liu, H.-J. Hao, R.-B. Huang,* L.-S. Zheng, Coexistent Ag center dot center dot center dot Ag and Ag center dot center dot center dot C interactions in three photoluminescentsilver(I) coordination networks based on o-, m-,p-methylbenzoicacid, J. Mol.Struct,1006 (2011) 475-482.
[27] D. Sun, G.-G. Luo, N. Zhang, Z.-H. Wei, C.-F. Yang, Q.-J. Xu, R.-B. Huang,* L.-S. Zheng, Influence of aminopyrimidylderivatives on the supramolecular architectures and abundant nonvalentinteractions of silver 5-nitroisophthalate coordination polymers, J. Mol.Struct, 967(2010) 147-152.
[28] D. Sun, N. Zhang, Z.-H. Wei, C.-F. Yang, R.-B. Huang,* L.-S. Zheng, The solid-state structures of two photoluminescent 2D silver(I) arenedisulfonate incorporating aminopyrimidyl ligands:Substituents influence on pi center dot center dot center dot pi interaction, J.Mol.Struct, 981 (2010) 80-85.
[29] D. Sun, N. Zhang, Q.-J. Xu,R.-B. Huang,* L.-S. Zheng, Syntheses, structures and luminescent properties of silver(I) coordination polymers based on aminopyrimidylderivatives and 1,2,3,4-butanetetracarboxylicacid, J. Mol. Struct,975(2010) 17-22.
[30] D. Sun, N. Zhang, Q.-J. Xu,G.-G. Luo, R.-B. Huang,* L.-S. Zheng, Self-assembly of silver(I) coordination polymers from aminopyrimidyl derivatives andmalonate acid: From 1D chain to 2D layer, J. Mol. Struct, 970(2010)134-138.
[31] D. Sun, N. Zhang, Q.-J. Xu,G.-G. Luo, R.-B. Huang,* L.-S. Zheng, A novel silver(I)-containing supramolecular framework incorporating eight different hydrogen bond motifs, J. Mol.Struct, 969(2010) 176-181.
[32] D. Sun, N. Zhang, Q.-J. Xu,R.-B. Huang,* L.-S. Zheng, A novel 3D silver(I) supramolecular framework assembled from hybrid ligands incorporating Ag-C interactions, J. Organomet. Chem., 695(2010)1598-1602.
[33] D. Sun, G.-G. Luo, N. Zhang, J.-H. Chen, R.-B. Huang,* L.-R. Lin, L.-S. Zheng, Influence of dicarboxylicacids on self-assembly process: Syntheses and structural characterization of new Ag(I) complexes derived from mixed ligands, Polyhedron, 28(2009)2983-2988.
[34] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, R.-B. Huang,*L.-S. Zheng, Syntheses, structures, photoluminescences of silver(I) coordination polymers with 2-aminopyrazine and varied dicarboxylateligands, Polyhedron, 29 (2010)1243-1250.
[35] D. Sun, N. Zhang, G.-G. Luo,Q.-J. Xu, R.-B. Huang,* L.-S. Zheng, Assembly of silver(I) coordination polymers incorporating pyromellitic acid and N-heterocyclic ligands, Polyhedron, 29 (2010)1842-1848.
[36] D. Sun, C.-F.Yang, Z.-H. Wei, G.-G. Luo, N. Zhang, Q.-J. Xu, R.-B. Huang,* L.-S. Zheng, Self-assembly of a Novel Three-dimensional Silver(I) Supramolecular Framework from Cationic Chains and Anionic Sheets, Z. Naturforsch. B, 65 (2010)152-156.
[37] D. Sun, G.-G. Luo, N. Zhang, Q.-J. Xu, Z.-H. Wei, C.-F. Yang, L.-R. Lin, R.-B. Huang,* L.-S. Zheng, A Novel 3D Photoluminescent Silver(I) Coordination Polymer Featuring Unusual m4-Bonded and Usual m2-Bonded 2-Aminopyrazine, Bull.Chem. Soc. Jpn. 83(2010) 173-175.
[38] D. Sun, G.-G. Luo, N. Zhang, Z.-H. Wei, C.-F. Yang, R.-B. Huang,* L.-S. Zheng, Capturing a Metastable Silver(I) Compound of Pyrazine-2,3-dicarboxylic Acid, Chem. Lett., 39 (2010)190-191.
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指导学生情况:
博士研究生:
王芝 (导师:孙頔)2017.9-2021.6,方向:原子簇化学,高核银簇组装,机理及功能。获得中国化学会首届菁青化学星火奖,2018年度博士研究生国家奖学金,2018年度首届山东大学研究生学术之星奖,2018年度唐敖庆化学奖学金,2018年度山东大学校长奖,2018年度山东大学化学与化工学院“晨曦杯”杰出奖,2019年度山东大学化学与化工学院“晨曦杯”专业优胜奖。
张闪闪(导师:孙頔)2018.9-至今,方向:原子簇化学,高核银簇组装及功能。
硕士研究生:
韩璐璐 (导师:孙頔)2012.9-2015.6,方向:功能配合物化学,联吡唑构筑的功能配合物。获得2014年度国家奖学金,2014年度山东大学研究生优秀学术成果奖,2014年度山东大学2014年度优秀研究生,2014年度山东大学化学与化工学院“晨曦杯”杰出奖,2015年度省级优秀毕业生,2016年山东省优秀硕士论文奖。
赵雅琴 (导师:王兴坡、孙頔)2012.9-2015.6, 方向:功能配合物化学,杂多酸构筑的新型功能材料。获得2014年度山东大学研究生科研成果奖,2014年度山东大学优秀研究生,2014年度山东大学化学与化工学院“晨曦杯”专业优胜奖。
李小雨(导师:王兴坡、孙頔)2013.9-2016.6,方向:原子簇化学,高核银簇组装功能及其研究。获得2015年度国家奖学金,2015年度山东大学校长奖学金,2016年度山东大学研究生优秀学术成果奖三等奖,毕业后加入南开大学卜显和教授团队攻读博士学位。
郭玲玉(导师:王兴坡、孙頔)2014.9-2017.6,方向:功能配合物化学,缺位杂多酸构筑的新型杂化材料。获得学业奖学金一等奖和2016年度IKA研究生创新奖。
王芝 (导师:孙頔)2014.9-2017.6,方向:原子簇化学,高核银簇组装及功能。获得2016年度国家奖学金,2016年度山东大学校长奖学金,2016年度山东大学化学与化工学院“晨曦杯”杰出奖,2018年山东省优秀硕士论文奖。
张闪闪(导师:孙頔)2015.9-2018.6,方向:原子簇化学,高核银簇组装及功能。获得2017年度国家奖学金,2017年度山东大学化学与化工学院“晨曦杯”杰出奖,2018年度山东大学研究生优秀学术成果奖三等奖。
卓红艳(导师:王兴坡、孙頔)2015.9-2018.6,方向:原子簇化学,高核银簇组装及功能。
苏艳敏(导师:孙頔)2016.9-至今,方向:原子簇化学,高核银簇组装及功能。
刘佳伟(导师:赵全芹、孙頔)2016.9-至今,方向:原子簇化学,高核银簇组装及功能。获得2018年度国家奖学金,2018年度山东大学化学与化工学院“晨曦杯”杰出奖。
季保乾(导师:孙頔)2017.9-至今,方向:原子簇化学,高核过渡金属簇组装及功能。
刘君燕(导师:赵全芹、孙頔)2017.9-至今,方向:原子簇化学,纳米银簇组装及功能。
张文晶(导师:孙頔)2018.9-至今,方向:原子簇化学,纳米银簇组装及功能。
韩保亮(导师:王兴坡、孙頔)2018.9-至今,方向:原子簇化学,亚铜簇组装及功能。
梁晓倩(导师:赵全芹、孙頔)2018.9-至今,方向:原子簇化学,银簇组装及功能。
本科生:
袁帅 (2009级本科化学专业)TexasA&M University,Hong-Cai JOE Zhou课题组
徐梦真 (2010级本科化学专业)保送北京大学
刘珊珊 (2010级本科化工专业)保送天津大学
方明响 (2011级本科化学专业)保送山东大学
邓永恺 (2011级本科泰山学堂化学专业)已保送厦门大学
陈文淼(2012级本科化学专业)TexasA&M University,Hong-Cai JOE Zhou课题组
欢迎优秀的博士后(常年招聘),研究生(硕士和博士生各两名)和本科生(不限人数)加入本题组并参与相关科研项目。读研三年期间,表现突出的学生可获得不低于2万的助研津贴!!
本课题组经常有外国专家/学生来访,参与项目的学生有机会和国外知名专家/学生进行面对面交流,研究生就读期间至少提供1次短期出国交流机会,1-2次参加国内外学术会议的机会。望有志者青年加盟本课题组。
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招收无机化学、配位化学、团簇化学、配位化学相关纳米材料方向博士后和科研助理(虚位以待,欢迎联系)!
一、研究方向
1.功能配合物;
2.金属团簇化学;
3.配位化学相关纳米材料化学
4.团簇计算化学
二、招聘条件
1.具有良好的职业道德,较强的事业心和责任感,具有良好的人际沟通能力;
2.已获得博士学位或近期内能顺利完成博士论文答辩并获得博士学位者(不超过35岁);
3.具有较高的科研能力和科研水平,在国际重要学术刊物发表高水平文章者优先;
三、岗位待遇
1.根据研究背景及成果,年薪20-40万,课题组将根据个人工作能力和科研成果给予科研奖励
注:(1)具有良好科研背景的博士后入站后可直接给予10万元绩效,优秀博士后出站可以留校任教;
(2)如果对待遇有任何想法,非常欢迎提出你自己希望的薪资待遇;
2.提供优良的工作环境,享受五险一金,其它福利待遇参照正式职工;
3.作为负责人积极申请国家自然科学基金及省、市各级课题;
4.表现优异且有意在山东大学继续发展者,可聘为助理研究员或副研究员。符合条件的可以申请山东大学齐鲁青年学者等获得相应人才补贴;
其它待遇:
1.学校现有四所附属医院及多家附属中小幼教(山大附中在初中部全国第二),能够为关系转入我校的博士后提供优质的医疗保健服务和基础教育服务;
2.博士后在站期间按在职教师同等标准缴纳社会保险和住房公积金,与在职教师享有同等的图书及科研资源;
3.学校为符合条件的博士后提供博士后公寓供优惠租住;
4.学校提供科研启动经费,资助期限为两年;
5.学校实施国际学术交流项目,支持在站博士后参加国际高水平学术活动;
6.课题组协助应聘者申请国家和省部级各类博士后基金项目;
7.济南校本部入选者且符合济南市相关政策的享受5000元/月资助;在济购房可申请相应的购房补贴。
教育经历
[1] 2008.9-2011.6
厦门大学 | 无机化学 | 理学博士学位
[2] 2005.9-2009.9
厦门大学 | 无机化学 | 理学硕士学位
[3] 2001.9-2005.7
聊城大学 | 化学 | 理学学士学位
[4] 1998.9-2001.6
聊城市第一中学
工作经历
[1] 2017.9-至今
山东大学化学与化工学院
[2] 2017.9-至今
化学与化工学院
|
无机化学与材料化学研究所
|
教授
[3] 2014.9-2017.8
山东大学化学与化工学院
|
副教授
[4] 2011.7-2014.8
山东大学化学与化工学院
社会兼职
-
[1] Molecule
Editorial Board Member for Inorganic Chemistry Section -
[2] Chinese Chemical Letter 青年编委
研究方向
团队成员
团队名称:金属团簇
团队介绍:课题组一直致力于功能配(簇)合物的设计合成、可控制备与性能研究;在合成方法学的探索、结构调变机制、组装机理、构效关系阐明等方面取得了多项具有创新性的科研成果。自2016至今,以通讯作者在CCS Chem. (2篇), Proc. Natl. Acad. Sci. U.S.A. (1篇), Nat. Commun. (6篇), J. Am. Chem. Soc. (9篇), Angew. Chem. Int. Ed. (12篇), Adv. Mater. (2篇), ACS Nano (5篇) , Chem. Mater. (2篇), Adv. Opt. Mater. (2篇), Adv. Energy Mater. (1篇), Coord. Chem. Rev. (2篇) 等杂志发表高水平SCI论文100余篇。研究工作被Science, Nat Rev Chem., ChemViews等学术组织或网站撰写专文亮点评述。论文被引1万余次,H指数=55, 单篇引用大于100次的20余篇(数据来源Web of Science, 2021.10.1)